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| 2. |
- Alekseeva, L. A., et al.
(författare)
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Determination of the low-temperature self-diffusion coefficient in solid p-H-2 from creep experiments
- 2018
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - : American Institute of Physics (AIP). - 1063-777X .- 1090-6517. ; 44:9, s. 946-951
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Tidskriftsartikel (refereegranskat)abstract
- Dependencies of the relative elongation epsilon under the constantly applied stress at T = 1.8 K on the endurance time t of polycrystalline parahydrogen (p-H-2, similar to 0.2% of o-H-2) of high purity (99.9999 mol.%), with varying deuterium content, were measured. The region of linear dependence between the measured creep rates (epsilon) over dot of samples and the applied stress s was revealed. The conclusion that the low-temperature creep of the studied p-H-2 possesses a vacancy-type diffusion character was made on the basis of linear dependence (epsilon) over dot similar to s. Determination of the low-temperature self-diffusion coefficient of vacancies D in solid p-H-2, which characterizes the rate of low-temperature mass transfer, was performed. The cases of migration of vacancies in the crystal bulk, along boundaries separating individual crystallites, as well as between dislocations existing in crystals, are considered. A significant decrease in the (epsilon) over dot and D values with an increase in the isotope concentration in the samples was observed, while maintaining the linear relationship between (epsilon) over dot and s for the studied p-H-2. Published by AIP Publishing.
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| 3. |
- Alekseeva, L.A., et al.
(författare)
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Unusual changes in the shape of solid parahydrogen with higher than natural isotope content
- 2016
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Ingår i: Low temperature physics (Woodbury, N.Y., Print). - : AIP Publishing. - 1063-777X .- 1090-6517. ; 42:6, s. 484-490
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Tidskriftsartikel (refereegranskat)abstract
- The relative elongation epsilon of samples of high purity (99.9999 mol. % with respect to nonhydrogenic impurities) parahydrogen (p-H-2, similar to 0.2% o-H-2) with different amounts of the stable hydrogen isotope deuterium is measured as a function of applied stress sigma at temperatures of 1.8-4.2 K. The samples were subjected to uniaxial tension by stepwise loading. The ratio [D]/[H] of the number [D] of deuterium atoms to the number [H] of p-H-2 hydrogen atoms ranged from 0.0055 +/- 0.0005 at. % up to 0.07 at. %. For deuterium enriched p-H-2, the easy slip dislocation stage vanished from the sigma(epsilon) curves and there was a significant reduction in the total relative elongation of the samples, as well as a substantial increase in the hardening coefficient d sigma/d epsilon. Deformation of samples of p-H-2 with deuterium contents higher than the natural amount produces an unusual change in their shape owing to the appearance of a rotational component of the low-temperature plastic mass transfer
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| 4. |
- Antikhovich, I. V., et al.
(författare)
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Corrosion Resistance of Nickel Coatings Deposited from Low-Temperature Nickel-Plating Electrolytes
- 2017
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Ingår i: Russian journal of applied chemistry. - : Maik Nauka/Interperiodica. - 1070-4272 .- 1608-3296. ; 90:4, s. 566-573
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Tidskriftsartikel (refereegranskat)abstract
- The corrosion resistance of nickel coatings on a copper substrate, plated from low-temperature electrolytes based on acetates, tartrates, and isobutyrates, was studied by the methods of electrochemical impedance spectroscopy (EIS) and polarization curves. The tests were performed in a 0.3% NaCl solution. The nickel coatings exhibit high chemical activity, dissolving in the NaCl solution. The electrochemical step is the limiting step of the corrosion process.
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| 5. |
- Attias, Noam, et al.
(författare)
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Biofabrication of Nanocellulose–Mycelium Hybrid Materials
- 2021
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Ingår i: Advanced Sustainable Systems. - : Wiley-VCH Verlag. - 2366-7486. ; 5:2
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Tidskriftsartikel (refereegranskat)abstract
- Healthy material alternatives based on renewable resources and sustainable technologies have the potential to disrupt the environmentally damaging production and consumption practices established throughout the modern industrial era. In this study, a mycelium–nanocellulose biocomposite with hybrid properties is produced by the agitated liquid culture of a white-rot fungus (Trametes ochracea) with nanocellulose (NC) comprised as part of the culture media. Mycelial development proceeds via the formation of pellets, where NC is enriched in the pellets and depleted from the surrounding liquid media. Micrometer-scale NC elements become engulfed in mycelium, whereas it is hypothesized that the nanometer-scale fraction becomes integrated within the hyphal cell wall, such that all NC in the system is essentially surface-modified by mycelium. The NC confers mechanical strength to films processed from the biocomposite, whereas the mycelium screens typical cellulose–water interactions, giving fibrous slurries that dewater faster and films that exhibit significantly improved wet resistance in comparison to pure NC films. The mycelium–nanocellulose biocomposites are processable in the ways familiar to papermaking and are suggested for diverse applications, including packaging, filtration, and hygiene products.
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| 6. |
- Bhuiyan, Iftekhar Uddin, et al.
(författare)
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Microstructure of Bentonite in Iron Ore Green Pellets
- 2014
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Ingår i: Microscopy and Microanalysis. - 1431-9276 .- 1435-8115. ; 20:1, s. 33-41
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Tidskriftsartikel (refereegranskat)abstract
- Sodium-activated calcium bentonite is used as a binder in iron ore pellets and is known to increase strength of both wet and dry iron ore green pellets. In this article, the microstructure of bentonite in magnetite pellets is revealed for the first time using scanning electron microscopy. The microstructure of bentonite in wet and dry iron ore pellets, as well as in distilled water, was imaged by various imaging techniques (e.g., imaging at low voltage with monochromatic and decelerated beam or low loss backscattered electrons) and cryogenic methods (i.e., high pressure freezing and plunge freezing in liquid ethane). In wet iron ore green pellets, clay tactoids (stacks of parallel primary clay platelets) were very well dispersed and formed a voluminous network occupying the space available between mineral particles. When the pellet was dried, bentonite was drawn to the contact points between the particles and formed solid bridges, which impart strength to the solid compact.
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| 7. |
- Borgani, Riccardo, et al.
(författare)
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Background-Force Compensation in Dynamic Atomic Force Microscopy
- 2017
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Ingår i: Physical Review Applied. - : AMER PHYSICAL SOC. - 2331-7019. ; 7:6
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Tidskriftsartikel (refereegranskat)abstract
- Background forces are linear long-range interactions of the cantilever body with its surroundings that must be compensated for in order to reveal tip-surface force, the quantity of interest for determining material properties in atomic force microscopy. We provide a mathematical derivation of a method to compensate for background forces, apply it to experimental data, and discuss how to include background forces in simulation. Our method, based on linear-response theory in the frequency domain, provides a general way of measuring and compensating for any background force and it can be readily applied to different force reconstruction methods in dynamic AFM.
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| 8. |
- Claesson, Per M., et al.
(författare)
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From force curves to surface nanomechanical properties
- 2017
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Ingår i: Physical Chemistry, Chemical Physics - PCCP. - : Royal Society of Chemistry. - 1463-9076 .- 1463-9084. ; 19:35, s. 23642-23657
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Tidskriftsartikel (refereegranskat)abstract
- Surface science, which spans the fields of chemistry, physics, biology and materials science, requires information to be obtained on the local properties and property variations across a surface. This has resulted in the development of different scanning probe methods that allow the measurement of local chemical composition and local electrical and mechanical properties. These techniques have led to rapid advancement in fundamental science with applications in areas such as composite materials, corrosion protection and wear resistance. In this perspective article, we focussed on the branch of scanning probe methods that allows the determination of surface nanomechanical properties. We discussed some different AFM-based modes that were used for these measurements and provided illustrative examples of the type of information that could be obtained. We also discussed some of the difficulties encountered during such studies.
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| 9. |
- Claesson, Per M., et al.
(författare)
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Surface Nanomechanics of Coatings and Hydrogels
- 2019
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Ingår i: IOP Conference Series. - : Institute of Physics Publishing.
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Konferensbidrag (refereegranskat)abstract
- Due to the increasing use of nanostructured materials and thin coatings as barrier materials, it has become of high importance to measure and understand material properties on the nm to 100 nm length scales. In this article we demonstrate and discuss how atomic force microscopy techniques can be used to this end. It is demonstrated that the classical analysis based on the assumption of a purely elastic material response is a fair approximation for relatively stiff coatings (elastic modulus order of GPa), whereas viscous responses must be considered for soft materials (apparent modulus order of MPa) such as hydrogels.
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| 10. |
- Demidova, S. I., et al.
(författare)
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A micrometeorite from a stony asteroid identified in Luna 16 soil
- 2022
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Ingår i: Nature Astronomy. - : Springer Science and Business Media LLC. - 2397-3366. ; 6:5, s. 560-567
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Tidskriftsartikel (refereegranskat)abstract
- Despite the intense cratering history of the Moon, very few traces of meteoritic material have been identified in the more than 380 kg of samples returned to Earth by the Apollo and Luna missions. Here we show that an ~200-µm-sized fragment collected by the Luna 16 mission has extra-lunar origins and probably originates from an LL chondrite with similar properties to near-Earth stony asteroids. The fragment has not experienced temperatures higher than 400 °C since its protolith formed early in the history of the Solar System. It arrived on the Moon, either as a micrometeorite or as the result of the break-up of a bigger impact, no earlier than 3.4 Gyr ago and possibly around 1 Gyr ago, an age that would be consistent with impact ages inferred from basaltic fragments in the Luna 16 sample and of a known dynamic upheaval in the Flora asteroid family, which is thought to be the source of L and LL chondrite meteorites. These results highlight the importance of extra-lunar fragments in constraining the impact history of the Earth–Moon system and suggest that material from LL chondrite asteroids may be an important component.
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