| 1. |
- Hou, Yandong, et al.
(författare)
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Numerical study on surface corrosion deposition of fuel elements and its influence on flow heat transfer
- 2024
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Ingår i: Annals of Nuclear Energy. - : Elsevier BV. - 0306-4549 .- 1873-2100. ; 201
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Tidskriftsartikel (refereegranskat)abstract
- Corrosion of pressurized water reactors (PWR) in nuclear power plants can lead to serious safety hazards. This study aims to analyze the deposition of corrosion products using FLUENT software. Deposition models and thermal resistance models were developed, and the effects of deposits on the reactor's thermal–hydraulic characteristics were evaluated. Additionally, the impact of various parameters on deposition and thermal–hydraulic characteristics was examined. Results show that deposits accumulate extensively in the inlet section of the fuel cladding, while appearing as spot deposits in the outlet section. For deposit thicknesses below 30 μm, the surface temperature of the cladding gradually increases. However, when the thickness exceeds 30 μm, the surface temperature rapidly rises. Furthermore, the study reveals that the deposition amount decreases with increasing inlet flow velocity, exhibits an upward trend with higher inlet temperature, and increases with a higher wall heat flux density. This research provides important insights for understanding core deposition and thermal–hydraulic characteristics in nuclear reactor systems. It offers valuable guidance for enhancing safety and operational efficiency in nuclear power plants.
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| 2. |
- Dang, Dongfeng, 1988, et al.
(författare)
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Enhanced Photovoltaic Performance of Indacenodithiophene-Quinoxaline Copolymers by Side- Chain Modulation
- 2014
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Ingår i: Advanced Energy Materials. - : Wiley. - 1614-6840 .- 1614-6832. ; 4:15, s. Art. no. 1400680-
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Tidskriftsartikel (refereegranskat)abstract
- Two pairs of indacenodithiophene (IDT) and quinoxaline-based copolymers with meta- or para-hexyl-phenyl side chains on the IDT unit are synthesized. The meta-substituted polymers offer better solubility, higher molecular weight for both fluorinated and non-fluorinated copolymers, and a superior photovoltaic performance with a power conversion efficiency of 7.8%. The side-chain design strategy presented is an efficient way to produce high performance conjugated polymers for organic electronics.
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| 3. |
- Hou, Yandong, et al.
(författare)
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Characteristics of heat transfer in corrosion products deposited on the surface of pressurized water reactor fuel elements
- 2024
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Ingår i: Applied Thermal Engineering. - : Elsevier BV. - 1359-4311 .- 1873-5606. ; 257
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Tidskriftsartikel (refereegranskat)abstract
- The occurrence of porous deposits on the core surface during the operation of a pressurized water reactor can seriously affect its heat transfer characteristics and increase the surface temperature of the cladding. Continued heat transfer deterioration causes subcooled boiling and boron enrichment within porous deposits, leading to axial power anomalies in the core, and the study of porous deposits is beneficial to improving the economics and safety of reactor operation. In this paper, a two-dimensional boiling unit model of a porous deposits was established using COMSOL software to couple heat conduction, darcy flow, solute transport and chemical reactions in a multiphysics field to reasonably predict the temperature field, velocity field, boric acid concentration distribution, and PH distribution within the porous deposits. On this basis, the influence of different parameters (porosity, boiling unit radius of porous deposits, heat flow density) on the maximum effective thermal conductivity, the pattern of thermal parameters (temperature, superheat, percentage of subcooled boiling, and saturation temperature) on the chimney boundary are analyzed. The results show that localized superheating, maximum boric acid concentration and subcooled boiling occur at the bottom of the porous deposits. There is a negative correlation between the porosity and the percentage of subcooled boiling area, and a positive correlation between the radius of the porous deposits and the heat flow density and the percentage of subcooled boiling area.
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| 4. |
- Jiang, Huanxiang, et al.
(författare)
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Appropriate Molecular Interaction Enabling Perfect Balance Between Induced Crystallinity and Phase Separation for Efficient Photovoltaic Blends
- 2020
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Ingår i: ACS Applied Materials and Interfaces. - : American Chemical Society. - 1944-8244 .- 1944-8252. ; 12:23, s. 26286-26292
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Tidskriftsartikel (refereegranskat)abstract
- Fluorination is a promising modification method to adjust the photophysical profiles of organic semiconductors. Notably, the fluorine modification on donor or acceptor materials could impact the molecular interaction, which is strongly related to the morphology of bulk heterojunction (BHJ) blends and the resultant device performance. Therefore, it is essential to investigate how the molecular interaction affects the morphology of BHJ films. In this study, a new fluorinated polymer PBDB-PSF is synthesized to investigate the molecular interaction in both nonfluorinated (ITIC) and fluorinated (IT-4F) systems. The results reveal that the F-F interaction in the PBDB-PSF:IT-4F system could effectively induce the crystallization of IT-4F while retaining the ideal phase separation scale, resulting in outstanding charge transport. On the contrary, poor morphology can be observed in the PBDB-PSF:ITIC system because of the unbalanced molecular interaction. As a consequence, the PBDB-PSF:IT-4F device delivers an excellent power conversion efficiency of 13.63%, which greatly exceeds that of the PBDB-PSF:ITIC device (9.84%). These results highlight manipulating the micromorphology with regard to molecular interaction.
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| 5. |
- Wang, Weichao, et al.
(författare)
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Remarkably enhanced hybrid piezo/triboelectric nanogenerator via rational modulation of piezoelectric and dielectric properties for self-powered electronics
- 2020
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 116:2
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Tidskriftsartikel (refereegranskat)abstract
- The hybridization of different materials for energy scavenging techniques based on piezoelectric and triboelectric effects has been studied widely for various applications of nanogenerators. However, there are few reports utilizing the same oxide matrix materials with appropriate doping to simultaneously enhance the piezoelectric and triboelectric outputs. Herein, a hybrid nanogenerator (HG) consisting of a piezoelectric nanogenerator (PENG) and a triboelectric nanogenerator (TENG) was constructed using (Ba0.838Ca0.162)(Ti0.9072Zr0.092)O3 (BCZTO)/polydimethylsiloxane (PDMS) as a piezoelectric layer and Ba(Ti0.8Zr0.2)O3 (BZTO)/PDMS as a triboelectric layer. For the PENG, how the electrical output was related to the BCZTO ratio in the BCZTO/PDMS composite films was systematically investigated. For the TENG, remarkably enhanced output performance is attributed to the ferroelectric polarization and large permittivity of the BZTO/PDMS. The Kelvin probe force microscopy measurements show that the poled BZTO/PDMS composite film with a 20 wt. % mass ratio of BZTO has the highest surface charge potential, in line with the macroscopic electrical outputs of the TENG. Interestingly, the output performance of the PENG in the HG is significantly enhanced compared to the PENG acting alone, which is also verified by COMSOL simulation. After rectification, the HG can produce a maximum output voltage of 390 V and a current density of 47 mA/m2. This work not only provides a feasible solution to enhance the output performance of the HG but also offers an effective approach to develop a small, portable power source with promising application in self-powered electronics.
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| 6. |
- Wu, Xiuchen, et al.
(författare)
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Exposures to temperature beyond threshold disproportionately reduce vegetation growth in the northern hemisphere
- 2019
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Ingår i: National Science Review. - : Oxford University Press (OUP). - 2095-5138 .- 2053-714X. ; 6:4, s. 786-795
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Tidskriftsartikel (refereegranskat)abstract
- In recent decades, terrestrial vegetation in the northern hemisphere (NH) has been exposed to warming and more extremely high temperatures. However, the consequences of these changes for terrestrial vegetation growth remain poorly quantified and understood. By examining a satellite-based vegetation index, tree-ring measurements and land-surface model simulations, we discovered a consistent convex pattern in the responses of vegetation growth to temperature exposure (TE) for forest, shrub and grass in both the temperate (30°−50° N) and boreal (50°−70° N) NH during the period of 1982−2012. The response of vegetation growth to TE for the three vegetation types in both the temperate and boreal NH increased convergently with increasing temperature, until vegetation type-dependent temperature thresholds were reached. A TE beyond these temperature thresholds resulted in disproportionately weak positive or even strong negative responses. Vegetation growth in the boreal NH was more vulnerable to extremely high-temperature events than vegetation growth in the temporal NH. The non-linear responses discovered here provide new insights into the dynamics of northern terrestrial ecosystems in a warmer world.
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