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Sökning: WFRF:(Beran Martin)

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1.
  • Appelgren, Jessica, et al. (författare)
  • Autonoma vapensystem – dagens debatt och en väg framåt : tekniska, legala och etiska aspekter
  • 2022
  • Rapport (övrigt vetenskapligt/konstnärligt)abstract
    • Framstegen inom AI väcker frågor kring den militära tilllämpningen av tekniken och tillåten grad av automatisering av vapensystem. Debatten om AI i militära tillämpningar förs både av civilsamhällets organisationer och av stater. Debatten började med det mycket specifika ifrågasättandet av fullt autonoma vapensystem, ofta kallade Lethal Autonomous Weapon Systems (LAWS), men debatten och ifrågasättandet har vidgats till att omfatta införandet av AI i militära tillämpningar. Diskussionen är mångfacetterad och präglas av flera olika perspektiv på ställningstaganden och argumentation. Autonoma system har många användningsområden i militära tillämpningar och det är viktigt att förstå hur integrationen av högautomatiserade system ska kunna göras medavseende på de rättsliga ramverk som försvaret lyder under.Även om debatten till viss del har sitt ursprung i det senaste decenniets drönarkrigföring är de flesta parter överens omatt dagens debatt snarare handlar om framtida teknik. De tekniska, militära och juridiska aspekterna är centrala i diskussionen men även etiska, psykologiska och säkerhetspolitiska aspekter tar plats i debatten.
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2.
  • Cedervall, Johan, et al. (författare)
  • Low temperature magneto-structural transitions in Mn3Ni20P6
  • 2016
  • Ingår i: Journal of Solid State Chemistry. - : Academic Press Inc.. - 0022-4596 .- 1095-726X. ; 237, s. 343-348
  • Tidskriftsartikel (refereegranskat)abstract
    • X-ray and neutron powder diffraction has been used to determine the crystal and magnetic structure of Mn3Ni20P6. The crystal structure can be described as cubic with space group Fm3¯m (225) without any nuclear phase transformation within studied temperature interval from room temperature down to 4 K. The magnetic structure of Mn3Ni20P6 is complex with two independent magnetic positions for the Mn atoms and the compound passes three successive magnetic phase transitions during cooling. At 30 K the spins of the Mn atoms on the Wyckoff 4a site (Mn1) order to form a primitive cubic antiferromagnetic structure with propagation vector k=(0 0 1). Between 29 and 26 K the Mn atoms on the Wyckoff 8c site (Mn2) order independently on already ordered Mn1 magnetic structure forming a commensurate antiferromagnetic structure with propagation vector k=(0 0 12) and below 26 K, both Mn positions order to form an incommensurate helical structure with propagation vector k=(0 0 ~0.45). Magnetization vs. temperature curve of Mn3Ni20P6 shows a steep increase indicating some magnetic ordering below 230 K and a sharp field dependent anomaly in a narrow temperature range around 30 K.
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3.
  • Cedervall, Johan, et al. (författare)
  • Magnetic structure of the magnetocaloric compound AlFe2B2
  • 2016
  • Ingår i: Journal of Alloys and Compounds. - : Elsevier. - 0925-8388 .- 1873-4669. ; 664, s. 784-791
  • Tidskriftsartikel (refereegranskat)abstract
    • The crystal and magnetic structures of AlFe2B2 have been studied with a combination of X-ray and neutron diffraction and electronic structure calculations. The magnetic and magnetocaloric properties have been investigated by magnetisation measurements. The samples have been produced using high temperature synthesis and subsequent heat treatments. The compound crystallises in the orthorhombic crystal system Cmmm and it orders ferromagnetically at 285 K through a second order phase transition. At temperatures below the magnetic transition the magnetic moments align along the crystallographic a-axis. The magnetic entropy change from 0 to 800 kA/m was found to be - 1.3 J/K kg at the magnetic transition temperature.
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4.
  • Cedervall, Johan, et al. (författare)
  • Magnetostructural transition in Fe5SiB2 observed with neutron diffraction
  • 2016
  • Ingår i: Journal of Solid State Chemistry. - : Elsevier BV. - 0022-4596 .- 1095-726X. ; 235, s. 113-118
  • Tidskriftsartikel (refereegranskat)abstract
    • The crystal and magnetic structure of Fe5SiB2 has been studied by a combination of X-ray and neutron diffraction. Also, the magnetocrystalline anisotropy energy constant has been estimated from magnetisation measurements. High quality samples have been prepared using high temperature synthesis and subsequent heat treatment protocols. The crystal structure is tetragonal within the space group I4/mcm and the compound behaves ferromagnetically with a Curie temperature of 760 K. At 172 K a spin reorientation occurs in the compound and the magnetic moments go from aligning along the c-axis (high T) down to the ab-plane (low T). The magnetocrystalline anisotropy energy constant has been estimated to 0.3 MJ/m3 at 300 K.
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5.
  • Cedervall, Johan, et al. (författare)
  • On the structural and magnetic properties of the double perovskite Nd2NiMnO6Nd2NiMnO6
  • 2019
  • Ingår i: Journal of Materials Science: Materials in Electronics. - : Springer Science and Business Media LLC. - 1573-482X .- 0957-4522. ; 30:17, s. 16571-16578
  • Tidskriftsartikel (refereegranskat)abstract
    • The structural, electronic and magnetic properties of phase pure and stoichiometric samples of the double perovskite Nd 2NiMnO 6 have been investigated with a combination of X-ray and neutron diffraction, X-ray photoelectron spectroscopy and magnetometry. It is found that the monoclinic space group P2 1/ n best describes the crystal structure of Nd 2NiMnO 6. Photoectron spectroscopy revels a mixed valence of the transition metal sites where Ni has 3+/2+ oxidation states and Mn has 3+/4+. The compound orders ferromagnetically at ∼195 K. The magnetic structure was determined from the refinement of the neutron diffraction data. The results suggests that the B-site magnetic moments align along the crystallographic a-direction.
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6.
  • Cedervall, Johan, et al. (författare)
  • Phase stability and structural transitions in compositionally complex LnMO 3 perovskites
  • 2021
  • Ingår i: Journal of Solid State Chemistry. - : Elsevier BV. - 0022-4596 .- 1095-726X. ; 300
  • Tidskriftsartikel (refereegranskat)abstract
    • Entropy stabilised materials have possibilities for tailoring functionalities to overcome challenges in materials science. The concept of configurational entropy can also be applied to metal oxides, but it is unclear whether these could be considered as solid solutions in the case of perovskite-structured oxides and if the configurational entropy plays a stabilising role. In this study, compositionally complex perovskite oxides, LnMO3 (Ln ​= ​La, Nd, Sm, Ca and Sr, M ​= ​Ti, Cr, Mn, Fe, Co, Ni, and Cu), are investigated for their phase stability and magnetic behaviour. Phase-pure samples were synthesised, and the room temperature structures were found to crystallise in either Pnma or R3¯c space groups, depending on the composition and the resulting tolerance factor, while the structural transition temperatures correlate with the pseudo cubic unit cell volume. The techniques used included diffraction with X-rays and neutrons, both ex- and in-situ, X-ray photoelectron spectroscopy, magnetometry as well as electron microscopy. Neutron diffraction studies on one sample reveal that no oxygen vacancies are found in the structure and that the magnetic properties are ferrimagnetic-like with magnetic moments mainly coupled antiferromagnetically along the crystallographic c-direction. X-ray photoelectron spectroscopy gave indications of the oxidation states of the constituting ions where several mixed oxidation states are observed in these valence-compensated perovskites.
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7.
  • Gebresenbut, Girma, 1982-, et al. (författare)
  • Long range ordered magnetic and atomic structures of the quasicrystal approximant in the Tb-Au-Si system
  • 2014
  • Ingår i: Journal of Physics. - : IOP Publishing. - 0953-8984 .- 1361-648X. ; 26:32, s. 322202-
  • Tidskriftsartikel (refereegranskat)abstract
    • The atomic and magnetic structure of the 1/1 Tb(14)Au(70)Si(16) quasicrystal approximant has been solved by combining x-ray and neutron diffraction data. The atomic structure is classified as a Tsai-type 1/1 approximant with certain structural deviations from the prototype structures; there are additional atomic positions in the so-called cubic interstices as well as in the cluster centers. The magnetic property and neutron diffraction measurements indicate the magnetic structure to be ferrimagnetic-like below 9 K in contrast to the related Gd(14)Au(70)Si(16) structure that is reported to be purely ferromagnetic.
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8.
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9.
  • Höglin, Viktor, et al. (författare)
  • Detailed study of the magnetic ordering in FeMnP0.75Si0.25
  • 2015
  • Ingår i: Journal of Solid State Chemistry. - : Elsevier BV. - 0022-4596 .- 1095-726X. ; 221, s. 240-246
  • Tidskriftsartikel (refereegranskat)abstract
    • Magnetic and crystallographic properties of FeMnP0.75Si0.25 in the hexagonal Fe2P-type structure have been investigated by X-ray powder diffraction, neutron powder diffraction and magnetic measurements. The room temperature diffractograms reveal co-existence of two distinct structural phases in the samples with small, but significant, differences only in the unit cell dimensions. The volume ratio between the two phases is governed by the annealing conditions. One of the phases orders ferromagnetically (TC = 250 K) and the other in an incommensurate antiferromagnetic structure at low temperatures (qx = 0.363(1), TN = 150 K).
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10.
  • Höglin, Viktor, et al. (författare)
  • The crystal and magnetic structure of the magnetocaloric compound FeMnP0.5Si0.5
  • 2011
  • Ingår i: Journal of Solid State Chemistry. - : Elsevier BV. - 0022-4596 .- 1095-726X. ; 184:9, s. 2434-2438
  • Tidskriftsartikel (refereegranskat)abstract
    • The crystal and magnetic structure of the magnetocaloric compound FeMnP0.5Si0.5 has been studied by means of neutron and X-ray powder diffraction. Single phase samples of nominal composition FeMnP0.5Si0.5 have been prepared by the drop synthesis method. The compound crystallizes in the Fe2P-type structure (P-62m) with the magnetic moments aligned along the a-axis. It is found that the Fe atoms are mainly situated in the tetrahedral 3g site while the Mn atoms prefer the pyramidal 3f position. The material is ferromagnetic (TC=382 K) and at 296 K the total magnetic moment is 4.4 µB/f.u. It is shown that the magnetic moment in the 3f site is larger (2.5 µB) than in the 3g site (1.9 µB).
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