| 1. |
- Chandrasekaran, Sundaram, et al.
(författare)
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Advanced opportunities and insights on the influence of nitrogen incorporation on the physico-/electro-chemical properties of robust electrocatalysts for electrocatalytic energy conversion
- 2021
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Ingår i: Coordination chemistry reviews. - : Elsevier. - 0010-8545 .- 1873-3840. ; 449
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Forskningsöversikt (refereegranskat)abstract
- The use of a wide range of methods for incorporating nitrogen atoms on robust catalysts has given rise to fundamental advances in the field of energy conversion and storage. Recently, nitrogen incorporation has proven to be able to fine-tune the electron densities of exposed active sites to create high-performance electrocatalysts. The preservation of a strong interface between the local atomic coordination of nitrogen atoms on bare carbon, single metal atoms, transition metal oxides, metal chalcogenides, and MXenes during synthesis plays an important role in producing an efficient electrocatalysts. In addition, the ability of nitrogen atoms to bind with carbon or metal atoms can be influenced by processing conditions. In this regard, this review is the first comprehensive overview of the range of synthetic strategies to form nitrogen incorporated catalysts and assess their chemical, structural, physical electronic property modification and their influence on electrocatalytic ORR, OER, and HER performance. This review will describe how specific strategies have been utilized to realise effective electrocatalytic systems, including the energy conversion of nitrogen incorporated catalysts, structural coordination, and material optimization. Finally, the main challenges to be considered in future investigations in order to initiate new research efforts in this promising research area are discussed.
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| 2. |
- Chen, Libo, et al.
(författare)
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Artificial tactile peripheral nervous system supported by self-power transducers
- 2021
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Ingår i: Nano Energy. - : Elsevier. - 2211-2855 .- 2211-3282. ; 82
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Tidskriftsartikel (refereegranskat)abstract
- The tactile peripheral nervous system innervating human hands, which is essential for sensitive haptic exploration and dexterous object manipulation, features overlapped receptive fields in the skin, arborization of peripheral neurons and many-to-many synaptic connections. Inspired by the structural features of the natural system, we report a supersensitive artificial slowly adapting tactile afferent nervous system based on the triboelectric nanogenerator technology. Using tribotronic transistors in the design of mechanoreceptors, the artificial afferent nervous system exhibits the typical adapting behaviours of the biological counterpart in response to mechanical stimulations. The artificial afferent nervous system is self-powered in the transduction and event-driven in the operation. Moreover, it has inherent proficiency of neuromorphic signal processing, delivering a minimum resolvable dimension two times smaller than the inter-receptor distance which is the lower limit of the dimension that existing electronic skins can resolve. These results open up a route to scalable neuromorphic skins aiming at the level of human?s exceptional perception for neurorobotic and neuroprosthetic applications.
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| 3. |
- Chen, Lan, et al.
(författare)
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Innovative aryl-based hydrophobic deep eutectic solvent for efficient removal of dyes and nanoplastics
- 2023
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Ingår i: Separation and Purification Technology. - : Elsevier BV. - 1383-5866 .- 1873-3794. ; 308
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Tidskriftsartikel (refereegranskat)abstract
- Efficient absorption is a highly important strategy to remove environmental pollutants (i.e., dyes and nano plastics), which relays on the development of innovative and sustainable absorbents. Herein, we designed an innovative aryl-based deep eutectic solvent (DES) using diphenylamine (DPA) and benzophenone (BZP) as the component at a molar ratio of 1:1, and this novel DES was denoted as DPA:BZP-1:1. The developed DPA:BZP-1:1 could efficiently adsorb RhB and PS nanoparticles from their aqueous solution/suspension, and the absorption efficiency could reach up to 97.3% and 80%, respectively. Notably, DPA:BZP-1:1 showed a higher absorption efficiency than commercial activated carbon. Experimental and computational results revealed that hydrogen bonding and 7C-7C stacking synergistically contributed to the excellent absorption ability of DPA:BZP-1:1 on dye Rhodamine B (RhB) and polystyrene (PS) nanoplastics. To the best our knowledge, this is the first study on efficient absorption of dye and nanoplastics by aryl-based DESs.
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| 4. |
- Chen, Libo, et al.
(författare)
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Spike timing–based coding in neuromimetic tactile system enables dynamic object classification
- 2024
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Ingår i: Science. - 0036-8075. ; 384, s. 660-665
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Tidskriftsartikel (refereegranskat)abstract
- Rapid processing of tactile information is essential to human haptic exploration and dexterous object manipulation. Conventional electronic skins generate frames of tactile signals upon interaction with objects. Unfortunately, they are generally ill-suited for efficient coding of temporal information and rapid feature extraction. In this work, we report a neuromorphic tactile system that uses spike timing, especially the first-spike timing, to code dynamic tactile information about touch and grasp. This strategy enables the system to seamlessly code highly dynamic information with millisecond temporal resolution on par with the biological nervous system, yielding dynamic extraction of tactile features. Upon interaction with objects, the system rapidly classifies them in the initial phase of touch and grasp, thus paving the way to fast tactile feedback desired for neuro-robotics and neuro-prosthetics.
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| 5. |
- Hu, Ya, et al.
(författare)
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Autogenic electrolysis of water powered by solar and mechanical energy
- 2022
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Ingår i: Nano Energy. - : Elsevier. - 2211-2855 .- 2211-3282. ; 91
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Tidskriftsartikel (refereegranskat)abstract
- A dual-bandgap photoelectrochemical (PEC) cell with two semiconductors stacked in tandem is a widely adopted concept to capture a large fraction of the solar spectrum for water splitting. While two photons are theoretically needed to produce one H2 molecule using single-bandgap PEC cells, four photons are generally required for one H2 molecule in the dual-bandgap cells because of an unavoidable charge recombination at the solid-solid interface. Here, triboelectric effects are exploited in the form of triboelectric nanogenerator (TENG) to allow for the generation of one H2 molecule at the expenses of two photons in a dual-bandgap device using an array of core/shell p-type silicon/anatase-TiO2 nanowires as photoelectrode. The TENG, that converts mechanical energy to electricity, efficiently suppresses the charge recombination at the interface and significantly increases the energy of the photo-generated carriers required for the simultaneous water reduction and oxidation. The synergy of photoexcitation and triboelectrics results in a rate of hydrogen production in a neutral Na2SO4 electrolyte around 150 times higher than that of the counterpart, i.e., the device in the absence of TENG. Furthermore, the TENG-induced enhancement in the PEC water splitting remains substantial even when the solar power density is reduced to 20 mW/cm2.
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| 6. |
- Huang, Zhao, et al.
(författare)
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Preparation of gold nanoparticles via anodic stripping of copper underpotential deposition in bulk gold electrodeposition for high-performance electrochemical sensing of bisphenol a
- 2023
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Ingår i: Molecules. - : MDPI. - 1431-5157 .- 1420-3049. ; 28:24
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Tidskriftsartikel (refereegranskat)abstract
- Bisphenol A is one of the most widely used industrial compounds. Over the years, it has raised severe concern as a potential hazard to the human endocrine system and the environment. Developing robust and easy-to-use sensors for bisphenol A is important in various areas, such as controlling and monitoring water purification and sewage water systems, food safety monitoring, etc. Here, we report an electrochemical method to fabricate a bisphenol A (BPA) sensor based on a modified Au nanoparticles/multiwalled carbon nanotubes composite electrocatalyst electrode (AuCu-UPD/MWCNTs/GCE). Firstly, the Au-Cu alloy was prepared via a convenient and controllable Cu underpotential/bulk Au co-electrodeposition on a multiwalled modified carbon nanotubes glassy carbon electrode (GCE). Then, the AuCu-UPD/MWCNTs/GCE was obtained via the electrochemical anodic stripping of Cu underpotential deposition (UPD). Our novel prepared sensor enables the high-electrocatalytic and high-performance sensing of BPA. Under optimal conditions, the modified electrode showed a two-segment linear response from 0.01 to 1 µM and 1 to 20 µM with a limit of detection (LOD) of 2.43 nM based on differential pulse voltammetry (DPV). Determination of BPA in real water samples using AuCu-UPD/MWCNTs/GCE yielded satisfactory results. The proposed electrochemical sensor is promising for the development of a simple, low-cost water quality monitoring system for the detection of BPA in ambient water samples.
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| 7. |
- Rangon, Claire-Marie, et al.
(författare)
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Myelination induction by a histamine H3 receptor antagonist in a mouse model of preterm white matter injury.
- 2018
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Ingår i: Brain, behavior, and immunity. - : Elsevier BV. - 1090-2139 .- 0889-1591. ; 74, s. 265-276
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Tidskriftsartikel (refereegranskat)abstract
- Fifteen million babies are born preterm every year and a significant number suffer from permanent neurological injuries linked to white matter injury (WMI). A chief cause of preterm birth itself and predictor of the severity of WMI is exposure to maternal-fetal infection-inflammation such as chorioamnionitis. There are no neurotherapeutics for this WMI. To affect this healthcare need, the repurposing of drugs with efficacy in other white matter injury models is an attractive strategy. As such, we tested the efficacy of GSK247246, an H3R antagonist/inverse agonist, in a model of inflammation-mediated WMI of the preterm born infant recapitulating the main clinical hallmarks of human brain injury, which are oligodendrocyte maturation arrest, microglial reactivity, and hypomyelination. WMI is induced by mimicking the effects of maternal-fetal infection-inflammation and setting up neuroinflammation. We induce this process at the time in the mouse when brain development is equivalent to the human third trimester; postnatal day (P)1 through to P5 with i.p. interleukin-1β (IL-1β) injections. We initiated GSK247246 treatment (i.p at 7mg/kg or 20mg/kg) after neuroinflammation was well established (on P6) and it was administered twice daily through to P10. Outcomes were assessed at P10 and P30 with gene and protein analysis. A low dose of GSK247246 (7mg/kg) lead to a recovery in protein expression of markers of myelin (density of Myelin Basic Protein, MBP & Proteolipid Proteins, PLP) and a reduction in macro- and microgliosis (density of ionising adaptor protein, IBA1 & glial fibrillary acid protein, GFAP). Our results confirm the neurotherapeutic efficacy of targeting the H3R for WMI seen in a cuprizone model of multiple sclerosis and a recently reported clinical trial in relapsing-remitting multiple sclerosis patients. Further work is needed to develop a slow release strategy for this agent and test its efficacy in large animal models of preterm infant WMI.
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| 8. |
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| 9. |
- Wu, Xutao, et al.
(författare)
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Simultaneous exfoliation and colloidal formation of few-layer semiconducting MoS2 sheets in water
- 2020
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Ingår i: Chemical Communications. - : ROYAL SOC CHEMISTRY. - 1359-7345 .- 1364-548X. ; 56:13, s. 2035-2038
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Tidskriftsartikel (refereegranskat)abstract
- A simple method allowing for simultaneous liquid-phase exfoliation of MoS2 crystals into few-layer sheets and colloidal formation of the exfoliated sheets is reported. This is enabled by using small molecular 1-pyrene-butyrate salts which provide a dual-role in the process, i.e., exfoliation enhancer and stabilizing agent of the MoS2 sheets.
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| 10. |
- Zeng, Jianhua, et al.
(författare)
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Intrinsically stretchable tribotronic mechanoplastic artificial synapse
- 2024
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Ingår i: Chemical Engineering Journal. - : Elsevier. - 1385-8947 .- 1873-3212. ; 492
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Tidskriftsartikel (refereegranskat)abstract
- Stretchable synaptic devices with adaptability to elastic deformation, sensing environmental stimuli, and unique information processing functions are of great significance for the development of the next generation of artificial nervous systems. Here, an intrinsically stretchable tribotronic mechanoplastic artificial synapse (STMAS) is proposed, which is integrated by a triboelectric nanogenerator and an electrolyte-gated transistor with ion-gel as dielectric layer. The STMAS can be modulated by the triboelectric potential induced by mechanical stimulation without the need to apply an external gate voltage, achieving an active mechanical tuning of synaptic plasticity such as excitatory postsynaptic current, paired-pulse facilitation, short-term plasticity, and long-term plasticity. The STMAS exhibits stable synaptic plasticity under 0–50% stretcher strain in parallel and vertical to channel directions, respectively. Furthermore, the International Morse code triggered by mechanical signals has been successfully mimicked. This work has achieved an intrinsically stretchable tribotronic artificial synapse with mechanically tuned synaptic behavior, which will help promote the development of artificial nervous systems and expand the applications of artificial synapses in intelligent robotics, artificial limbs and human–machine interaction.
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