| 1. |
- Buyanova, Irina A, et al.
(författare)
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Unusual effects of hydrogen on electronic and lattice properties of GaNP alloys
- 2006
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Ingår i: Physica. B, Condensed matter. - : Elsevier BV. - 0921-4526 .- 1873-2135. ; 376, s. 568-570
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Tidskriftsartikel (refereegranskat)abstract
- Hydrogen incorporation is shown to cause passivation of various N-related localized states and partial neutralization of N-induced changes in the electronic structure of the GaNxP1-x alloys with x < 0.008. According to the performed X-ray diffraction measurements, the hydrogenation is also found to cause strong expansion of the GaNP lattice which even changes from a tensile strain in the as-grown GaNP epilayers to a compressive strain in the post-hydrogenated structures with the highest H concentration. By comparing results obtained using two types of hydrogen treatments, i.e. by implantation from a Kaufman source and by using a remote dc H plasma, the observed changes are shown to be inherent to H due to its efficient complexing with N atoms, whereas possible effects of implantation damage are only marginal. (c) 2005 Elsevier B.V. All rights reserved.
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| 2. |
- Buyanova, Irina, 1960-, et al.
(författare)
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Analysis of band anticrossing in GaNxP1-x alloys
- 2004
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 70, s. 085209-
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Tidskriftsartikel (refereegranskat)abstract
- Temperature-dependent absorption, photoluminescence excitation, and spectroscopic ellipsometry measurements are employed to accurately determine compositional and temperature dependences of the conduction band (CB) states in GaNP alloys. The CB edge and the higher lying Γc CB minimum (CBM) are shown to exhibit an apparently anticrossing behavior, i.e., the N-induced redshift of the bandgap energy is accompanied by a matching blueshift of the Γc CBM. The obtained data can be phenomenologically described by the band anticrossing model. By considering strong temperature dependence of the energy of the interacting N level, which has largely been overlooked in earlier studies of GaNP, the interacting N level can be attributed to the isolated substitutional NP and the coupling parameter is accurately determined.
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| 3. |
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| 4. |
- Buyanova, Irina, 1960-, et al.
(författare)
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Direct experimental evidence for unusual effects of hydrogen on the electronic and vibrational properties of GaNxP1−x alloys : a proof for a general property of dilute nitrides
- 2004
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Ingår i: Physical Review B Condensed Matter. - 0163-1829 .- 1095-3795. ; 70:24, s. 245215-245219
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Tidskriftsartikel (refereegranskat)abstract
- Direct experimental evidence for dramatic effects of hydrogen incorporation on the electronic structure and lattice properties of GaNxP1−x alloys is presented. By employing photoluminescence excitation spectroscopy, postgrowth hydrogenation is shown to reopen the band gap of the GaNP alloys and to efficiently reduce the N-induced coupling between the conduction band states. By Raman spectroscopy, these effects are shown to be accompanied by hydrogen-induced breaking of the Ga-P bond in the alloy, evident from disappearance of the corresponding vibrational mode. According to the performed Raman and x-ray diffraction measurements, the hydrogenation is also found to cause a strong expansion of the GaNP lattice, which changes the sign of strain from tensile in the as-grown GaNP epilayers to compressive in the posthydrogenated structures, due to the formation of complexes between N and H.
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| 5. |
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| 6. |
- Buyanova, Irina, 1960-, et al.
(författare)
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Effects of N incorporation on the electronic structure of GaNP : Origin of the 2.87 eV optical transition
- 2005
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Konferensbidrag (refereegranskat)abstract
- Temperature dependent photoluminescence excitation (PLE) spectroscopy is employed to evaluate basic physical properties of the 2.87 eV absorption peak, recently discovered (I. A. Buyanova et al, PRB 69, 201303 (2004)) in the GaNxP1-x alloys. Whereas appearance of this transition is found to be facilitated by incorporation of N and also H atoms, its intensity does not scale with N content. This questions a possible association of this feature with a N-related localized state. Based on the results of temperature dependent measurements, the involved state is concluded to have a non-$\Gamma $ character. Excitation of the known N-related localized states via this state is found to be non-selective, opposed to that between the N-related centers. The observed properties are shown to be hardly consistent with those predicted for the higher lying localized state of the isolated N atom derived from the Γ conduction band minimum (CBM). Alternative explanations for the ``2.87 eV'' state as being due to either a t2 component of the X3c (or L1c CBM or a level arising from a complex of N and H (in some form) are also discussed.
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| 7. |
- Buyanova, Irina, 1960-, et al.
(författare)
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Experimental evidence for N-induced strong coupling of host conduction band states in GaNP : insight into the dominant mechanism for giant band-gap bowing
- 2004
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - : American Physical Society. - 1098-0121 .- 1550-235X. ; 69, s. 201303-
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Tidskriftsartikel (refereegranskat)abstract
- Direct evidence for N-induced strong coupling of host conduction band (CB) states in GaNxP1-x is provided by photoluminescence excitation. It is manifested as: (1) a drastic change in the ratio of oscillator strengths between the optical transitions involving the CB minimum (CBM) and the high-lying Γ CB state; (2) a strong blueshift of the Γ CB state with increasing x accompanying a redshift of the CBM, (3) pinning of the localized N states and a newly emerging t2 (L or X3) CB state. These findings shed new light on the issue of the dominant mechanism responsible for the giant band-gap bowing of dilute nitrides.
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| 8. |
- Buyanova, Irina, 1960-, et al.
(författare)
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Hydrogen-induced improvements in optical quality of GaNAs alloys
- 2003
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 82:21, s. 3662-3665
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Tidskriftsartikel (refereegranskat)abstract
- Strong suppression of potential fluctuations in the band edges of GaNAs alloys due to postgrowth hydrogen treatment, which is accompanied by a reopening of the alloy band gap, is revealed from temperature-dependent photoluminescence (PL) and PL excitation measurements. The effect likely indicates preferential trapping of hydrogen near the lattice sites with the highest nitrogen content. A remarkable improvement in the radiative efficiency of the alloys at room temperature is also demonstrated and is ascribed to efficient hydrogen passivation of competing nonradiative centers.
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| 9. |
- Buyanova, Irina, 1960-, et al.
(författare)
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Hydrogen passivation of nitrogen in GaNAs and GaNP alloys : How many H atoms are required for each N atom?
- 2007
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 90:2, s. 021920-
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Tidskriftsartikel (refereegranskat)abstract
- Secondary ion mass spectrometry and photoluminescence are employed to evaluate the origin and efficiency of hydrogen passivation of nitrogen in GaNAs and GaNP. The hydrogen profiles are found to closely follow the N distributions, providing unambiguous evidence for their preferential binding as the dominant mechanism for neutralization of N-induced modifications in the electronic structure of the materials. Though the exact number of H atoms involved in passivation may depend on the conditions of the H treatment and the host matrixes, it is generally found that more than three H atoms are required to bind to a N atom to achieve full passivation for both alloys. © 2007 American Institute of Physics.
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| 10. |
- Buyanova, Irina, 1960-, et al.
(författare)
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On spin injection in GaMnN/InGaN Light-Emitting Diodes
- 2004
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Ingår i: 3rd International Conference on Physics and Applications of Spin-Related Phenomena in Semiconductors PASPS III,2004.
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)
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