| 1. |
- Wu, Jingnan, et al.
(författare)
-
Carboxylate substituted pyrazine: A simple and low-cost building block for novel wide bandgap polymer donor enables 15.3% efficiency in organic solar cells
- 2021
-
Ingår i: Nano Energy. - : Elsevier BV. - 2211-2855. ; 82
-
Tidskriftsartikel (refereegranskat)abstract
- In addition to high power conversion efficiency (PCE) and good stability, the low-cost of photovoltaic materials is also very important for the practical application of organic solar cells (OSCs). Herein, we synthesized a carboxylate substituted pyrazine-based electron-deficient building block (DTCPz) with a simple structure and low synthetic cost, and then developed a novel wide bandgap polymer donor PFBCPZ. Due to the synergistic electron-withdrawing effects of the fluorination in donor unit (BDT-TF) and esterification and C=N double-bond in DTCPz unit, PFBCPZ shows a deeper HOMO level of −5.60 eV, a strong intermolecular π-π interaction, good crystallinity and stacking, and high hole-mobility of 2.11 × 10−3 cm2 V−1 s−1. Matched with a low bandgap acceptor IT-4F, excellent charge transfer, weak recombination, and small non-radiative energy loss in OSCs was achieved, resulting in an impressive fill factor of 0.785 and a high open-circuit voltage of 0.92 V. As a result, a PCE of up to 15.3% is obtained in OSCs, which is the highest value in the IT-4F-based binary OSCs so far and indicates that low-cost DTCPz with a simple structure is a promising building block to construct high-performance polymer donors for application in efficient OSCs.
|
|
| 2. |
- Bai, Yang, et al.
(författare)
-
Geometry design of tethered small-molecule acceptor enables highly stable and efficient polymer solar cells
- 2023
-
Ingår i: Nature Communications. - : NATURE PORTFOLIO. - 2041-1723. ; 14:1
-
Tidskriftsartikel (refereegranskat)abstract
- With the power conversion efficiency of binary polymer solar cells dramatically improved, the thermal stability of the small-molecule acceptors raised the main concerns on the device operating stability. Here, to address this issue, thiophene-dicarboxylate spacer tethered small-molecule acceptors are designed, and their molecular geometries are further regulated via the thiophene-core isomerism engineering, affording dimeric TDY-alpha with a 2, 5-substitution and TDY-beta with 3, 4-substitution on the core. It shows that TDY-alpha processes a higher glass transition temperature, better crystallinity relative to its individual small-molecule acceptor segment and isomeric counterpart of TDY-beta, and amore stablemorphology with the polymer donor. As a result, the TDY-alpha based device delivers a higher device efficiency of 18.1%, and most important, achieves an extrapolated lifetime of about 35000 hours that retaining 80% of their initial efficiency. Our result suggests that with proper geometry design, the tethered small-molecule acceptors can achieve both high device efficiency and operating stability.
|
|
| 3. |
- Guo, Mengyuan, et al.
(författare)
-
High gas tightness ZrO2-added silicate glass sealant with low thermal stress for solid oxide fuel cells
- 2023
-
Ingår i: Ceramics International. - : Elsevier BV. - 0272-8842. ; 49:12, s. 19708-19716
-
Tidskriftsartikel (refereegranskat)abstract
- A low leakage rate sealant of 10 wt% ZrO2-added CaO–K2O–Na2O–BaO silicate glass for SOFC has been studied. The structure of the sealant is stable at high temperatures with leakage rates less than 10−4 sccm∙cm−1, and no crystal except for ZrO2 is found in XRD analysis after heating at 800 °C for 100 h. ZrO2 is distributed in the glass matrix and plays a supporting role in avoiding over-softening at operating temperature. Good compatibility in both oxidizing and reducing atmospheres between the sealant and SUS430 interconnect was proved by SEM at 750 °C for 100 h. A fully coupled 3D Multiphysics button SOFC is constructed for mechanical analyses. The results show that the increase of ZrO2 in the sealant will decrease the stress and displacement in the SOFC. Besides, the width of the sealant also affects the stress value and distribution. The results show that GZ10 is a competitive sealing material compared with other ZrO2-added sealants.
|
|
| 4. |
- Weiguang, Ma, et al.
(författare)
-
Review on Noise Immune Cavity Enhanced Optical Heterodyne Molecular Spectroscopy
- 2018
-
Ingår i: Chinese Journal of Lasers-Zhongguo Jiguang. - : Chinese Laser Press. - 0258-7025. ; 45:9
-
Forskningsöversikt (refereegranskat)abstract
- Noise immune cavity enhanced optical heterodyne molecular spectroscopy (NICE-OHMS) can provide the highest detection sensitivity in the field of laser absorption spectroscopy by combining two techniques of frequency modulation spectroscopy and cavity enhanced absorption spectroscopy. The principle and implementation process of NICE-OHMS arc introduced. Then, the historical development of NICE-OHMS is overviewed, which mainly focuses on the key parameters, such as the applied laser source and the cavity finesse used by each research group and their obtained detection sensitivity. Finally, the limitation factors of the detection sensitivity of NICE-OHMS arc analyzed, and the related solutions arc provided.
|
|
| 5. |
- Yang, Shangchen, et al.
(författare)
-
Genomic investigation of the Chinese alligator reveals wild-extinct genetic diversity and genomic consequences of their continuous decline
- 2023
-
Ingår i: Molecular Ecology Resources. - : Wiley. - 1755-098X .- 1755-0998. ; 23:1, s. 294-311
-
Tidskriftsartikel (refereegranskat)abstract
- Critically endangered species are usually restricted to small and isolated populations. High inbreeding without gene flow among populations further aggravates their threatened condition and reduces the likelihood of their long-term survival. Chinese alligator (Alligator sinensis) is one of the most endangered crocodiles in the world and has experienced a continuous decline over the past c. 1 million years. In order to identify the genetic status of the remaining populations and aid conservation efforts, we assembled the first high-quality chromosome-level genome of Chinese alligator and explored the genomic characteristics of three extant breeding populations. Our analyses revealed the existence of at least three genetically distinct populations, comprising two breeding populations in China (Changxing and Xuancheng) and one breeding population in an American wildlife refuge. The American population does not belong to the last two populations of its native range (Xuancheng and Changxing), thus representing genetic diversity extinct in the wild and provides future opportunities for genetic rescue. Moreover, the effective population size of these three populations has been continuously declining over the past 20 ka. Consistent with this decline, the species shows extremely low genetic diversity, a large proportion of long runs of homozygous fragments, and mutational load across the genome. Finally, to provide genomic insights for future breeding management and conservation, we assessed the feasibility of mixing extant populations based on the likelihood of introducing new deleterious alleles and signatures of local adaptation. Overall, this study provides a valuable genomic resource and important genomic insights into the ecology, evolution, and conservation of critically endangered alligators.
|
|
