| 1. |
- Allali, Naoual, et al.
(författare)
-
Accurate control of the covalent functionalization of single-walled carbon nanotubes for the electro-enzymatically controlled oxidation of biomolecules
- 2018
-
Ingår i: Beilstein Journal of Nanotechnology. - : Beilstein-Institut. - 2190-4286. ; 9, s. 2750-2762
-
Tidskriftsartikel (refereegranskat)abstract
- Single-walled carbon nanotubes (SWCNTs) were functionalized by ferrocene through ethyleneglycol chains of different lengths (FcETGn) and the functionalized SWCNTs (f-SWCNTs) were characterized by different complementary analytical techniques. In particular, high-resolution scanning electron transmission microscopy (HRSTEM) and electron energy loss spectroscopy (EELS) analyses support that the outer tubes of the carbon-nanotube bundles were covalently grafted with FcETGn groups. This result confirms that the electrocatalytic effect observed during the oxidation of the reduced form of nicotinamide adenine dinucleotide (NADH) co-factor by the f-SWCNTs is due to the presence of grafted ferrocene derivatives playing the role of a mediator. This work clearly proves that residual impurities present in our SWCNT sample (below 5 wt. %) play no role in the electrocatalytic oxidation of NADH. Moreover, molecular dynamic simulations confirm the essential role of the PEG linker in the efficiency of the bioelectrochemical device in water, due to the favorable interaction between the ETG units and water molecules that prevents π-stacking of the ferrocene unit on the surface of the CNTs. This system can be applied to biosensing, as exemplified for glucose detection. The well-controlled and well-characterized functionalization of essentially clean SWCNTs enabled us to establish the maximum level of impurity content, below which the f-SWCNT intrinsic electrochemical activity is not jeopardized.
|
|
| 2. |
- Allali, Naoual, et al.
(författare)
-
Covalent functionalization of few-wall carbon nanotubes by ferrocene derivatives for bioelectrochemical devices
- 2012
-
Ingår i: Physica status solidi. B, Basic research. - : Wiley. - 0370-1972 .- 1521-3951. ; 249:12, s. 2349-2352
-
Tidskriftsartikel (refereegranskat)abstract
- The present work reports the covalent functionalization of few-wall CNTs (FWCNTs) by ferrocene derivatives to (i) improve their dispersion efficiency in water and (ii) graft electroactive chemical groups on their side-walls in order to promote electron transfer to biomolecules. The functionalized CNTs (f-CNTs) are used to modify a glassy carbon electrode and this modified electrode is used for oxidizing the cofactor NADH (dihydronicotinamide adenine dinucleotide).
|
|
| 3. |
- Allali, Naoual, et al.
(författare)
-
Electrocatalytic effect towards NADH induced by HiPco single-walled carbon nanotubes covalently functionalized by ferrocene derivatives
- 2013
-
Ingår i: 2012 MRS Fall Meeting. - : Cambridge University Press.
-
Konferensbidrag (refereegranskat)abstract
- The present work reports the covalent functionalization of single-walled carbon nanotubes (SWCNTs) by ferrocene derivatives with polyethyleneglycol linkers. A very clean initial sample was chosen to avoid any residual catalyst and carbon impurities. Functionalized SWCNTs (f-CNTs) are deposited on the surface of a glassy carbon electrode (GCE) and this modified electrode is used for oxidizing the cofactor NADH (dihydronicotinamide adenine dinucleotide) in the presence of diaphorase. A clear electrocatalytic effect is evidenced, which can only be attributed to the f-CNTs.
|
|
| 4. |
- Allali, Naoual, et al.
(författare)
-
Few-wall carbon nanotubes covalently functionalized by ferrocene groups for bioelectrochemical devices
- 2012
-
Ingår i: MRS Online Proceedings Library. - : Cambridge University Press. - 9781605114286
-
Konferensbidrag (refereegranskat)abstract
- The present work reports the covalent functionalization of few-wall CNTs (FWCNTs) by ferrocene derivatives to i) improve their dispersion efficiency in water and ii) to graft electroactive chemical groups on their side-walls in order to promote electron transfer to biomolecules. The functionalized CNTs (f-CNTs) are used to modify a glassy carbon electrode and this modified electrode is used for oxidizing the cofactor NADH (dihydronicotinamide adenine dinucleotide).
|
|
| 5. |
- Baudrier, Etienne, et al.
(författare)
-
Retrieval of the ornaments from the Hand-Press Period : An overview
- 2009
-
Ingår i: Proceedings of the International Conference on Document Analysis and Recognition, ICDAR. - : IEEE. - 9780769537252 ; , s. 496-500
-
Konferensbidrag (refereegranskat)abstract
- This paper deals with the topic of the retrieval of document images focused on a specific application: the ornaments of the Hand-Press period. It presents an overview as a result of the work and the discussions undertaken by a workgroup on this subject. The paper starts by giving a general view about digital libraries of ornaments and associated retrieval problematics. Two main issues are underlined: content based image retrieval (CBIR) and image difference visualization. Several contributions are summarized, commented and compared. Conclusions and open problems arising from this overview are twofold: 1. contributions on CBIR miss scale-invariant methods and don't provide significative evaluation results. 2. robust registration is the open problem for visual comparison.
|
|
| 6. |
- Chambault, Philippine, et al.
(författare)
-
The Gulf Stream frontal system : A key oceanographic feature in the habitat selection of the leatherback turtle?
- 2017
-
Ingår i: Deep Sea Research Part I. - : Elsevier BV. - 0967-0637 .- 1879-0119. ; 123, s. 35-47
-
Tidskriftsartikel (refereegranskat)abstract
- Although some associations between the leatherback turtle Dermochelys coriacea and the Gulf Stream current have been previously suggested, no study has to date demonstrated strong affinities between leatherback movements and this particular frontal system using thorough oceanographic data in both the horizontal and vertical dimensions. The importance of the Gulf Stream frontal system in the selection of high residence time (HRT) areas by the North Atlantic leatherback turtle is assessed here for the first time using state-of-the-art ocean reanalysis products. Ten adult females from the Eastern French Guianese rookery were satellite tracked during post-nesting migration to relate (1) their horizontal movements to physical gradients (Sea Surface Temperature (SST), Sea Surface Height (SSH) and filaments) and biological variables (micronekton and chlorophyll a), and (2) their diving behaviour to vertical structures within the water column (mixed layer, thermocline, halocline and nutricline). All the turtles migrated northward towards the Gulf Stream north wall. Although their HRT areas were geographically remote (spread between 80-30 degrees W and 28-45 degrees N), all the turtles targeted similar habitats in terms of physical structures, i.e. strong gradients of SST, SSH and a deep mixed layer. This close association with the Gulf Stream frontal system highlights the first substantial synchronization ever observed in this species, as the HRTs were observed in close match with the autumn phytoplankton bloom. Turtles remained within the enriched mixed layer at depths of 38.5 +/- 7.9 m when diving in HRT areas, likely to have an easier access to their prey and maximize therefore the energy gain. These depths were shallow in comparison to those attained within the thermocline (82.4 +/- 5.6 m) while crossing the nutrient-poor subtropical gyre, probably to reach cooler temperatures and save energy during the transit. In a context of climate change, anticipating the evolution of such frontal structure under the influence of global warming is crucial to ensure the conservation of this vulnerable species.
|
|
| 7. |
- Cuni-Sanchez, Aida, et al.
(författare)
-
High aboveground carbon stock of African tropical montane forests
- 2021
-
Ingår i: Nature. - : Springer Science and Business Media LLC. - 0028-0836 .- 1476-4687. ; 596:7873, s. 536-542
-
Tidskriftsartikel (refereegranskat)abstract
- Tropical forests store 40–50per cent of terrestrial vegetation carbon. However, spatial variations in aboveground live tree biomass carbon (AGC) stocks remain poorly understood, in particular in tropical montane forests. Owing to climatic and soil changes with increasing elevation, AGC stocks are lower in tropical montane forests compared with lowland forests. Here we assemble and analyse a dataset of structurally intact old-growth forests (AfriMont) spanning 44 montane sites in 12 African countries. We find that montane sites in the AfriMont plot network have a mean AGC stock of 149.4megagrams of carbon per hectare (95% confidence interval 137.1–164.2), which is comparable to lowland forests in the African Tropical Rainforest Observation Network4 and about 70per cent and 32per cent higher than averages from plot networks in montane and lowland forests in the Neotropics, respectively. Notably, our results are two-thirds higher than the Intergovernmental Panel on Climate Change default values for these forests in Africa8. We find that the low stem density and high abundance of large trees of African lowland forests is mirrored in the montane forests sampled. This carbon store is endangered: we estimate that 0.8 million hectares of old-growth African montane forest have been lost since 2000. We provide country-specific montane forest AGC stock estimates modelled from our plot network to helpto guide forest conservation and reforestation interventions. Our findings highlight the need for conserving these biodiverse and carbon-rich ecosystems.
|
|
| 8. |
- Simon-Bouy, Brigitte, et al.
(författare)
-
Hypophosphatasia: molecular testing of 19 prenatal cases and discussion about genetic counseling.
- 2008
-
Ingår i: Prenatal diagnosis. - : Wiley. - 0197-3851 .- 1097-0223. ; 28:11, s. 993-8
-
Tidskriftsartikel (refereegranskat)abstract
- OBJECTIVE: We studied hypophosphatasia (HP) mutations in 19 cases prenatally detected by ultrasonography without familial history of HP. We correlated the mutations with the reported ultrasound signs, and discussed genetic counseling with regard to the particular dominantly inherited prenatal benign form of HP. METHOD: The coding sequence of the tissue nonspecific alkaline phosphatase (TNSALP) gene was analyzed by DNA sequencing, and 3D modeling was used to locate the mutated amino acids with regard to the functional domains of TNSALP. RESULTS: Although reported ultrasound signs were heterogeneous, two mutated alleles were found in 18 of the 19 cases studied, indicating recessive transmission of the disease. Functional domains of TNSALP were affected by 74% of missense mutations. In all the cases, including one with only a heterozygous mutation, molecular, biological, and familial data do not corroborate the hypothesis of prenatal benign HP. The mutation c.1133A>T observed in the prenatal benign form of HP and common in USA was not found in this series. CONCLUSION: The results point out the prenatally detectable allelic heterogeneity of HP. The nature of the detected mutations and the evidence of recessive inheritance do not support these cases being affected with prenatal benign HP.
|
|
| 9. |
- Strinati, Emilio Calvanese, et al.
(författare)
-
Wireless environment as a service enabled by reconfigurable intelligent surfaces: The RISE-6G perspective
- 2021
-
Ingår i: 2021 Joint European Conference on Networks and Communications and 6G Summit, EuCNC/6G Summit 2021. ; , s. 562-567
-
Konferensbidrag (refereegranskat)abstract
- The design of 6th Generation (6G) wireless networks points towards flexible connect-and-compute technologies capable to support innovative services and use cases. Targeting the 2030 horizon, 6G networks are poised to pave the way for sustainable human-centered smart societies and vertical industries, such that wireless networks will be transformed into a distributed smart connectivity infrastructure, where new terminal types are embedded in the daily environment. In this context, the RISE-6G project aims at investigating innovative solutions that capitalize on the latest advances in the emerging technology of Reconfigurable Intelligent Surfaces (RISs), which offers dynamic and goal-oriented radio wave propagation control, enabling the concept of the wireless environment as a service. The project will focus on: i) the realistic modeling of RIS-assisted signal propagation, ii) the investigation of the fundamental limits of RIS-empowered wireless communications and sensing, and iii) the design of efficient algorithms for orchestrating networking RISs, in order to implement intelligent, sustainable, and dynamically programmable wireless environments enabling diverse services that go well beyond the 5G capabilities. RISE-6G will offer two unprecedented proof-of-concepts for realizing controlled wireless environments in near-future use cases.
|
|
| 10. |
-
- 2017
-
Ingår i: Physical Review D. - 2470-0010 .- 2470-0029. ; 96:2
-
Tidskriftsartikel (refereegranskat)
|
|
