| 1. |
- Abid, Fahim, et al.
(författare)
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Differences in morphology and polarization properties of heat-treated XLPE and LDPE insulation
- 2016
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Ingår i: 2016 IEEE CONFERENCE ON ELECTRICAL INSULATION AND DIELECTRIC PHENOMENA (IEEE CEIDP). - : IEEE conference proceedings. - 9781509046546 ; , s. 113-116
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Konferensbidrag (refereegranskat)abstract
- Cross-linked polyethylene (XLPE) is the most commonly used insulating material for extruded high voltage cable applications. Degassing is a heat-treatment process that is performed to remove methane from XLPE insulation which is formed during the crosslinking reactions as a by-product. Apart from removing methane, heat-treatment influences the electrical properties through changing the morphology due to annealing and also removal of polar crosslinking by-products. Scanning electron microscopy (SEM) is generally used to observe the changes in crystalline structure of the polymer. Frequency domain spectroscopy (FDS) is widely used to study polarization properties of dielectric materials. In this study these two methods are used for a comparative analysis of XLPE and LDPE subjected to different heat-treatment time, with or without a diffusion barrier. Electrical measurements are performed at room temperature. From the SEM imaging conducted after permanganate acid etching, formation of spherulites due to heat-treatment is not obvious in neither LDPE nor in XLPE. However, distinctions between LDPE and XLPE in SEM micrographs are evident. From studies with dielectric polarization spectroscopy, it is found that the LDPE samples are less sensitive to heat-treatment in comparison to the XLPE samples while dissipation factor of XLPE samples are influenced by the choice of pressing film used during sample preparation.
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| 2. |
- Ahmed, Abdelsalam, et al.
(författare)
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Fire-retardant, self-extinguishing triboelectric nanogenerators
- 2019
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Ingår i: Nano Energy. - : Elsevier BV. - 2211-2855. ; 59, s. 336-345
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Tidskriftsartikel (refereegranskat)abstract
- The development of highly sensitive sensors and power generators that could function efficiently in extreme temperatures and contact with fire can be lifesaving but challenging to accomplish. Herein, we report, for the first time, a fire-retardant and self-extinguishing triboelectric nanogenerator (FRTENG), which can be utilized as a motion sensor and/or power generator in occupations such as oil drilling, firefighting or working in extreme temperature environments with flammable and combustible materials. The device takes advantage of the excellent thermal properties of carbon derived from resorcinol-formaldehyde aerogel whose electrical, mechanical and triboelectric properties have been improved via the introduction of Polyacrylonitrile nanofibers and graphene oxide nanosheets. This FRTENG is not flammable even after 90 s of trying, whereas conventional triboelectric materials were entirely consumed by fire under the same conditions. The developed device shows exceptional charge transfer characteristics, leading to a potential difference up to 80 V and a current density up to 25 mu A/m(2). When integrated into firefighter's shoes, the FRTENG is able to discern the movements of a firefighter in hazardous situations, while providing the high thermal stability missing in conventional TENGs. The fire-retardant and self-extinguishing characteristics offered by the FRTENG makes it a path-breaking device for lifesaving wearable applications.
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| 3. |
- Ahmed, A., et al.
(författare)
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Toward High-Performance Triboelectric Nanogenerators by Engineering Interfaces at the Nanoscale : Looking into the Future Research Roadmap
- 2020
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Ingår i: Advanced Materials Technologies. - : Wiley-Blackwell. - 2365-709X. ; 5:11, s. 2000520-
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Tidskriftsartikel (refereegranskat)abstract
- To meet the future need for clean and sustainable energies, there has been considerable interest in the development of triboelectric nanogenerators (TENGs) that scavenge waste mechanical energies. The performance of a TENG at the macroscale is determined by the multifaceted role of surface and interface properties at the nanoscale, whose understanding is critical for the future development of TENGs. Therefore, various protocols from the atomic to the macrolevel for fabrication and tuning of surfaces and interfaces are required to obtain the desired TENG performance. These protocols branch out into three categories: chemical engineering, physical engineering, and structural engineering. Chemical engineering is an affordable and optimal strategy for introducing more surface polarities and higher work functions for the improvement of charge transfer. Physical engineering includes the utilization of surface morphology control, and interlayer interactions, which can enhance the active interfacial area and electron transfer capacity. Structural engineering at the macroscale, which includes device and electrode design/modifications has a considerable effect on the performance of TENGs. Future challenges and promising research directions related to the construction of next-generation TENG devices, taking into consideration “interfaces” are also presented.
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| 4. |
- Akhlaghi, Shahin, et al.
(författare)
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Degradation of carbon-black-filled acrylonitrile butadiene rubber in alternative fuels : Transesterified and hydrotreated vegetable oils
- 2016
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Ingår i: Polymer degradation and stability. - : Elsevier. - 0141-3910 .- 1873-2321. ; 123, s. 69-79
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Tidskriftsartikel (refereegranskat)abstract
- The deterioration of acrylonitrile butadiene rubber (NBR), a common sealing material in automobile fuel systems, when exposed to rapeseed biodiesel and hydrotreated vegetable oil (HVO) was studied. The fuel sorption was hindered in HVO-exposed rubber by the steric constraints of bulky HVO molecules, but it was promoted in biodiesel-exposed rubber by fuel-driven cavitation in the NBR and by the increase in diffusivity of biodiesel after oxidation. The absence of a tan δ peak of the bound rubber and the appearance of carbon black particles devoid of rubber suggested that the cavitation was made possible in biodiesel-aged rubber by the detachment of bound rubber from particle surfaces. The HVO-exposed NBR showed a small decrease in strain-at-break due to the migration of plasticizer from the rubber, and a small increase in the Young’s modulus due to oxidative crosslinking. A drastic decrease in extensibility and Payne-effect amplitude of NBR on exposure to biodiesel was explained as being due to the damage caused by biodiesel to the continuous network of bound rubber-carbon black. A decrease in the ZnO crystal size with increasing exposure time suggested that the particles are gradually dissolved in the acidic components of oxidized biodiesel. The Zn2+ cations released from the dissolution of ZnO particles in biodiesel promoted the hydrolysis of the nitrile groups of NBR.
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| 5. |
- Akhlaghi, Shahin, et al.
(författare)
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Degradation of fluoroelastomers in rapeseed biodiesel at different oxygen concentrations
- 2017
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Ingår i: Polymer degradation and stability. - : Elsevier. - 0141-3910 .- 1873-2321. ; 136, s. 10-19
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Tidskriftsartikel (refereegranskat)abstract
- The degradation of fluoroelastomers (FKM) based on different monomers, additives and curing systems was studied after exposure to rapeseed biodiesel at 100 °C and different oxygen partial pressures. The sorption of fuel in the carbon black-filled FKM terpolymer was promoted by the fuel-driven cavitation in the rubber. The bisphenol-cured rubbers swelled more in biodiesel than the peroxide-cured FKM, presumably due to the chain cleavage caused by the attack of biodiesel on the double bonds formed during the bisphenol curing. With any of the selected types of monomer, the FKM rubbers absorbed biodiesel faster and to a greater extent with increasing oxygen partial pressure due to the increase in concentration of the oxidation products of biodiesel. Water-assisted complexation of biodiesel on magnesium oxide and calcium hydroxide particles led to dehydrofluorination of FKM, resulting in an extensive fuel uptake and a decrease in the strain-at-break and the Young's modulus of the rubbers. An increase in the CH2-concentration determined by infrared spectroscopy, and the appearance of biodiesel flakes in scanning electron micrographs of the extracted rubbers, were explained as being due to the presence of insoluble biodiesel grafted onto FKM on the unsaturated sites resulting from dehydrofluorination. The extensibility of the GFLT-type FKM was the least affected on exposure to biodiesel because this rubber contained less unsaturation and metal oxide/hydroxide particles.
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| 6. |
- Aljure, Mauricio, et al.
(författare)
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Electric Conduction in Mineral Oil based ZnONanofluids under Intense Electric Fields
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- The electric conduction processes in mineral oil based ZnO–C18 nanofluids under intense electric fields are investigated. For this, conduction currents are measured usinga needle-plane electrode configuration. Furthermore, an electrohydrodynamic (EHD) model is used here to discuss the charge generation mechanisms and the electronic properties of the ZnO–C18 nanofluids. The analysis of the conduction currents shows that ZnO–C18 nanoparticles increase the generation of charge carriers, and at the same time they augment the scavenging of quasi-free electrons compared with the measurements with mineral oil only. It is found that the existing nanoparticle electron scavenging model reported in the literature grossly underestimates the electron scavenging process here reported. A new analytical formulation for the nanoparticle electron scavenging process is proposed. The EHD model is also used to simulate the electric conduction processes just before negative streamer inception in mineral oil and ZnO–C18 nanofluids. It is shown that ZnO–C18 nanoparticles hinder the streamer initiation process by reducing the effective electric field at the tip of the needle. This electric field reduction is caused by the combined effect of the generation of charge carriers and the electron scavenging of ZnO–C18 nanoparticles.
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| 7. |
- Becerra Garcia, Marley, 1979-, et al.
(författare)
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High field conduction in mineral oil based zno nanofluids prior to negative streamer inception
- 2021
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Ingår i: Journal of Physics Communications. - : IOP Publishing. - 2399-6528. ; 5:4
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Tidskriftsartikel (refereegranskat)abstract
- The electric conduction under intense electric fields (up to ∼ 10 V/m) in nanofluids using surface-modified ZnO–C nanoparticles dispersed in mineral oil as host, is investigated with both experiments and numerical simulations. The measurements are used to estimate unknown parameters necessary to represent the generation and loss of electrons in an electrohydrodynamic model for mineral oil with and without ZnO–C nanoparticles in a needle-plane configuration. The model suggests that ZnO–C nanoparticles induce an enhanced field emission from negative needles, explaining the significantly larger conduction currents measured in the nanofluid compared with those in the host liquid. It is also found that the scavenging of electrons by ZnO–C nanoparticles is a process which is negligible compared with the loss of electrons due to attachment in mineral oil. It is shown that ZnO–C nanoparticles hinder the streamer initiation process by reducing the effective electric field at the tip of the needle. This electric field reduction is caused by the combined effect of enhanced electron injection through ZnO–C nanoparticles and strong electron attachment in mineral oil. Thus, the electric field on the needle tip reaches the same threshold value when the streamer is incepted in the nanofluid as in mineral oil, although at a larger voltage. Solid evidence indicating that the additional electron scavenging and the reduced electron mobility introduced by nanoparticles has no effect in the conduction currents and in the negative streamer inception in the tested ZnO–C nanofluids is shown.
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| 8. |
- Castro-Mayorga, J. L., et al.
(författare)
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The impact of zinc oxide particle morphology as an antimicrobial and when incorporated in poly(3-hydroxybutyrate-co-3-hydroxyvalerate) films for food packaging and food contact surfaces applications
- 2017
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Ingår i: Food and Bioproducts Processing. - : Institution of Chemical Engineers. - 0960-3085 .- 1744-3571. ; 101, s. 32-44
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Tidskriftsartikel (refereegranskat)abstract
- In this work, zinc oxide (ZnO) micron and nano sized-particles with different morphologies were synthesized by aqueous precipitation and evaluated as antimicrobial agents against foodborne pathogens. The most effective bactericide system was selected to prepare active poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) films by three different methods (i) direct melt-mixing, (ii) melt-mixing of preincorporated ZnO into PHBV18 (18 mol% valerate content) fiber mats made by electrospinning, and, (iii) as a coating of the annealed electrospun PHBV18/ZnO fiber mats over compression molded PHBV. Results showed that ZnO successfully improved the thermal stability of the PHBV18, being the preincorporation method the most efficient in mitigating the negative impact that the PHBV18 had on the thermal stability, barrier and optical properties of the PHBV films. Similar behavior was found for the coating structure although this film showed effective and prolonged antibacterial activity against Listeria monocytogenes. This study highlights the suitability of the PHBV/ZnO nanostructures for active food packaging and food contact surface applications.
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| 9. |
- D'Auria, Silvia, et al.
(författare)
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Polyethylene Based Ionomers as High Voltage Insulation Materials
- 2023
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Ingår i: Advanced Functional Materials. - 1616-3028 .- 1616-301X. ; 33:36
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Tidskriftsartikel (refereegranskat)abstract
- Polyethylene based ionomers are demonstrated to feature a thermo-mechanical and dielectric property portfolio that is comparable to cross-linked polyethylene (XLPE), which may enable the design of more sustainable high voltage direct-current (HVDC) power cables, a crucial component of future electricity grids that seamlessly integrate renewable sources of energy. A new type of ionomer is obtained via high-pressure/high-temperature free radical copolymerization of ethylene in the presence of small amounts of ion-pair comonomers comprising amine terminated methacrylates and methacrylic acid. The synthesized ionomers feature a crystallinity, melting temperature, rubber plateau modulus and thermal conductivity like XLPE but remain melt-processable. Moreover, the preparation of the ionomers is free of byproducts, which readily yields a highly insulating material with a low dielectric loss tangent and a low direct-current (DC) electrical conductivity of 1 to 6·10−14 S m−1 at 70 °C and an electric field of 30 kV mm−1. Evidently, the investigated ionomers represent a promising alternative to XLPE-based high voltage insulation, which may permit to ease the production as well as end-of-use recycling of HVDC power cables by combining the advantages of thermoset and thermoplastic materials while avoiding the formation of byproducts.
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| 10. |
- Gubanski, Stanislaw, 1950, et al.
(författare)
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Polymer composition and electrical devices
- 2021
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Patent (övrigt vetenskapligt/konstnärligt)abstract
- The invention relates to a polymer composition comprising a polymer (a) and a nanoparticle filler (b), wherein the polymer composition comprises a volume percentage (vol. %) of the nanoparticle filler (b), which is Dvol vol. %, and has a center-to-center average distance, in nanometer (nm), in two dimensions (2D) and with a free radius, from one nanoparticle to its nearest nanoparticle neighbour, which is R1st nm, and wherein the polymer composition shows a dependency between said center-to-center average distance to nearest neighbour, R1st, and said volume percentage, Dvol vol. %, which is R1st=E/(Dvol+0.3)+F, wherein Dvol1≤Dvol≤Dvol2, E1≤E≤E2, F1≤F≤F2, and Dvol1 is 0.010 and Dvol2 is 4.4, E1 is 100 and E2 is 280, and F1 is 50 and F2 is 140; an electrical device, e.g. a power cable; and a process for producing an electrical device.
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