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- Akiba, K., et al.
(författare)
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LHC forward physics
- 2016
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Ingår i: Journal of Physics G: Nuclear and Particle Physics. - : IOP Publishing. - 0954-3899 .- 1361-6471. ; 43:11
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Tidskriftsartikel (refereegranskat)
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- Nilsson, Jessica, et al.
(författare)
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Hexakis(tetraaquasodium) decavanadate(V) dihydrate
- 2010
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Ingår i: Acta Crystallographica Section E: Structure Reports Online. - 1600-5368. ; 66, s. 30-148
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Tidskriftsartikel (refereegranskat)abstract
- The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.
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4. |
- Nilsson, Jessica, et al.
(författare)
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Salicylamide and salicylglycine oxidovanadium complexes with insulin-mimetic properties.
- 2011
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Ingår i: Journal of Inorganic Biochemistry. - : Elsevier BV. - 1873-3344 .- 0162-0134. ; 105, s. 1795-1800
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Tidskriftsartikel (refereegranskat)abstract
- Reaction of N-(2-hydroxybenzyl)-N-(2-picolyl) glycine (H(2)papy) with VOSO(4) in water gives the oxidovanadium(V) oxido-bridged dimer [{(papy)(VO)}(2) μ-O)] (1). Similarly, reaction of N-(2-hydroxybenzyl) glycine (H(2)glysal) with VOSO(4) gives [(glysal)VO(H(2)O)] (2) and reaction of salicylamide (Hsalam) with VOSO(4) in methanol gives [(salam)(2)VO] (3). The crystal structure of the oxido-bridged complex 1 is reported. The insulin-mimetic activity of all three complexes was evaluated with respect to their ability to phosphorylate protein kinase B (PKB). The speciations of complexes 1 and 2 were studied over the pH range 2-10. Complex 1 shows greater stability over the whole pH range but only 2 and 3 exhibit an insulin-mimetic effect.
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- Nilsson, Jessica, et al.
(författare)
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The redox interaction between the vanadyl cation and tris[6-(2-hydroxymethyl)pyridylmethyl]amine
- 2012
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Ingår i: Inorganica Chimica Acta. - : Elsevier BV. - 0020-1693. ; 392, s. 490-493
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Tidskriftsartikel (refereegranskat)abstract
- Reaction of tris[6-(2-hydroxymethyl)pyridylmethyl]amine, tpa(OH)(3), with (VOSO4)-O-IV center dot 5H(2)O resulted in an unexpected redox reaction producing [(VLH)-L-III][(VLH2)-L-III][PF6](3)center dot 1.5H(2)O (where H3L is bis(2-hydroxymethylpyridyl)(2-carboxypyridylmethyl)amine). This reaction is interesting in the light of the ability of ascidians to accumulate V-III by reduction of V-V from sea water. It also provides additional proof to the susceptibility of pyridylmethylamines to oxidation by certain metal ions. (C) 2012 Elsevier B. V. All rights reserved.
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8. |
- Aad, G, et al.
(författare)
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- 2015
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swepub:Mat__t
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