| 1. |
- Burmeister, F., et al.
(författare)
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A study of the inner-valence ionization region in HCl and DCl
- 2004
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Ingår i: Journal of Physics B. - : IOP Publishing. - 0953-4075 .- 1361-6455. ; 37:6, s. 1173-1183
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Tidskriftsartikel (refereegranskat)abstract
- An in-depth photoionization study of the inner-valence electrons in HCl and DCl has been performed using synchrotron radiation. A series of photoelectron spectra of HCl were obtained at a resolution of 23 meV over the binding energy range 25-30.5 eV at various excitation energies and at two different electron collection angles relative to the plane of polarization of the undulator radiation. In addition, photoelectron spectra of DCl were recorded at two different excitation energies. These spectra were compared directly with the threshold photoelectron spectra of HCl and DCl that were recorded previously under similar resolution conditions (similar to30 meV). This comparative study reveals new information on the nature of the numerous band systems observed in this binding energy region. In addition, we present the experimental confirmation of the theoretical prediction given by Andersson et al (2001 Phys. Rev. A 65 012705) that a vibrational progression showing interference structure would appear in the main inner-valence ionization band in the photoelectron spectrum of DCl at a resolution of 10 meV.
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| 2. |
- Sandell, A., et al.
(författare)
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THE INNER VALENCE REGION OF CO ADSORBED ON PD(100)
- 1994
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Ingår i: Journal of Physics. - : IOP Publishing. - 0953-8984 .- 1361-648X. ; 26:19, s. 10659-10668
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Tidskriftsartikel (refereegranskat)abstract
- The inner valence region of CO/Pd(100) p(2square-root2 x square-root2)R45-degrees has been studied by angular resolved photoemission at the Pd 4d Cooper minimum, and with resonant Auger spectroscopy at photon energies corresponding to the C 1s and O 1s x-ray absorption (XA) maxima of the unoccupied parts of the 2pi*-Pd 4d hybrid (2pi(un)). Previously unobserved inner valence states are revealed in the direct photoemission and are compared with resonant Auger results. The interpretation and assignment of the different spectral features to different main final state configurations are based on energy, symmetry and intensity arguments, as well as comparisons with previous results.
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| 3. |
- Abu-samha, M, et al.
(författare)
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Lineshapes in carbon 1s photoelectron spectra of methanol clusters
- 2006
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Ingår i: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9084. ; 8:21, s. 2473-2482
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Tidskriftsartikel (refereegranskat)abstract
- A general protocol for theoretical modeling of inner-shell photoelectron spectra of molecular clusters is presented and applied to C1s spectra of oligomers and medium-sized clusters of methanol. The protocol employs molecular dynamics for obtaining cluster geometries and a polarizable force field for computing site-specific chemical shifts in ionization energy and linewidth. Comparisons to spectra computed from first-principle theories are used to establish the accuracy of the proposed force field approach. The model is used to analyze the C1s photoelectron spectrum of medium-sized clusters in terms of surface and bulk contributions. By treating the surface-to-bulk ratio as an adjustable parameter, satisfactory fits are obtained to experimental C1s spectra of a beam of methanol clusters.
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| 4. |
- Ausmees, A, et al.
(författare)
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Observation of excitation-energy-dependent Xe 4d(5/2,3/2)(-1) lifetime widths
- 1999
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Ingår i: JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS. - : IOP PUBLISHING LTD. ; 32:9
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- The creation and decay of photon-excited Xe 4d(5/2,3/2)(-1) core-hole states has been studied in the photon energy region 70-110 eV, where photon absorption is dominated by the strong shape resonance. Unprecedented experimental quality has enabled the stu
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| 5. |
- Baev, A., et al.
(författare)
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Geometrical information on core-excited states obtained from interference quenching of vibrational states in resonant x-ray photoemission
- 2003
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Ingår i: Physical Review A. Atomic, Molecular, and Optical Physics. - 1050-2947 .- 1094-1622. ; 67:2
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Tidskriftsartikel (refereegranskat)abstract
- An interference quenching of the m=1 final state vibrational line in the resonant Auger decay of N 1s-->pi(*) core-excited N-2 is observed and analyzed. The intensity ratio between the m=1 and m=0 vibrational levels of the X (2)Sigma(g)(+) final state shows a surprising nonmonotonic variation as a function of frequency detuning, going through a minimum with a complete suppression of m=1. We have developed a simple model which indicates a linear relation between the value of the detuning frequency for this minimum and the equilibrium bond distance of the core-excited state. This implies the possibility of determining the equilibrium bond distances for core-excited states to a high degree of accuracy. Simultaneously with the simple model we present a strict theory of the studied effect. This strict theory allows us to explore the accuracy of determining the bond length of the core-excited state from resonant Auger spectra. We obtain a weak influence of the core-hole lifetime on the determined bond length, whereas the number of intermediate vibrational states accounted for in the numerical simulations seems to be quite important.
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| 6. |
- Bassler, M, et al.
(författare)
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Beam line 1411 at MAX II - performance and first results
- 2001
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Ingår i: NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT. - : ELSEVIER SCIENCE BV. - 0168-9002. ; 469:3, s. 382-393
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Tidskriftsartikel (refereegranskat)abstract
- We report on the characteristics and first results from the soft X-ray beam line I411, based on an undulator at the third generation synchrotron facility MAX II, Sweden. The beam line is designed for high-resolution, angle-resolved electron spectroscopy o
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| 7. |
- Bassler, M, et al.
(författare)
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Soft X-ray undulator beam line I411 at MAX-II for gases, liquids and solid samples
- 1999
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Ingår i: JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA. - : ELSEVIER SCIENCE BV. - 0368-2048. ; 103, s. 953-957
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- We report on the build-up of the new undulator beam line I411 at the third-generation synchrotron radiation facility MAX II in Lund, Sweden. This beam line is based on an upgraded version of the modified SX700-monochromator and the end station which were
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| 8. |
- Bjorneholm, O, et al.
(författare)
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Between vapor and ice: Free water clusters studied by core level spectroscopy
- 1999
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Ingår i: JOURNAL OF CHEMICAL PHYSICS. - : AMER INST PHYSICS. - 0021-9606. ; 111:2, s. 546-550
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- Core level x-ray absorption and photoemission spectra of free water clusters are presented. Core and valence photoemission spectra show a weak but gradual change with cluster size. Comparisons to spectra of the isolated molecule and solid ice indicate tha
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| 9. |
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| 10. |
- Bjorneholm, O, et al.
(författare)
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Femtosecond dissociation of core-excited HCl monitored by frequency detuning
- 1997
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Ingår i: PHYSICAL REVIEW LETTERS. - : AMER INST PHYSICS. - 0031-9007. ; 79:17, s. 3150-3153
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- Core excitation of gaseous HCl to the dissociative sigma* state leads to a deexcitation spectrum with two qualitatively different contributions-a broad molecular background and narrow atomic lines. The experiment demonstrates that the ratio of integrated
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