| 1. |
- Duttagupta, Srimanti, et al.
(författare)
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Role of aquifer media in determining the fate of polycyclic aromatic hydrocarbons in the natural water and sediments along the lower Ganges river basin
- 2020
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Ingår i: Journal of Environmental Science and Health. Part A. - : TAYLOR & FRANCIS INC. - 1093-4529 .- 1532-4117. ; 55:4, s. 354-373
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Tidskriftsartikel (refereegranskat)abstract
- Groundwater-sourced drinking water quality in South Asia, specifically India, is extremely stressed, mostly from the presence of many pervasive and geogenic pollutants. The presence and behavior of anthropogenic pollutants like polycyclic aromatic hydrocarbons (PAHs) are poorly investigated on a regional or basin-wide scale. The present study provides one of the first documentation of the presence and behavior of PAH in the aquifer sediments in the Ganges river basin. Lower and medium molecular weight PAHs, e.g., naphthalene, phenanthrene, and fluoranthene were detected in 79, 36, and 13% of samples (n = 25). The PAH level in groundwater was approximately five times lower than river water. The sorption behavior of PAHs were studied in experiments in presence/absence of organic carbon and by simulating advective transport of low to medium molecular weight PAHs, e.g., naphthalene, phenanthrene, and fluoranthene in aquifer sediments collected from agricultural, peri-urban, and urban areas. Naphthalene and phenanthrene adsorbed on quartz and kaolinite, but not on clay minerals like kaolinite. Fluoranthene adsorbed more favorably on kaolinite. Numerical modeling of the advective transport of PAHs in aquifers suggest up to 25 times faster movement of pollutants from irrigation-induced pumping, indicating the strong control of hydraulics on the spatial distribution of PAHs in subsurface.
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| 2. |
- Mukherjee, Abhijit, et al.
(författare)
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Elevated arsenic in deeper groundwater of the western Bengal basin, India : Extent and controls from regional to local scale
- 2011
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Ingår i: Applied Geochemistry. - : Elsevier. - 0883-2927 .- 1872-9134. ; 26:4, s. 600-613
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Tidskriftsartikel (refereegranskat)abstract
- The deeper groundwater (depending on definition) of the Bengal basin (Ganges-Brahmaputra delta) has long been considered as an alternate, safe drinking-water source in areas with As-enrichment in near-surface groundwater. The present study provides the first collective discussion on extent and controls of elevated As in deeper groundwater of a regional study area in the western part of the Bengal basin. Deeper groundwater is defined here as non-brackish, potable (Cl- <= 250 mg/L) groundwater available at the maximum accessed depth (similar to 80-300 m). The extent of elevated As in deeper groundwater in the study area seems to be largely controlled by the aquifer-aquitard framework. Arsenic-enriched deeper groundwater is mostly encountered north of 22.75 degrees N latitude, where an unconfined to semi-confined aquifer consisting of Holocene- to early Neogene-age gray sand dominates the hydrostratigraphy to 300 m depth below land surface. Aquifer sediments are not abnormally enriched in As at any depth, but sediment and water chemistry are conducive to As mobilization in both shallow and deeper parts of the aquifer(s). The biogeochemical triggers are influenced by complex redox disequilibria. Results of numerical modeling and profiles of environmental tracers at a local-scale study site suggest that deeper groundwater abstraction can draw As-enriched water to 150 m depth within a few decades, synchronous with the advent of wide-scale irrigational pumping in West Bengal (India).
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| 3. |
- Mukherjee, Abhijit, et al.
(författare)
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Occurrence, predictors and hazards of elevated groundwater arsenic across India through field observations and regional-scale AI-based modeling
- 2021
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Ingår i: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 759
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Tidskriftsartikel (refereegranskat)abstract
- Existence of wide spread elevated concentrations of groundwater arsenic (As) across South Asia, including India, has endangered a huge groundwater-based drinking water dependent population. Here, using high-spatial resolution As field-observations (similar to 3 million groundwater sources) across India, we have delineated the regional-scale occurrence of elevated groundwater As (>= 10 mu g/L), along with the possible geologic-geomorphologic-hydrologic and human-sourced predictors that influence the spatial distribution of the contaminant. Using statistical and machine learning method, we also modeled the groundwater As concentrations probability at 1 Km resolution, along with probabilistic delineation of high As-hazard zones across India. The observed occurrence of groundwater As was found to be most strongly influenced by geology-tectonics, groundwater-fed irrigated area (%) and elevation. Pervasive As contamination is observed in major parts of the Himalayan mega-river Indus-Ganges-Brahmaputra basins, however it also occurs in several more-localized pockets, mostly related to ancient tectonic zones, igneous provinces, aquifers in modern delta and chalcophile mineralized regions. The model results suggest As-hazard potential in yet-undetected areas. Our model performed well in predicting groundwater arsenic, with accuracy: 82% and 84%; area under the curve (AUC): 0.89 and 0.88 for test data and validation datasets. An estimated similar to 90 million people across India are found to be exposed to high groundwater As from field-observed data, with the five states with highest hazard are West Bengal (28 million), Bihar (21 million), Uttar Pradesh (15 million), Assam(8.6 million) and Punjab (6 million). However it can be much more if the modeled hazard is considered (>250 million). Thus, our study provides a detailed, quantitative assessment of high groundwater As across India, with delineation of possible intrinsic influences and exogenous forcings. The predictive model is helpful in predicting As-hazard zones in the areas with limited measurements.
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