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- Nordstrand, Johan
(författare)
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At the Mountains of Modeling : Multiscale Simulations of Desalination by Capacitive Deionization
- 2022
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- More than 2 billion people are living in water-scarce areas. Meanwhile, there are enormous amounts of water in the salty oceans. Capacitive deionization (CDI) rises to the challenge with electrochemical cells for desalinating the water. As the CDI field expands, modeling becomes an increasingly important part of the development landscape. Multiscale modeling could bring innovations from the material scale to pilot plants. The multiscale work in this thesis has been like climbing a mountain. At the start, we investigate the macroscopic device level. One milestone is the electrolytic-capacitor (ELC) model, which can simulate CDI process dynamics. Whereas previous 2D models were unsteady for a single CDIcell, the ELC model could accurately simulate stacks of over 100 cells at a fraction of the time. It also enables simulations of complex upscaled geometries, such as bipolar electrode stacks, ohmic charging, and asymmetric devices. Going up the mountain, the mesoscopic level reveals the local mechanisms behind the macroscopic behavior. One important stepping stone is the dynamic Langmuir (DL) model, which reveals how isotherm-based modeling can crease stable and tractable simulations. Also, developments in isotherm, double-layer, and circuit modeling make it possible to choose what model structures to lean on depending on the conditions. Near the top of the mountain, the microscopic level shows the fundamental atomic mechanisms behind the mesoscopic material properties. These investigations reveal a ladder mechanism of ion transport in crystals of Prussian blue analogs (PBA), meaning the cations climb frames formed by negative groups in the crystal structure.In the end, we plant a flag by combining the developments from the journey into a complete multiscale model. That model demonstrated that we could predict CDI charging trends from the atomic structure of PBA electrodes. Having the full multiscale model also made it possible to backtrack and determine atomic-level mechanisms by comparing the output of different mechanism cases with macroscopic experiment data. The multiscale mountain is massive and has big potential. A dream is that future research will expand these concepts, in CDI and beyond.
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- Abiso, Ahmad Muhammad, et al.
(författare)
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Advances in copper-based catalysts for sustainable hydrogen production via methanol steam reforming
- 2024
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Ingår i: Chemical Engineering Journal Advances. - : Elsevier BV. - 2666-8211. ; 19
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Forskningsöversikt (refereegranskat)abstract
- Efficient hydrogen production through Methanol Steam Reforming (MSR) is an area of high importance due to its environmental suitability and superior energy efficiency compared to methane steam reforming. Therefore, we present a comprehensive investigation into the development of copper-based catalysts for MSR. Over the past decades, research in this domain has intensified, encompassing Cu-based catalysts that exhibit notable promise. Strategies to enhance catalytic activity and stability involve the utilisation of mesoporous support materials with tuneable properties, novel promoters, and the introduction of mixed oxides and metal organic framework amongst others. Furthermore, the paper underscores the significance of catalyst morphology and metal precursors in determining their final performance. Several new catalysts have shown remarkable selectivity for hydrogen while minimizing carbon monoxide production even at elevated temperatures, positioning them as strong candidates for environmentally friendly commercial hydrogen production through methanol steam reforming. Valuable insights into synthesis approaches and catalyst performance variations across different research groups are also presented.
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- Al-Abri, M., et al.
(författare)
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Chlorination disadvantages and alternative routes for biofouling control in reverse osmosis desalination
- 2019
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Ingår i: npj Clean Water. - : Nature Research. - 2059-7037. ; 2:1
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Tidskriftsartikel (refereegranskat)abstract
- With an ever-increasing human population, access to clean water for human use is a growing concern across the world. Seawater desalination to produce usable water is essential to meet future clean water demand. Desalination processes, such as reverse osmosis and multi-stage flash have been implemented worldwide. Reverse osmosis is the most effective technology, which uses a semipermeable membrane to produce clean water under an applied pressure. However, membrane biofouling is the main issue faced by such plants, which requires continuous cleaning or regular replacement of the membranes. Chlorination is the most commonly used disinfection process to pretreat the water to reduce biofouling. Although chlorination is widely used, it has several disadvantages, such as formation of disinfection by-products and being ineffective against some types of microbes. This review aims to discuss the adverse effect of chlorination on reverse osmosis membranes and to identify other possible alternatives of chlorination to reduce biofouling of the membranes. Reverse osmosis membrane degradation and mitigation of chlorines effects, along with newly emerging disinfection technologies, are discussed, providing insight to both academic institutions and industries for the design of improved reverse osmosis systems.
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6. |
- Al-Soubaihi, Rola, et al.
(författare)
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Comparative investigation of structure and operating parameters on the performance and reaction dynamic of CO conversion on silica aerogel and fumed-silica-supported Pd catalysts
- 2022
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Ingår i: SURFACES AND INTERFACES. - : Elsevier BV. - 2468-0230. ; 29, s. 101776-
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Tidskriftsartikel (refereegranskat)abstract
- The catalyst morphology, metal-support interaction, and reaction conditions greatly influence the catalytic performance and reaction dynamics. Similarly, the dispersion of the metal within the support plays a crucial in the thermal stability and sintering of the catalyst. Furthermore, temperature-dependent conversion hysteresis is well-known to occur during ignition and extinction of exothermic CO oxidation over supported Pd catalysts due to the variation of CO adsorption on the surface or bulk oxidation of Pd and the ability of the catalyst regenerate the active sites. Herein, the catalytic performance and the hysteresis behavior of mesoporous silica aerogel supported Pd (Pd/a-SiO2), and commercial fumed silica-supported Pd (Pd/f-SiO2) were investigated compared using CO oxidation as a probe reaction under different reaction conditions and operating parameters (i.e., catalyst weight, ramp rate, and flow rate). Surface and morphologic examination using XPS, FTIR, and of Pd/a-SiO2 and Pd/f-SiO2 reveal a strong correlation between the catalyst surface and structure and its catalytic performance and stability under different reaction parameters. Moreover, this study presents the effect of surface area, particle size, and size distribution on diffusion and mass transport of reactants (CO, O-2) and products (CO2) and active sites accessibility. This study showed that Pd/f-SiO2 had better efficiency under high (turbulence) flow. Moreover, intrinsic apparent activation energy (E-a) and the number of active sites were calculated from the Kinetics of CO oxidation fitted using Arrhenius plots indicate that the ramp rate has less effect on Pd/f-SiO2 catalytic behavior. though, Pd/f-SiO2 had higher relative active sites than Pd/a-SiO2, (E-a) was lower. Cyclic stability and long-term stabilities showed that both catalysts are stable and can regenerate the active sites. The current study contributes to understanding the catalysts' surface, structural and morphological properties on the catalysts' performance toward CO oxidation and other reactions under dynamic conditions.
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7. |
- Al-Soubaihi, Rola, et al.
(författare)
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Investigation of palladium catalysts in mesoporous silica support for CO oxidation and CO2 adsorption
- 2023
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Ingår i: Heliyon. - : Elsevier BV. - 2405-8440. ; 9:7
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Tidskriftsartikel (refereegranskat)abstract
- The oxidation of Carbon monoxide (CO) to Carbon dioxide (CO2) is one of the most extensively investigated reactions in the field of heterogeneous catalysis, and it occurs via molecular rearrangements induced by catalytic metal atoms with oxygen intermediates. CO oxidation and CO2 capture are instrumental processes in the reduction of green-house gas emissions, both of which are used in low-temperature CO oxidation in the catalytic converters of vehicles. CO oxidation and CO2 adsorption at different temperatures are evaluated for palladium-supported silica aerogel (Pd/SiO2). The synthesized catalyst was active and stable for low-temperature CO oxidation. The catalytic activity was enhanced after the first cycle due to the reconditioning of the catalyst's pores. It was found that the presence of oxide forms of palladium in the SiO2 microstructure, influences the performance of the catalysts due to oxygen vacancies that increases the frequency of active sites. CO2 gas adsorption onto Pd/SiO2 was investigated at a wide-ranging temperature from 16 to 120 degrees C and pressures similar to 1 MPa as determined from the isotherms that were evaluated, where CO2 showed the highest equilibrium adsorption capacity at 16 degrees C. The Langmuir model was employed to study the equilibrium adsorption behavior. Finally, the effect of moisture on CO oxidation and CO2 adsorption was considered to account for usage in real-world applications. Overall, mesoporous Pd/SiO2 aerogel shows potential as a material capable of removing CO from the environment and capturing CO2 at low temperatures.
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- Al-Soubaihi, Rola, et al.
(författare)
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Low-temperature CO oxidation by silver nanoparticles in silica aerogel mesoreactors
- 2023
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Ingår i: Chemical Engineering Journal. - : Elsevier BV. - 1385-8947 .- 1873-3212. ; 455, s. 140576-
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Tidskriftsartikel (refereegranskat)abstract
- Low-temperature carbon monoxide (CO) oxidation on silver/silica aerogel (Ag/SiO2 AG) catalyst prepared by one-pot sol-gel synthesis followed by supercritical ethanol drying method is reported. Highly stable and sinterproof catalyst led to easy reactant diffusion to the active sites. The Ag/SiO2 AG catalyst showed enhanced catalytic activity toward low-temperature CO oxidation by preventing agglomeration of silver nanoparticles inside pores and facilitating well-dispersed active sites to enhance the mass heat transfer in the mesopores. Catalyst pretreatment conditions were found to play a crucial role in achieving high CO conversion efficiency at low light-off temperatures. Inverse counter-clockwise CO oxidation hysteresis was found to occur after the first run. The active sites contributing to this enhanced catalytic behavior were confirmed to be Ag0 from XPS, XRD, and TEM analysis. The catalyst exhibited good thermal stability up to 450 degrees C over repeated number of cycles.
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9. |
- Al Soubaihi, Rola Mohammad, et al.
(författare)
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CO Oxidation Efficiency and Hysteresis Behavior over Mesoporous Pd/SiO2 Catalyst
- 2021
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Ingår i: Catalysts. - : MDPI AG. - 2073-4344. ; 11:1
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Tidskriftsartikel (refereegranskat)abstract
- Carbon monoxide (CO) oxidation is considered an important reaction in heterogeneous industrial catalysis and has been extensively studied. Pd supported on SiO2 aerogel catalysts exhibit good catalytic activity toward this reaction owing to their CO bond activation capability and thermal stability. Pd/SiO2 catalysts were investigated using carbon monoxide (CO) oxidation as a model reaction. The catalyst becomes active, and the conversion increases after the temperature reaches the ignition temperature (T-ig). A normal hysteresis in carbon monoxide (CO) oxidation has been observed, where the catalysts continue to exhibit high catalytic activity (CO conversion remains at 100%) during the extinction even at temperatures lower than T-ig. The catalyst was characterized using BET, TEM, XPS, TGA-DSC, and FTIR. In this work, the influence of pretreatment conditions and stability of the active sites on the catalytic activity and hysteresis is presented. The CO oxidation on the Pd/SiO2 catalyst has been attributed to the dissociative adsorption of molecular oxygen and the activation of the C-O bond, followed by diffusion of adsorbates at T-ig to form CO2. Whereas, the hysteresis has been explained by the enhanced stability of the active site caused by thermal effects, pretreatment conditions, Pd-SiO2 support interaction, and PdO formation and decomposition.
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10. |
- Al-Soubaihi, Rola, et al.
(författare)
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Silica and carbon decorated silica nanosheet impact on primary human immune cells
- 2018
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Ingår i: Colloids and Surfaces B. - : Elsevier B.V.. - 0927-7765 .- 1873-4367. ; 172, s. 779-789
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Tidskriftsartikel (refereegranskat)abstract
- Silica nanosheets (SiO 2 NS) are considered to be a promising material in clinical practice for diagnosis and therapy applications. However, an appropriate surface functionalization is essential to guarantee high biocompatibility and molecule loading ability. Although SiO 2 NS are chemically stable, its effects on immune systems are still being explored. In this work, we successfully synthesized a novel 2D multilayer SiO 2 NS and SiO 2 NS coated with carbon (C/SiO 2 NS), and evaluated their impact on human Peripheral Blood Mononuclear Cells (PBMCs) and some immune cell subpopulations. We demonstrated that the immune response is strongly dependent on the surface functionalities of the SiO 2 NS. Ex vivo experiments showed an increase in biocompatibility of C/SiO 2 NS compared to SiO 2 NS, resulting in a lowering of hemoglobin release together with a reduction in cellular toxicity and cellular activation. However, none of them are directly involved in the activation of the acute inflammation process with a consequent release of pro-inflammatory cytokines. The obtained results provide an important direction towards the biomedical applications of silica nanosheets, rendering them an attractive material for the development of future immunological therapies.
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