| 1. |
- Ahniyaz, Anwar, et al.
(författare)
-
Preparation of iron oxide nanocrystals by surfactant-free or oleic acid-assisted thermal decomposition of a Fe(III) alkoxide
- 2008
-
Ingår i: Journal of Magnetism and Magnetic Materials. - : Elsevier BV. - 0304-8853 .- 1873-4766. ; 320:6, s. 781-787
-
Tidskriftsartikel (refereegranskat)abstract
- A new non-hydrolytic, alkoxide-based route was developed to synthesize iron oxide nanocrystals. Surfactant-free thermal decomposition of the iron 2-methoxy-ethoxide precursors results in the formation of uniform iron oxide nanocrystals with an average size of 5.6 nm. Transmission electron microscope study shows that the nanocrystals are protected against aggregation by a repulsive surface layer, probably originating from the alkoxy-alkoxide ligands. Addition of oleic acid resulted in monodisperse nanocrystals with an average size of 4 nm. Mössbauer analysis confirmed that the nanocrystals mainly consisted of maghemite. Analysis of the magnetic hysteresis loop measurements and the zero field and field cooled measurements displayed an excellent fit to established theories for single-domain superparamagnetic nanocrystals and the size of the magnetic domains correlated well to the crystallite size obtained from transmission electron microscope.
|
|
| 2. |
- Agredo Chavez, Angelica Maria, et al.
(författare)
-
Cracking and Fatigue of Heavy Loaded Prestressed Concrete Bridge in Sweden
- 2022
-
Ingår i: IABSE Symposium Prague 2022: Challenges for Existing and Oncoming Structures - Report, International Association for Bridge and Structural Engineering. - Zürich : International Association for Bridge and Structural Engineering. ; , s. 792-799
-
Konferensbidrag (refereegranskat)abstract
- A prestressed concrete bridge was built in 1963 with BBRV cables. It has three spans and a total length of 134.8 m. Due to mining activities the bridge was loaded with trucks with a total weight of 90 ton during 2012-2014 and from 2019. Crack development has been monitored manually and from 2020 with strain gauges and LVDTs.Cracks normally vary between 0.1 to 0.3 mm in width and grow in length with time. In November 2020 some of the strain gauges on the concrete showed alarming growth and the bridge was closed for traffic. Additional strain gauges were installed on vertical reinforcement bars and an assessment was carried out of the fatigue capacity of the bridge. It was found that the new strain gauges did not indicate any growth in strain and that the fatigue capacity was sufficient. The bridge could be opened again for traffic after being closed for five weeks. Monitoring drift in the strain gauges and fatigue are discussed.
|
|
| 3. |
|
|
| 4. |
- Andreeva, M. A., et al.
(författare)
-
Magnetic ordering in a [Fe/Co](35) BCC film studied by nuclear resonant reflectometry
- 2007
-
Ingår i: Journal of Experimental and Theoretical Physics. - 1063-7761 .- 1090-6509. ; 104:4, s. 577-585
-
Tidskriftsartikel (refereegranskat)abstract
- An analysis of the angular dependences of nuclear resonant reflectivity time spectra for different models of magnetic ordering in films reveals an ambiguity in the magnetization direction determined from spectra measured at one orientation of the sample. This analysis explains features in the spectra of the nuclear resonant reflectivity from a MgO/[Fe(6 ML)/Co(3 ML)]35/V (1 nm) film measured before and after sample rotation by 90° about the normal to the surface. It is shown that the spectrum measured only at one orientation of the sample determines only the effective azimuth angle of magnetization γeff. This does not exclude the occurrence of a domain structure, while the angle γeff does not correspond to the true direction of the preferred orientation of magnetization. The results of measurements at two orientations of the sample can be satisfactorily matched using a model that considers a coherent mixture of states with magnetization directed along the 〈110〉 axis (77%) and with a chaotic orientation of the magnetic hyperfine field B hf in the film plane for the other nuclei.
|
|
| 5. |
|
|
| 6. |
- Andreeva, M. A., et al.
(författare)
-
Nuclear resonant reflectivity with standing waves for the investigation of a thin 57Fe layer buried inside a superconducting Si/[Mo/Si]45/57Fe/Nb multilayer
- 2008
-
Ingår i: Nuclear Instruments and Methods in Physics Research Section B. - : Elsevier BV. - 0168-583X .- 1872-9584. ; 266:1, s. 187-196
-
Tidskriftsartikel (refereegranskat)abstract
- A special multilayer sample Si/[Mo/Si]45/57Fe/Nb has been prepared for the depth selective investigations of the hyperfine fields in thin iron layer at low temperatures above and below the superconducting transition in the top Nb layer (Tc 8 K) by means of the nuclear resonant reflectivity with standing waves. The periodic multilayer [Mo/Si]45 below the iron layer in our sample was used as “a standing wave generator”. A weak magnetic hyperfine splitting in the 57Fe layer was detected just at low temperature. A slight variation of the nuclear resonant reflectivity time spectra measured above and below Tc was observed. At first it was supposed that this change of the spectrum shape is caused by the spatial modulation of ferromagnetic domains in the 57Fe layer caused by a proximity effect. A closer analysis, however, reveals that the spectrum variations are due to just the changes of the relative weights of the magnetic and paramagnetic phases in 57Fe layer.
|
|
| 7. |
- Andreeva, M. A., et al.
(författare)
-
Polarization selection in Mössbauer reflectivity for magnetic multilayer investigation
- 2019
-
Ingår i: VII Euro-Asian Symposium on Trends In Magnetism. - : IOP Publishing.
-
Konferensbidrag (refereegranskat)abstract
- Mossbauer reflectivity experiment with polarization selection are reported. The use of the LiF polarization analyzer allows us to get the pi ->sigma' peak on the reflectivity curve at the critical angle and Mossbauer pi ->sigma' reflectivity spectra of reasonable quality at the critical angle and also at the Bragg angles of superlattice. The impressive difference of the reflectivity spectra measured near the critical angle with and without polarizations analysis is observed for [Fe-57(10)/V-10](20) multilayer characterizing by the ferromagnetic interlayer coupling. The combined fit of the whole set of spectra measured at different angles reveals the existence of antiferromagnetic Fe oxide phases in the top three bilayers. The experiment demonstrates benefits of the Mossbauer reflectivity with polarization analysis in ultrathin surface layer investigations.
|
|
| 8. |
|
|
| 9. |
- Ansari, Shaquib Rahman, et al.
(författare)
-
Pharmaceutical Quality by Design Approach to Develop High-Performance Nanoparticles for Magnetic Hyperthermia
- 2024
-
Ingår i: ACS Nano. - 1936-0851 .- 1936-086X. ; 18:23, s. 15284-15302
-
Tidskriftsartikel (refereegranskat)abstract
- Magnetic hyperthermia holds significant therapeutic potential, yet its clinical adoption faces challenges. One obstacle is the large-scale synthesis of high-quality superparamagnetic iron oxide nanoparticles (SPIONs) required for inducing hyperthermia. Robust and scalable manufacturing would ensure control over the key quality attributes of SPIONs, and facilitate clinical translation and regulatory approval. Therefore, we implemented a risk-based pharmaceutical quality by design (QbD) approach for SPION production using flame spray pyrolysis (FSP), a scalable technique with excellent batch-to-batch consistency. A design of experiments method enabled precise size control during manufacturing. Subsequent modeling linked the SPION size (6–30 nm) and composition to intrinsic loss power (ILP), a measure of hyperthermia performance. FSP successfully fine-tuned the SPION composition with dopants (Zn, Mn, Mg), at various concentrations. Hyperthermia performance showed a strong nonlinear relationship with SPION size and composition. Moreover, the ILP demonstrated a stronger correlation to coercivity and remanence than to the saturation magnetization of SPIONs. The optimal operating space identified the midsized (15–18 nm) Mn0.25Fe2.75O4 as the most promising nanoparticle for hyperthermia. The production of these nanoparticles on a pilot scale showed the feasibility of large-scale manufacturing, and cytotoxicity investigations in multiple cell lines confirmed their biocompatibility. In vitro hyperthermia studies with Caco-2 cells revealed that Mn0.25Fe2.75O4 nanoparticles induced 80% greater cell death than undoped SPIONs. The systematic QbD approach developed here incorporates process robustness, scalability, and predictability, thus, supporting the clinical translation of high-performance SPIONs for magnetic hyperthermia.
|
|
| 10. |
- Bagge, Niklas, 1987-, et al.
(författare)
-
Full Scale Test of a PC Bridge to Calibrate Assessment Methods
- 2021
-
Ingår i: IABSE Congress Ghent 2021. - Zurich, Switzerland : International Association for Bridge and Structural Engineering (IABSE). ; , s. 965-973
-
Konferensbidrag (refereegranskat)abstract
- In this paper, experiences on the development of an assessment method for existing bridges are presented. The method is calibrated using the results of full-scale testing to failure of a prestressed bridge in Sweden. To evaluate the key parameters for the structural response, measured by deflections, strains in tendons and stirrups and crack openings, a sensitivity study based on the concept of fractional factorial design is incorporated to the assessment. Results showed that the most significant parameters are related to the tensile properties of the concrete (tensile strength and fracture energy) and the boundary conditions. A finite element (FE) model in which the results of the sensitivity analysis were applied, was able to predict accurately the load-carrying capacity of the bridge and its failure mode. Two additional existing prestressed concrete bridges, that will be used to improve further the method, are also described, and discussed.
|
|
