| 1. |
- Hoang-Minh, Thao, et al.
(författare)
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Mineralogical Characterization of Di Linh Bentonite, Vietnam: A Methodological Approach of X-ray Diffraction and Transmission Electron Microscopy
- 2014
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Ingår i: Proceedings of 13th International Symposium on Mineral Exploration (ISME-XIII). - Hanoi : Vietnam National University Press, Hanoi. - 9786046215400 ; , s. 143-148
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Konferensbidrag (refereegranskat)abstract
- Vietnam has decided to establish nuclear power as further energy option. In order to develop a Vietnamese reference bentonite as potential barrier in a final repository for high radioactive waste, a detailed mineralogical investigation of Di Linh bentonite (Lam Dong province), lacustrine clay, was carried out by different methods especially transmission electron microscopy (TEM) linked with energy-dispersive X-ray (EDX). From a sample homogenized from 5 tones of the bentonite, mineral formulae of clay particles was calculated The calculation also focuses on randomly interstratifications of two and three members. The fraction <2 μm of Di Linh bentonite is composed mainly by montmorillonite (Ca0.06Mg0.03Na0.09K0.03Al1.39Fe0.25Mg0.26(OH)2 Si3.96Al0.04O10) and regular ordering (R1) illite-smectite interstratifications with K- and charge-deficiency (Ca0.04Mg0.07Na0.18K0.16Al1.76Fe0.08Mg0.16(OH)2Si3.62Al0.38O10). Additionally, Fe-poor kaolinite-smectite-vermiculite interstratifications and trace of Fe-rich chloritesmectite- vermiculite interstatifications were identified. TEM-investigations showed analytical proofs of the sedimentary character of smectite formation in the Di Linh deposit. Parent muscovite was weathered in several steps in two different environments: (i) K-leaching and layer-wise alteration into kaolinite; (ii) further edge- controlled alteration of mica into lathlike montmorillonite particles under dissolution of kaolinite layers from former kaolinite-mica intergrowths. Mineralogical composition of the Di Linh bentonite with mainly montmorillonite and illite-rich illite-smectite interstratifications shows that the Di Linh bentonite can be a suitable barrier candidate in final repositories.
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| 2. |
- Hoang-Minh, Thao, et al.
(författare)
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Use of TEM-EDX for structural formula identification of clay minerals : a case study of Di Linh bentonite, Vietnam
- 2019
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Ingår i: Journal of applied crystallography. - : International Union of Crystallography (IUCr). - 0021-8898 .- 1600-5767. ; 52:1, s. 133-147
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Tidskriftsartikel (refereegranskat)abstract
- Transmission electron microscopy linked with energy-dispersive X-ray spectroscopy (TEM-EDX) was applied to characterize mineralogical signals ofweathering processes in the Di Linh bentonite deposit (Vietnam) and to visualize the effects of Na activation on the smectitic phases. Modelling of X ray diffraction patterns (oriented mount) was applied in order to refine the computed structural formula. X-ray diffraction, X-ray fluorescence and Fouriertransform infrared spectroscopy (FT-IR) methods were also applied to verify the TEM-EDX results. An Excel-based routine has been developed in this research to allow fast computation of structural formulae and classification of the investigated clay particles. This routine supports the acquirement of 100 300 TEM-EDX analyses as a representative set of individual particles for each sample. The Excel-based routine involves end members of different clay mineral groups and interstratifications with two or three members (e.g. illite smectite interstratifications – IS-ml; dioctahedral vermiculite–smectite interstratifications – diVS-ml; and kaolinite–montmorillonite–dioctahedral vermiculite interstratifications – KSV-ml). The routine is now freely available. According to the identification procedure, the <2 mm fraction of the Di Linh bentonite (Vietnam) is composed mainly of K- and charge-deficient illite smectite interstratifications (or diVS-ml): montmorillonite-rich randomly ordered (R0) type and illite-rich regularly ordered (R1) type. Additionally, Fe-poor KSV-ml was identified.Industrial Na activation of the Di Linh bentonite resulted in an increase of theR1 diVS-ml portion and dissolution of a large part of the smectite-rich phases.The TEM-EDX approach also gave analytical proof of a sedimentary processfor Di Linh smectite. The parent muscovite was altered in two different environments: (i) K-leaching and layer-wise alteration into kaolinite (weathering), and (ii) further edge-controlled alteration of mica into lath-like montmorillonite particles associated with a dissolution of kaolinite layers from the former kaolinite–mica intergrowths by heat impact (basalt flow).
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| 3. |
- Kasbohm, Jörn, et al.
(författare)
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Lab-scale performance of selected expandable clays under HLW repository conditions
- 2013
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Ingår i: Environmental Earth Sciences. - : Springer Science and Business Media LLC. - 1866-6280 .- 1866-6299. ; 69:8, s. 2569-2579
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Tidskriftsartikel (refereegranskat)abstract
- Smectite clay has been proposed for embedding canisters with highly radioactive waste in deep repositories because of its isolating capacity. Montmorillonite-rich bentonite is a premier buffer candidate for many national organizations that are responsible for disposal of such waste. Experience from the use of drilling mud at large depths indicates that other smectite clay minerals are more stable chemically and saponite is one of them. The physical properties of smectitic mixed-layer minerals like Friedland clay are known to be less sensitive to high salt contents and such clay may also be a buffer candidate. Montmorillonite-rich MX-80 clay, Greek saponite with a minor amount of palygorskite, and Friedland clay were investigated in hydrothermal tests with dense samples confined in oedometers with 95 °C temperature at one end, which was made of copper, and 35 °C at the other, for 8 weeks. A 1 % CaCl 2 solution was circulated through a filter at the cold end. At the end of the tests, the samples were sliced into three parts, which were tested with respect to expandability, hydraulic conductivity, and chemical composition. The tests showed that while the saponite was hardly changed at all and did not take up any copper, MX-80 underwent substantial changes in physical performance and adsorbed significant amounts of copper. The Friedland clay sample was intermediate in both respects
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| 4. |
- Nguyen, Thi Ngoc Phuong, 1993, et al.
(författare)
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Individual-, social- and policy- factors associated with smoking cessation among adult male cigarette smokers in Hanoi, Vietnam: a longitudinal study
- 2023
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Ingår i: BMC PUBLIC HEALTH. - : BioMed Central (BMC). - 1471-2458. ; 23:1
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Tidskriftsartikel (refereegranskat)abstract
- BackgroundNearly one-in-two Vietnamese men smoke cigarettes placing them among the highest tobacco consumers in the world. Despite the need for smoking cessation to curb the burden of tobacco-related diseases in Vietnam, this rate remains at less than 30%. Therefore, this study examines individual-, social- and policy factors associated with smoking cessation among adult male smokers in Vietnam.MethodsWe established a longitudinal International Tobacco Control study of male smokers in Hanoi, Vietnam, in September 2018. This paper analyses 1525 men who participated in baseline and one-year follow-up. We applied a weighted multivariable logistic regression to examine the association between smoking cessation and individual-, social- and policy predictors.ResultsAt follow-up, 14.8% of participants had quit smoking for at least 30 consecutive days during the last year. Among the persistent smokers, 56.6% expressed intention to quit smoking. Factors associated with smoking cessation included a lower number of cigarettes smoked per day (aOR = 0.96, 95% CI: 0.94, 0.99) and having several attempts to quit smoking (aOR = 2.16, 95% CI 1.13, 4.12). Intention to quit smoking was associated with multiple quit attempts, a chronic condition diagnosis, more tobacco-related knowledge, greater self-efficacy, and more worries about their future health. The perceived impact of smoke-free policy and health warning labels were positively associated with intention to quit at any stage.ConclusionsInterventions aimed at increasing smoking cessation should focus on all aspects of individual, social, and policy factors. Persistent smokers are more motivated to quit if they have made multiple quit attempts, more self-efficacy of quitting and worried about their future health, indicating that increasing smokers' beliefs and knowledge may be important for behavioural change. Health warning labels and tobacco taxation policies should be maintained and promoted as they are perceived to be particularly useful for persistent smokers' intention to quit.
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| 5. |
- Pusch, Roland, et al.
(författare)
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Deep disposal of spent nuclear fuel
- 2019
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Ingår i: Waste Management and the Environment IX. - : WIT Press. ; , s. 399-414
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Konferensbidrag (refereegranskat)abstract
- An alternative but still untested approach is to dispose of highly radioactive waste in very deep boreholes, a concept being considered in the UK and the US. One version of this concept known as Very-Deep-Hole (VDH) storage proposes drilling of up to 4 km deep holes and placing in a series of stacked super-containers sealed by a combination of dense clay and concrete. In this case the risk of losing clay material by dispersion and erosion where the holes intersect fracture zones would be eliminated by casting concrete of a new type. VDH containment relies on the use of copper or Navy Bronze tubes filled with dense clay in the upper parts of the holes and with clay-embedded canisters with waste in the lower parts. The maturation and isolating function of the clay seals in the holes and their chemical interaction with concrete and waste canisters are considered and assessed. The work has focused on the mechanical testing and microscope investigations of the clay/concrete. Hydrothermally treated clay and concrete, exposed to 20-150°C, which represents the conditions over the entire length of a real VDH, have been tested. The recorded impact of strong heating showed stiffening and some reduction in hydraulic conductivity of the clay and concrete.
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| 6. |
- Pusch, Roland, et al.
(författare)
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Degradation Mechanisms in Smectitic Clay for Isolating Radioactive Waste
- 2019
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Ingår i: Journal of Earth Sciences and Geotechnical Engineering. - UK : Scientific Press International Limited. - 1792-9040 .- 1792-9660. ; 9:3, s. 115-130
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Tidskriftsartikel (refereegranskat)abstract
- Most of the proposed techniques for chemical shielding of radioactive waste implies use of smectite clay, which degrades according to a well-known scheme. Since such “buffer” clay has to serve for many thousands of years, the mechanisms in the unavoidable long-term degradation process must be understood and accounted for as described in the paper. In addition to conversion of smectite to non-expandable minerals cementation by precipitation of siliceous matter created in the degradation process is of concern since it can reduce the self-sealing capacity of desiccated or mechanically damaged clay.
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| 7. |
- Pusch, Roland, et al.
(författare)
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Disposal of Low- and Intermediate-Level Radioactive Waste
- 2019
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Ingår i: Journal of Earth Sciences and Geotechnical Engineering. - UK : Scientific Press International Limited. - 1792-9040 .- 1792-9660. ; 9:3, s. 237-272
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Tidskriftsartikel (refereegranskat)abstract
- As for isolation of high-level radioactive waste by use of smectite clay it serves very well also for hindering radionuclides from low- and intermediate-level waste to contaminate groundwater. It can be used for minimizing groundwater flow through and along waste packages and for providing them with ductile embedment for eliminating the risk of damage caused by displacements in host rock or concrete vaults. The clay can have the form of liners placed and compacted on site over vaults constructed on the ground surface, or consist of compacted blocks of clay granules that are tightly placed around waste packages in underground drifts and rooms. In either case the initially incompletely water saturated clay will swell in conjunction with water uptake until tight contact with the confining medium has been established. The clay seals must be sufficiently dense to fulfill criteria set with respect to hydraulic conductivity and swelling capacity, paying due attention to the salt content in the porewater. Their physical and chemical stabilities must be acceptable in short- and long-term perspectives, which is a few hundred years for most low-level wastes up to tens of thousands of years for long-lived waste.
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| 8. |
- Pusch, Roland, et al.
(författare)
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Holmehus clay — A Tertiary smectitic clay of potential use for isolation of hazardous waste
- 2015
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Ingår i: Engineering Geology. - : Elsevier BV. - 0013-7952 .- 1872-6917. ; 188, s. 38-47
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Tidskriftsartikel (refereegranskat)abstract
- The Danish Tertiary Holmehus clay belongs to the series of illite-smectite mixed-layer clays in northern Europe and has a potential to serve as an effective engineered barrier for isolating hazardous waste. Mineralogical specification was made of the components illite/smectite mixed-layer and dioctahedral vermiculite/smectite mixed-layer structures. The lower content of expandable phase than of smectite- rich clays like MX-80 gives somewhat higher hydraulic conductivity and somewhat lower swelling pressure but both are deemed suitable for isolating canisters with high-level radioactive waste in deeprepositories for densities at water saturation of at least 1900 kg/m3. The lower swelling pressure, the potential of being chemically more stable, and the high buffer capacity by providing dissolved Si makes Holmehus clay a candidate for use in both deep and near-surface repositories.
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| 9. |
- Pusch, Roland, et al.
(författare)
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Mechanisms Involved in Maturation of Clay Seals in Boreholes for Storing Spent Reactor Fuel
- 2019
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Ingår i: Journal of Earth Sciences and Geotechnical Engineering. - UK : Scientific Press International Limited. - 1792-9040 .- 1792-9660. ; 9:3, s. 197-226
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Tidskriftsartikel (refereegranskat)abstract
- Smectite clay, especially montmorillonite, is proposed for isolating canisters containing highly radioactive waste (HLW) like spent reactor fuel placed in deep boreholes. It is used for minimizing groundwater flow around and along waste packages (“Buffer Clay”) and for providing them with ductile embedment for eliminating risk of canister damage caused by displacements in the host rock. The clay has the form of heavily compacted blocks of granules that swell in conjunction with water uptake until their full hydration potential has been utilized. The dense clay blocks are fitted in perforated supercontainers that are submerged in smectite mud. The long-term chemical stability of the clay is sufficient for providing the required waste-isolating capacity, which is primarily supplied by the heavyness of stagnant, very salt groundwater at depth.
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| 10. |
- Pusch, Roland, et al.
(författare)
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Pilot study of the performance of organic and clay-based sun creames
- 2016
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Ingår i: Journal of Earth Sciences and Geotechnical Engineering. - : Scientific Press International Limited. - 1792-9040 .- 1792-9660. ; 6:3, s. 319-329
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Tidskriftsartikel (refereegranskat)abstract
- Sun protection creams based on smectite(S) and mixed-layer (IS) clays in glycerol emulsions were compared to commercial organic creams with respect to UV penetration. For very thin cream films the organic creams were superior while for thicker films the clay creams gave lower UV penetration. The investigated I/S mixed-layer clay gave more effective protection than Fe-poor S-clays because of better particle alignment and thicker particles. The content of iron compounds was found to be of greatest importance as demonstrated by tests with different amounts of Fe2O3.
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