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- Jiang, K., et al.
(författare)
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Interfacial Approach toward Benzene-Bridged Polypyrrole Film–Based Micro-Supercapacitors with Ultrahigh Volumetric Power Density
- 2020
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Ingår i: Advanced Functional Materials. - : Wiley. - 1616-301X .- 1616-3028. ; 30:7
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Tidskriftsartikel (refereegranskat)abstract
- 2D soft nanomaterials are an emerging research field due to their versatile chemical structures, easily tunable properties, and broad application potential. In this study, a benzene‐bridged polypyrrole film with a large area, up to a few square centimeters, is synthesized through an interfacial polymerization approach. As‐prepared semiconductive films exhibit a bandgap of ≈2 eV and a carrier mobility of ≈1.5 cm2 V−1 s−1, inferred from time‐resolved terahertz spectroscopy. The samples are employed to fabricate in‐plane micro‐supercapacitors (MSCs) by laser scribing and exhibit an ultrahigh areal capacitance of 0.95 mF cm−2, using 1‐ethyl‐3‐methylimidazolium tetrafluoroborate ([EMIM][BF4]) as an electrolyte. Importantly, the maximum energy and power densities of the developed MSCs reach values up to 50.7 mWh cm−3 and 9.6 kW cm−3, respectively; the performance surpassing most of the 2D material‐based MSCs is reported to date.
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