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Sökning: WFRF:(Jin Yanting)

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1.
  • Jin, Yanting, et al. (författare)
  • Understanding Fluoroethylene Carbonate and Vinylene Carbonate Based Electrolytes for Si Anodes in Lithium Ion Batteries with NMR Spectroscopy
  • 2018
  • Ingår i: Journal of the American Chemical Society. - : American Chemical Society (ACS). - 1520-5126 .- 0002-7863. ; 140:31, s. 9854-9867
  • Tidskriftsartikel (refereegranskat)abstract
    • Fluoroethylene carbonate (FEC) and vinylene carbonate (VC) are widely used as electrolyte additives in lithium ion batteries. Here we analyze the solid electrolyte interphase (SEI) formed on binder-free silicon nanowire (SiNW) electrodes in pure FEC or VC electrolytes containing 1 M LiPF6by solid-state NMR with and without dynamic nuclear polarization (DNP) enhancement. We find that the polymeric SEIs formed in pure FEC or VC electrolytes consist mainly of cross-linked poly(ethylene oxide) (PEO) and aliphatic chain functionalities along with additional carbonate and carboxylate species. The formation of branched fragments is further confirmed by13C-13C correlation NMR experiments. The presence of cross-linked PEO-type polymers in FEC and VC correlates with good capacity retention and high Coulombic efficiencies of the SiNWs. Using29Si DNP NMR, we are able to probe the interfacial region between SEI and the Si surface for the first time with NMR spectroscopy. Organosiloxanes form upon cycling, confirming that some of the organic SEI is covalently bonded to the Si surface. We suggest that both the polymeric structure of the SEI and the nature of its adhesion to the redox-active materials are important for electrochemical performance.
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2.
  • Zhang, Yanting, et al. (författare)
  • Two-Dimensional Defective Boron-Doped Niobic Acid Nanosheets for Robust Nitrogen Photofixation
  • 2021
  • Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-0851 .- 1936-086X. ; 15:11, s. 17820-17830
  • Tidskriftsartikel (refereegranskat)abstract
    • Direct nitrogen photofixation is a feasible solution toward sustainable production of ammonia under mild conditions. However, the generation of active sites for solar-dirven nitrogen fixation not only limits the fundamental understanding of the relationship among light absorption, charge transfer, and catalytic efficiency but also influences the photocatalytic activity. Herein, we report two-dimensional boron-doped niobic acid nanosheets with oxygen vacancies (B-V-o-HNbO3 NSs) for efficient N-2 photofixation in the absence of any scavengers and cocatalysts. Impressively, B-V-o-HNbO3 NS as a model catalyst achieves the enhanced ammonia evolution rate of 170 mu mol g(cat)(-1) h(-1) in pure water under visible-light irradiation. The doublet coupling representing (NH4+)-N-15 in an isotopic labeling experiment and in situ infrared spectra confirm the reliable ammonia generation. The experimental analysis and density functional theory (DFT) calculations indicate that the strong synergy of boron dopant and oxygen vacancy regulates band structure of niobic acid, facilitates photogenerated charge transfer, reduces free energy barriers, accelerates reaction kinetics, and promotes the high rates of ammonia evolution. This work provides a general strategy to design active photocatalysts toward solar N-2 conversion.
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