| 1. |
- El Jery, Atef, et al.
(författare)
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Industrial oily wastewater treatment by microfiltration using silver nanoparticle-incorporated poly (acrylonitrile-styrene) membrane
- 2023
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Ingår i: Environmental Sciences Europe. - : Springer. - 2190-4707 .- 2190-4715. ; 35:1
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Tidskriftsartikel (refereegranskat)abstract
- Membrane filtration exhibit operational limitations such as biofouling, which leads to concentration polarization and reduces permeability and selectivity, despite advantages such as low operating cost, high selectivity, and permeability. In recent years, the antibacterial properties of silver nanoparticles (AgNPs) have been investigated for improving membrane processes; however, the fouling phenomena in presence of AgNPs in the membrane matrix have not been fully discussed. Herein, the antifouling properties of a poly (acrylonitrile-styrene) copolymer incorporated with AgNPs were studied in a microfiltration membrane process. The Creighton method was used to synthesize AgNPs, and the effects of AgNPs on the porosity, morphology, pore size, mechanical strength, permeability, and selectivity of the membranes were investigated. Moreover, to investigate the biofouling of the obtained membranes, microfiltration of industrial oily wastewater was performed at constant pressure over three cycles. Using AgNPs in the membrane matrix resulted in enhanced antifouling properties of the copolymer membrane, which is related to the structure of the AgNPs in the casting solution, as proven by SAXS analysis. The results show that the CFU% for Staphylococcus aureus and E.coli reach 2% and 6%, respectively. Finally, the Derjaguin–Landau–Verwey–Overbeek (DLVO) thermodynamic model was applied to study the antifouling mechanism, correctly predict the separation behavior in the membrane, and design, simulate, and optimize the separation processes in the membrane separation plantsa. The DLVO model could predict the separation behavior in the synthesized membranes, and the poly(acrylonitrile-styrene) copolymer membranes containing AgNPs were proven have promising industrial wastewater treatment applications.
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| 2. |
- El Jery, Atef, et al.
(författare)
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Isotherms, kinetics and thermodynamic mechanism of methylene blue dye adsorption on synthesized activated carbon
- 2024
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Ingår i: Scientific Reports. - : Springer Nature. - 2045-2322. ; 14:1
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Tidskriftsartikel (refereegranskat)abstract
- The treatment of methylene blue (MB) dye wastewater through the adsorption process has been a subject of extensive research. However, a comprehensive understanding of the thermodynamic aspects of dye solution adsorption is lacking. Previous studies have primarily focused on enhancing the adsorption capacity of methylene blue dye. This study aimed to develop an environmentally friendly and cost-effective method for treating methylene blue dye wastewater and to gain insights into the thermodynamics and kinetics of the adsorption process for optimization. An adsorbent with selective methylene blue dye adsorption capabilities was synthesized using rice straw as the precursor. Experimental studies were conducted to investigate the adsorption isotherms and models under various process conditions, aiming to bridge gaps in previous research and enhance the understanding of adsorption mechanisms. Several adsorption isotherm models, including Langmuir, Temkin, Freundlich, and Langmuir–Freundlich, were applied to theoretically describe the adsorption mechanism. Equilibrium thermodynamic results demonstrated that the calculated equilibrium adsorption capacity (qe) aligned well with the experimentally obtained data. These findings of the study provide valuable insights into the thermodynamics and kinetics of methylene blue dye adsorption, with potential applications beyond this specific dye type. The utilization of rice straw as an adsorbent material presents a novel and cost-effective approach for MB dye removal from wastewater.
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| 3. |
- El Jery, Atef, et al.
(författare)
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Optimization of oil industry wastewater treatment system and proposing empirical correlations for chemical oxygen demand removal using electrocoagulation and predicting the system’s performance by artificial neural network
- 2023
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Ingår i: PeerJ. - : PeerJ Inc.. - 2167-8359. ; 11
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Tidskriftsartikel (refereegranskat)abstract
- The alarming pace of environmental degradation necessitates the treatment of wastewater from the oil industry in order to ensure the long-term sustainability of human civilization. Electrocoagulation has emerged as a promising method for optimizing the removal of chemical oxygen demand (COD) from wastewater obtained from oil refineries. Therefore, in this study, electrocoagulation was experimentally investigated, and a single-factorial approach was employed to identify the optimal conditions, taking into account various parameters such as current density, pH, COD concentration, electrode surface area, and NaCl concentration. The experimental findings revealed that the most favorable conditions for COD removal were determined to be 24 mA/cm2 for current density, pH 8, a COD concentration of 500 mg/l, an electrode surface area of 25.26 cm2, and a NaCl concentration of 0.5 g/l. Correlation equations were proposed to describe the relationship between COD removal and the aforementioned parameters, and double-factorial models were examined to analyze the impact of COD removal over time. The most favorable outcomes were observed after a reaction time of 20 min. Furthermore, an artificial neural network model was developed based on the experimental data to predict COD removal from wastewater generated by the oil industry. The model exhibited a mean absolute error (MAE) of 1.12% and a coefficient of determination (R2) of 0.99, indicating its high accuracy. These findings suggest that machine learning-based models have the potential to effectively predict COD removal and may even serve as viable alternatives to traditional experimental and numerical techniques.
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| 4. |
- El Jery, Atef, et al.
(författare)
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Proposing empirical correlations and optimization of Nu and Sgen of nanofluids in channels and predicting them using artificial neural network
- 2023
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Ingår i: Case Studies in Thermal Engineering. - : Elsevier. - 2214-157X. ; 45
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Tidskriftsartikel (refereegranskat)abstract
- Getting the best performance from a thermal system requires two fundamental analyses, energy and entropy generation. An ideal mechanism has the highest Nu and the lowest entropy Sgen. As part of this research, a large dataset of fluid flow via tubes has been collected experimentally. As well as the inclusion of nanoparticles, analyses are included as well. By using deep learning algorithms, the Nusselt number and total entropy generation are predicted. In both models, the mean absolute error was lower than 5%. To determine the most accurate model, hyperparameter tuning is performed. That is adjusting all the settings in the neural network to attain the best results. The results of the predictive models are compared against experimental and benchmark results. The study incorporates a massive optimization strategy to fine-tune the predictive capabilities of the models. Furthermore, the model's predictive abilities are evaluated through the use of the coefficient of determination R2. For water and nanofluids flowing through circular, square, and rectangular cross-sections, the proposed models can predict Nu and Sgen. The results showed remarkable agreement with the experimental results. The models showed an MAE of not higher than 1.33%, which is a great achievement. Also, empirical correlations are proposed for both parameters, and double factorial optimization is implemented. The results showed that to achieve the best results, the Re should be higher than 1600, and the nanoparticle concentration should be 3%. A thorough justification of selected cases is presented as well.
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| 5. |
- El Jery, Atef, et al.
(författare)
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Thermodynamic and structural investigation of oily wastewater treatment using peach kernel and walnut shell based activated carbon
- 2024
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Ingår i: PLOS ONE. - : Public Library of Science. - 1932-6203. ; 19:5
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Tidskriftsartikel (refereegranskat)abstract
- Despite the many articles about activated carbon with different precursors in adsorption process, no in-depth research has been carried out to understand the causes of the difference in surface adsorption characteristics of activated carbon with different precursors and different activation processes. In this work, the ability of two active carbon adsorbents made of walnut shell and peach kernel by two chemical and physical methods (totally 4 different types of activated carbon) in treatment of oily wastewater including diesel, gasoline, used oil or engine lubricant has been compared. The results show that the chemical activated peach carbon active with 97% hardness has provided the highest hardness and physical activated walnut carbon active has obtained the lowest hardness value (87%). It is also found that peach activated carbon has a higher iodine number than walnut activated carbon, and this amount can be increased using chemical methods; Therefore, the highest amount of Iodine Number is related to Peach activated carbon that is made by chemical method (1230 mg/g), and the lowest amount of iodine number is seen in walnut activated carbon that is made by physical method (1020 mg/g). moreover, the pore diameter of physical activated carbon is lower than chemical activated carbon in all cases. So that the pore diameter of chemical activated peach carbon active is equal to 22.08 μm and the measured pore diameter of physical activated peach carbon active is equal to 20.42 μm. These values for walnut are obtained as 22.74 μm and 21.86 μm, respectively. Furthermore, the temperature and pH effects on the adsorption of different synthesized oily wastewater was studied and it was found that a decrease in adsorption can be seen with an increase in temperature or decreasing the pH value, which can be referred to this fact that the process of adsorption is an exothermic process. Finally, to analyze the compatibility of adsorption isotherms with experimental data and to predict the adsorption process, three different isotherms named Langmuir, Temkin, and Freundlich isotherms were applied and their parameters were correlated. The correlation results show that the Langmuir isotherm had the best correlation in all cases compared to the Freundlich and Temkin isotherms, based on the correlation coefficient, and the calculated R2 values which was greater than 0.99 in all the studied cases.
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| 6. |
- Jery, Atef El, et al.
(författare)
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A novel experimental and machine learning model to remove COD in a batch reactor equipped with microalgae
- 2023
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Ingår i: Applied water science. - : Springer. - 2190-5487 .- 2190-5495. ; 13:7
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Tidskriftsartikel (refereegranskat)abstract
- By using microorganisms and the microalgae Chlorella vulgaris in conjunction with sequencing batch reactors (SBRs), the performance of a wastewater treatment facility was studied. For this purpose, the effect of pH, temperature, CODinlet, and air flowrate on COD removal rate and residual was investigated. A single-factorial optimization method is utilized to optimize the amount of COD removal, and the best result is obtained with a pH of 8, CODinlet=600mg/l, and an airflow rate of 55 l/min. Under optimal conditions, the amount of residual COD in the effluent reached 36 mg/l, showing an augmentation in the efficiency of the desired system. Moreover, empirical correlations are proposed for double-factorial optimization of residual COD and COD removal. Also, a multilayer perceptron artificial neural network is proposed to model the process and predict the residual COD concentration. The useful technique of hyperparameter tuning is utilized to obtain the best result for the predictions. All the effective parameters, including the number of hidden layers, neurons, epochs, and batch size, are adjusted. Data from the experiments agreed well with the artificial neural network modeling results. For this modeling, the values of the correlation coefficient (R2) and mean absolute error (MAE) were obtained as 0.98 and 2%, respectively.
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