| 1. |
- Aiuppa, A., et al.
(author)
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Gas measurements from the Costa Rica-Nicaragua volcanic segment suggest possible along-arc variations in volcanic gas chemistry
- 2014
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In: Earth and Planetary Science Letters. - : Elsevier BV. - 1385-013X .- 0012-821X. ; 407, s. 134-147
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Journal article (peer-reviewed)abstract
- Obtaining accurate estimates of the CO2 output from arc volcanism requires a precise understanding of the potential along-arc variations in volcanic gas chemistry, and ultimately of the magmatic gas signature of each individual arc segment. In an attempt to more fully constrain the magmatic gas signature of the Central America Volcanic Arc (CAVA), we present here the results of a volcanic gas survey performed during March and April 2013 at five degassing volcanoes within the Costa Rica-Nicaragua volcanic segment (CNVS). Observations of the volcanic gas plume made with a multicomponent gas analyzer system (Multi-GAS) have allowed characterization of the CO2/SO2-ratio signature of the plumes at Pads (0.30 +/- 0.06, mean +/- SD), Rincon de la Vieja (27.0 +/- 15.3), and Turrialba (2.2 +/- 0.8) in Costa Rica, and at Telica (3.0 +/- 0.9) and San Cristobal (4.2 +/- 1.3) in Nicaragua (all ratios on molar basis). By scaling these plume compositions to simultaneously measured SO2 fluxes, we estimate that the CO2 outputs at CNVS volcanoes range from low (25.5 +/- 11.0 tons/day at Pods) to moderate (918 to 1270 tons/day at Turrialba). These results add a new information to the still fragmentary volcanic CO2 output data set, and allow estimating the total CO2 output from the CNVS at 2835 1364 tons/day. Our novel results, with previously available information about gas emissions in Central America, are suggestive of distinct volcanic gas CO2/S-T (= SO2 + H2S)-ratio signature for magmatic volatiles in Nicaragua (similar to 3) relative to Costa Rica (similar to 0.5-1.0). We also provide additional evidence for the earlier theory relating the CO2-richer signature of Nicaragua volcanism to increased contributions from slab-derived fluids, relative to more-MORB-like volcanism in Costa Rica. The sizeable along-arc variations in magmatic gas chemistry that the present study has suggested indicate that additional gas observations are urgently needed to more-precisely confine the volcanic CO2 from the CAVA, and from global arc volcanism.
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| 2. |
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| 3. |
- Arellano, Santiago, 1981, et al.
(author)
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Synoptic analysis of a decade of daily measurements of SO2 emission in the troposphere from volcanoes of the global ground-based Network for Observation of Volcanic and Atmospheric Change
- 2021
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In: Earth System Science Data. - : Copernicus GmbH. - 1866-3516 .- 1866-3508. ; 13:3, s. 1167-1188
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Journal article (peer-reviewed)abstract
- Volcanic plumes are common and far-reaching manifestations of volcanic activity during and between eruptions. Observations of the rate of emission and composition of volcanic plumes are essential to recognize and, in some cases, predict the state of volcanic activity. Measurements of the size and location of the plumes are important to assess the impact of the emission from sporadic or localized events to persistent or widespread processes of climatic and environmental importance. These observations provide information on volatile budgets on Earth, chemical evolution of magmas, and atmospheric circulation and dynamics. Space-based observations during the last decades have given us a global view of Earth's volcanic emission, particularly of sulfur dioxide (SO2). Although none of the satellite missions were intended to be used for measurement of volcanic gas emission, specially adapted algorithms have produced time-averaged global emission budgets. These have confirmed that tropospheric plumes, produced from persistent degassing of weak sources, dominate the total emission of volcanic SO2. Although space-based observations have provided this global insight into some aspects of Earth's volcanism, it still has important limitations. The magnitude and short-term variability of lower-atmosphere emissions, historically less accessible from space, remain largely uncertain. Operational monitoring of volcanic plumes, at scales relevant for adequate surveillance, has been facilitated through the use of ground-based scanning differential optical absorption spectrometer (ScanDOAS) instruments since the beginning of this century, largely due to the coordinated effort of the Network for Observation of Volcanic and Atmospheric Change (NOVAC). In this study, we present a compilation of results of homogenized post-analysis of measurements of SO2 flux and plume parameters obtained during the period March 2005 to January 2017 of 32 volcanoes in NOVAC. This inventory opens a window into the short-term emission patterns of a diverse set of volcanoes in terms of magma composition, geographical location, magnitude of emission, and style of eruptive activity. We find that passive volcanic degassing is by no means a stationary process in time and that large sub-daily variability is observed in the flux of volcanic gases, which has implications for emission budgets produced using short-term, sporadic observations. The use of a standard evaluation method allows for intercomparison between different volcanoes and between ground- and space-based measurements of the same volcanoes. The emission of several weakly degassing volcanoes, undetected by satellites, is presented for the first time. We also compare our results with those reported in the literature, providing ranges of variability in emission not accessible in the past. The open-access data repository introduced in this article will enable further exploitation of this unique dataset, with a focus on volcanological research, risk assessment, satellite-sensor validation, and improved quantification of the prevalent tropospheric component of global volcanic emission. Datasets for each volcano are made available at https://novac.chalmers.se (last access: 1 October 2020) under the CC-BY 4 license or through the DOI (digital object identifier) links provided in Table 1.
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| 4. |
- Boikos, Christos, et al.
(author)
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Validating CFD modelling of ship plume dispersion in an urban environment with pollutant concentration measurements
- 2024
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In: Atmospheric Environment. - 1873-2844 .- 1352-2310. ; 319
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Journal article (peer-reviewed)abstract
- Air pollution in urban areas constitutes a global environmental problem, with shipping being one major contributor to hazardous pollutants in harbour areas. This work concerns the application of a method using CFD modelling to study how ships affect the air quality of port areas at a microscale level. A steady RANS-CFD approach was applied to simulate the dispersion of shipping-emitted pollutants, and a spatial sensitivity analysis of the CFD modelling results was conducted. The port of Marseille was used as a case study, and the CFD predictions were compared with on-site observations from two monitoring stations for CO2, CO, NOx, SO2 and PM concentrations. Representative modelled and measured concentrations were considered at the location of the monitoring stations to facilitate one-by-one comparisons for all pollutants in three different test cases of departing vessels. The modelling predictions presented an 8.2% (95% CI: -9.3%, 25.7%) average deviation from the measurements. Validation metrics were included to conduct a statistical comparison between predicted and measured concentrations, with almost all metric values indicating acceptable agreement between the CFD model and measurements. From a technical perspective, this study demonstrates the reliability of the applied CFD modelling method in estimating shipping plume dispersion, while from a societal perspective, this model can serve as an advisory tool for port authorities and policy makers to reduce the impact of shipping emissions on urban air quality.
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| 5. |
- Conde Jacobo, Alexander Vladimir, 1979, et al.
(author)
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A rapid deployment instrument network for temporarily monitoring volcanic SO2 emissions - a study case from Telica volcano
- 2014
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In: Geoscientific Instrumentation, Methods and Data Systems. - : Copernicus GmbH. - 2193-0856 .- 2193-0864. ; 3:2, s. 127-134
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Journal article (peer-reviewed)abstract
- Volcanic gas emissions play a crucial role in describing geophysical processes; hence measurements of magmatic gases such as SO2 can be used as tracers prior and during volcanic crises. Different measurement techniques based on optical spectroscopy have provided valuable information when assessing volcanic crises. This paper describes the design and implementation of a network of spectroscopic instruments based on Differential Optical Absorption Spectroscopy (DOAS) for remote sensing of volcanic SO2 emissions, which is robust, portable and can be deployed in relative short time. The setup allows the processing of raw data in situ even in remote areas with limited accessibility, and delivers pre-processed data to end-users in near real time even during periods of volcanic crisis, via a satellite link. In addition, the hardware can be used to conduct short term studies of volcanic plumes in remotes areas. The network was tested at Telica, an active volcano located in western Nicaragua, producing what is so far the largest data set of continuous SO2 flux measurements at this volcano.
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| 6. |
- Conde Jacobo, Alexander Vladimir, 1979
(author)
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Application of DOAS for Studies of Evolving Volcanic Activity in Central America
- 2012
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Licentiate thesis (other academic/artistic)abstract
- Volcanic gas emissions play a critical role in understanding the physical processes that drive eruptive activity. Combining gas measurements with other geophysical parameters provides a more accurate description of the changes that occur beneath a volcano. Understanding and tracking the evolution of volcanic activity is crucial for populated areas that may be affected by a potential eruptive crisis.This thesis illustrates the application of ground-based optical remote sensing using Differential Optical Absorption Spectroscopy (DOAS) for measuring volcanic gas emissions. Some measurements have been made within a range of several days to a few weeks, while in some cases we made measurements for more than one year. The case studies include the following volcanoes: Turrialba (Costa Rica), Concepción (Nicaragua), Arenal (Costa Rica), and Télica (Nicaragua).At Turrialba volcano the measured SO2 flux emissions clearly indicated an imminent eruptive event. The volcano’s degassing evolution during different periods was extensively compared with the most relevant seismic signatures. At Concepción volcano our measurements were related to seismic and geodesic indicators during an active eruptive period and a quiescent period. Preliminary results of ongoing measurements at Télica and Arenal volcano are also reported.Different comparisons in different scenarios provide multi-parametric surveillance methods that may be adopted by local institutions in charge of dealing with volcanic risk assessment.
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| 7. |
- Conde Jacobo, Alexander Vladimir, 1979, et al.
(author)
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Linking SO2 emission rates and seismicity by continuous wavelet transform: implications for volcanic surveillance at San Cristbal volcano, Nicaragua
- 2016
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In: International Journal of Earth Sciences. - : Springer Science and Business Media LLC. - 1437-3262 .- 1437-3254. ; 105:5, s. 1453-1465
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Journal article (peer-reviewed)abstract
- San Cristbal volcano is the highest and one of the most active volcanoes in Nicaragua. Its persistently high activity during the past decade is characterized by strong degassing and almost annual VEI 1-2 explosions, which present a threat to the local communities. Following an eruption on 8 September 2012, the intervals between eruptions decreased significantly, which we interpret as the start of a new eruptive phase. We present here the results of semi-continuous SO2 flux measurements covering a period of 18 months, obtained by two scanning UV-DOAS instruments installed as a part of the network for observation of volcanic and atmospheric change project, and the results of real-time seismic amplitude measurements (RSAM) data. Our data comprise a series of small to moderately explosive events in December 2012, June 2013 and February 2014, which were accompanied by increased gas emissions and seismicity. In order to approach an early warning strategy, we present a statistical method for the joint analysis of gas flux and seismic data, by using continuous wavelet transform and cross-wavelet transform (XWT) methods. This analysis shows that the XWT coefficients of SO2 flux and RSAM are in good agreement with the occurrence of eruptive events and thus may be used to indicate magma ascent into the volcano edifice. Such multi-parameter surveillance efforts can be useful for the interpretation and surveillance of possible eruptive events and could thus be used by local institutions for the prediction of upcoming volcanic unrest.
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| 8. |
- Conde Jacobo, Alexander Vladimir, 1979, et al.
(author)
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Measurements of volcanic SO2 and CO2 fluxes by combined DOAS, Multi-GAS and FTIR observations: a case study from Turrialba and Telica volcanoes
- 2014
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In: International Journal of Earth Sciences. - : Springer Science and Business Media LLC. - 1437-3262 .- 1437-3254. ; 103:8, s. 2335-2347
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Journal article (peer-reviewed)abstract
- Over the past few decades, substantial progress has been made to overcome the technical difficulties of continuously measuring volcanic SO2 emissions. However, measurements of CO2 emissions still present many difficulties, partly due to the lack of instruments that can directly measure CO2 emissions and partly due to its strong atmospheric background. In order to overcome these difficulties, a commonly taken approach is to combine differential optical absorption spectroscopy (DOAS) by using NOVAC scan-DOAS instruments for continuous measurements of crateric SO2 emissions, and electrochemical/NDIR multi-component gas analyser system (multi-GAS) instruments for measuring CO2/SO2 ratios of excerpts of the volcanic plume. This study aims to quantify the representativeness of excerpts of CO2/SO2 ratios measured by Multi-GAS as a fraction of the whole plume composition, by comparison with simultaneously measured CO2/SO2 ratios using cross-crater Fourier transform infrared spectroscopy (FTIR). Two study cases are presented: Telica volcano (Nicaragua), with a homogenous plume, quiescent degassing from a deep source and ambient temperature, and Turrialba volcano (Costa Rica), which has a non-homogeneous plume from three main sources with different compositions and temperatures. Our comparison shows that in our "easier case" (Telica), FTIR and Multi-GAS CO2/SO2 ratios agree within a factor about 3 %. In our "complicated case" (Turrialba), Multi-GAS and FTIR yield CO2/SO2 ratios differing by approximately 13-25 % at most. These results suggest that a fair estimation of volcanic CO2 emissions can be provided by the combination of DOAS and Multi-GAS instruments for volcanoes with similar degassing conditions as Telica or Turrialba. Based on the results of this comparison, we report that by the time our measurements were made, Telica and Turrialba were emitting approximately 100 and 1,000 t day(-1) of CO2, respectively.
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| 9. |
- Conde Jacobo, Alexander Vladimir, 1979, et al.
(author)
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SO2 degassing from Turrialba Volcano linked to seismic signatures during the period 2008-2012
- 2014
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In: International Journal of Earth Sciences. - : Springer Science and Business Media LLC. - 1437-3262 .- 1437-3254. ; 103:7, s. 1983-1998
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Journal article (peer-reviewed)abstract
- wIn 1996, after 150 years of relative calm, Turrialba Volcano was reawakening. A visible plume and serious damage to surrounding vegetation due to acid rain are the most obvious signals. As part of the Network for Observation of Volcanic and Atmospheric Change project, four gas-monitoring stations were initially installed on the west flank of the volcano with the purpose of measuring sulphur dioxide emissions during this period of increased activity using the scanning-differential optical absorption spectroscopy technique. We present here the results of semicontinuous gas flux measurements over a period of 5 years (from 2008 to 2012), providing a novel data set that documents a relatively rapid increase in SO2 fluxes from around 350 t day(-1) to around 4,000 t day(-1) leading up to an eruptive period, followed by a gradual return to the former baseline values. Gas flux data were also compared with seismic data for selected periods of interest, providing insights into the link between degassing and seismicity. The most important result from this comparison is the identification of an inflexion point in the gas emissions followed by a clearly increasing trend in seismic activity, distinguishable 6 months prior to a phreatic eruptive event that occurred on 5 January 2010. This signal can be interpreted as a possible indicator of future eruptive events. Monitoring of SO2 thus complements seismic monitoring as a forecasting tool for eruptive events. Such monitoring is critical considering the proximity of Turrialba to the Central Valley, an area inhabited by more than 50 % of Costa Rica's population.
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| 10. |
- De Moor, J. M., et al.
(author)
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Turmoil at Turrialba Volcano (Costa Rica): Degassing and eruptive processes inferred from high-frequency gas monitoring
- 2016
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In: Journal of Geophysical Research. - : American Geophysical Union (AGU). - 0148-0227 .- 2156-2202 .- 2169-9313. ; 121:8, s. 5761-5775
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Journal article (peer-reviewed)abstract
- Eruptive activity at Turrialba Volcano (Costa Rica) has escalated significantly since 2014, causing airport and school closures in the capital city of San Jose. Whether or not new magma is involved in the current unrest seems probable but remains a matter of debate as ash deposits are dominated by hydrothermal material. Here we use high-frequency gas monitoring to track the behavior of the volcano between 2014 and 2015 and to decipher magmatic versus hydrothermal contributions to the eruptions. Pulses of deeply derived CO2-rich gas (CO2/S-total>4.5) precede explosive activity, providing a clear precursor to eruptive periods that occurs up to 2weeks before eruptions, which are accompanied by shallowly derived sulfur-rich magmatic gas emissions. Degassing modeling suggests that the deep magmatic reservoir is similar to 8-10km deep, whereas the shallow magmatic gas source is at similar to 3-5km. Two cycles of degassing and eruption are observed, each attributed to pulses of magma ascending through the deep reservoir to shallow crustal levels. The magmatic degassing signals were overprinted by a fluid contribution from the shallow hydrothermal system, modifying the gas compositions, contributing volatiles to the emissions, and reflecting complex processes of scrubbing, displacement, and volatilization. H2S/SO2 varies over 2 orders of magnitude through the monitoring period and demonstrates that the first eruptive episode involved hydrothermal gases, whereas the second did not. Massive degassing (>3000T/d SO2 and H2S/SO2>1) followed, suggesting boiling off of the hydrothermal system. The gas emissions show a remarkable shift to purely magmatic composition (H2S/SO2
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