| 1. |
- Ahmad, Nawaz, 1972-, et al.
(författare)
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Injection of CO2-saturated brine in geological reservoir : A way to enhanced storage safety
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- Injection of free phase supercritical CO2 into deep geological reservoirs is associated with risk of considerable return flows towards the land surface due to the buoyancy of CO2, which is lighter than the resident brine in the reservoir. Such upward movements can be avoided if CO2 is injected in the dissolved phase (CO2aq). In this work, injection of CO2-saturated brine in a subsurface carbonate reservoir is modelled. Physical and geochemical interactions of injected low-pH CO2-saturated brine with the carbonate minerals (calcite, dolomite and siderite) are investigated in the reactive transport modelling. CO2-saturated brine, being low in pH, shows high reactivity with the reservoir minerals, resulting in a significant mineral dissolution and CO2 conversion in reactions. Over the injection period of 10 years, up to 16% of the injected CO2 is found consumed in geochemical reactions. Sorption included in the transport analysis resulted in additional quantities of CO2 mass stored. However, for the considered carbonate minerals, the consumption of injected CO2aq is found mainly in the form of ionic trapping.
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| 2. |
- Ahmad, Nawaz, 1972-, et al.
(författare)
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Non-isothermal reactive transport modelling of dissolved CO2 leaking through a fractured caprock
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- Geological storage of CO2 is considered as one of the mitigation actions for climate change adverse effects. However, some fraction of CO2 dissolved in the brine following injection, may leak from the reservoir through permeable zones such as conducting fractures. In this study we perform the reactive transport modelling of single-phase brine saturated with dissolved CO2 (CO2aq) along a conducting fracture in a clay-rich caprock. This study investigates the role of temperature and various reaction systems on the fate of migrating CO2aq, its geochemical interactions with the carbonate minerals, its conversion in geochemical reactions and associated medium porosity and permeability evolutions along the transport pathway.About 0.64% of leaking CO2aq is found converted into other ions in its geochemical interactions with calcite (simplified geochemical system). Addition of mineral dolomite in the geochemical system (extended geochemical system) results in up to 11% higher mass conversion of CO2 in reactions as compared to the simplified geochemical system. Considering extended geochemical system and heat transport by moving brine resulted in about 27.34% higher mass conversion of CO2 in reactions as compared to the simplified geochemical system. A combination of extended geochemical system, heat transport and sorption resulted in about 82.59% higher mass conversion of CO2 compared to the simplified geochemical system. Leaking CO2aq travelled less than 250 m along the fractured pathway, for a velocity of nearly 19 m/year in the fracture, due to retardation caused by mass stored in aqueous and adsorbed states.
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| 3. |
- Neubeck, Anna, et al.
(författare)
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Olivine alteration and H-2 production in carbonate-rich, low temperature aqueous environments
- 2014
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Ingår i: Planetary and Space Science. - : Elsevier BV. - 0032-0633 .- 1873-5088. ; 96, s. 51-61
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Tidskriftsartikel (refereegranskat)abstract
- Hydrous alteration of olivine is capable of producing molecular hydrogen (H-2) under a wide variety of hydrothermal conditions. Although olivine hydrolysis (i.e., serpentinization) has commonly been assessed at elevated temperatures ( > 100 degrees C), the nature of these reactions in relation to H-2 production at lower temperatures has not been systematically evaluated, especially with regard to carbonate-rich fluids. Specifically, carbonate formation may kinetically infringe on geochemical routes related to serpentinization and H-2 production at lower temperatures. Here time-dependent interactions of solid, liquid, and gaseous phases with respect to olivine hydrolysis in a carbonate-rich solution (20 mM HCO3-) at 30, 50 and 70 degrees C for 315 days is investigated experimentally. Within the first two months, amorphous Si-rich (i.e., talc-like) and carbonate phases precipitated; however, no inhibition of olivine dissolution is observed at any temperature based on surface chemistry analyses. High-resolution surface analyses confirm that precipitates grew as spheroids or vertically to form topographic highs allowing further dissolution of the free olivine surfaces and exposing potential catalysts. Despite no magnetite (Fe3O4) being detected, H-2 increased with time in experiments carried out at 70 degrees C, indicating an alternative coupled route for Fe oxidation and H-2 production. Spectrophotometry analyses show that aqueous Fe(II) is largely converted to Fe(III) potentially integrating into other phases such as serpentine and talc, thus providing a viable pathway for H-2 production. No increase in H-2 production was observed in experiments carried out at 30 and 50 degrees C supporting observations that incorporation of Fe(II) into carbonates occurred faster than the intertwined processes of olivine hydrolysis and Fe(III) oxidation. Overall, carbonate formation is confirmed to be a major influence related to H-2 production in low-temperature serpentinization systems.
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| 4. |
- Nigéus, Susanne
(författare)
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Recycling of green liquor dregs in cover application on acid generating mine waste
- 2023
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Doktorsavhandling (övrigt vetenskapligt/konstnärligt)abstract
- The mining industry generates massive amounts of waste that without treatment and in contact with atmospheric oxygen can cause the formation of acid rock drainage (ARD). In Sweden, the most common reclamation measure for mine waste is to apply a multi-layer cover on top of the waste deposit. The access to suitable cover-materials is, however, limited and can lead to extensive costs for the mining companies. This creates a driving force for alternative solutions, e.g., bentonite amendment to till. As bentonite production is costly both economically and environmentally, recycling of industrial residues to produce sealing layer material is an attractive option. The recycling is beneficial for the industry generating the residue, the mining industry using the residue and the society in its strive for zero waste. An industrial residue that has potential to improve the sealing properties of local till is green liquor dregs (GLD), a residue from pulp production. The main objective of this study was to, by laboratory studies and field application and evaluations, investigate if green liquor dregs amended till can be used as a sealing layer material on top of acid generating mine waste. The conclusion from the laboratory study is that the hydraulic conductivity does not decrease significantly with GLD addition to the silty till. However, the water retention capacity, which can be seen as the major important feature of a sealing layer to be used on top of sulfidic mine waste by keeping the layer close to saturation, shows significant improvements with GLD addition. In the field study the GLD amended till was applied successfully from a soil mechanical point of view (e.g., the compaction degree after application). The early results from the monitoring of the sealing layer indicate results comparable to the more frequently used bentonite amendment in a sealing layer, with soil moisture values reaching close to saturation. However, this study also concludes that the great variation in GLD, especially regarding its soil mechanical properties such as water content, makes it difficult to use compared to commercial products. The material used in the laboratory investigations in the planning phase of a project might behave differently than the one that is delivered to the minesite for reclamation.
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