| 1. |
- Biermann, Max, 1989, et al.
(författare)
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Lessons learned from the Preem-CCS project – a pioneering Swedish-Norwegian collaboration showcasing the full CCS chain
- 2022
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Ingår i: 16th Greenhouse Gas Control Technologies Conference 2022 (GHGT-16).
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Konferensbidrag (refereegranskat)abstract
- This paper presents the key findings of the Preem-CCS project, a co-funded Swedish-Norwegian R&D collaboration that investigated CO2 capture from the Preem refineries in Sweden, and subsequent ship transport of captured CO2 for permanent storage on the Norwegian Continental Shelf. The project was conducted 2019-2022 and accomplished: 1) the on-site pilot scale demonstration of amine-based CO2 absorption using Aker Carbon Capture’s mobile test unit (MTU), 2) an in-depth investigation of energy-efficient heat supply for CO2 capture, 3) a detailed techno-economic evaluation of a feasible carbon capture and storage (CCS) chain (from CO2 capture in Sweden to ship transport to Norway), and 4) an investigation of relevant legal and regulatory aspects of trans-border CO2 transport between Sweden and Norway.
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| 2. |
- Kjärstad, Jan, 1956, et al.
(författare)
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Transforming the energy system in Västra Götaland and Halland – linking short term actions to long term goals
- 2015
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- This study analyzes pathways to meet EU, national and regional targets for CO2 emissions, energy efficiency and penetration of renewable energy in the Swedish part of the Kattegat-Skagerrak region (KASK-SE), i.e. more specifically in the counties of Västra Götaland (VGR) and Halland. Special focus is placed on four areas: The potential for energy savings in the building sector, energy savings and fuel shifting in the energy intensive industry, large-scale deployment of renewables in the electricity generation sector and greenhouse gas emission reductions in the transport sector. The energy savings are through the implementation of different energy efficiency measures.
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| 3. |
- Robba, Chiara, et al.
(författare)
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Oxygen targets and 6-month outcome after out of hospital cardiac arrest : a pre-planned sub-analysis of the targeted hypothermia versus targeted normothermia after Out-of-Hospital Cardiac Arrest (TTM2) trial
- 2022
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Ingår i: Critical Care. - : Springer Science and Business Media LLC. - 1364-8535 .- 1466-609X. ; 26, s. 1-13
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Tidskriftsartikel (refereegranskat)abstract
- Background: Optimal oxygen targets in patients resuscitated after cardiac arrest are uncertain. The primary aim of this study was to describe the values of partial pressure of oxygen values (PaO2) and the episodes of hypoxemia and hyperoxemia occurring within the first 72 h of mechanical ventilation in out of hospital cardiac arrest (OHCA) patients. The secondary aim was to evaluate the association of PaO2 with patients’ outcome. Methods: Preplanned secondary analysis of the targeted hypothermia versus targeted normothermia after OHCA (TTM2) trial. Arterial blood gases values were collected from randomization every 4 h for the first 32 h, and then, every 8 h until day 3. Hypoxemia was defined as PaO2 < 60 mmHg and severe hyperoxemia as PaO2 > 300 mmHg. Mortality and poor neurological outcome (defined according to modified Rankin scale) were collected at 6 months. Results: 1418 patients were included in the analysis. The mean age was 64 ± 14 years, and 292 patients (20.6%) were female. 24.9% of patients had at least one episode of hypoxemia, and 7.6% of patients had at least one episode of severe hyperoxemia. Both hypoxemia and hyperoxemia were independently associated with 6-month mortality, but not with poor neurological outcome. The best cutoff point associated with 6-month mortality for hypoxemia was 69 mmHg (Risk Ratio, RR = 1.009, 95% CI 0.93–1.09), and for hyperoxemia was 195 mmHg (RR = 1.006, 95% CI 0.95–1.06). The time exposure, i.e., the area under the curve (PaO2-AUC), for hyperoxemia was significantly associated with mortality (p = 0.003). Conclusions: In OHCA patients, both hypoxemia and hyperoxemia are associated with 6-months mortality, with an effect mediated by the timing exposure to high values of oxygen. Precise titration of oxygen levels should be considered in this group of patients. Trial registration: clinicaltrials.gov NCT02908308, Registered September 20, 2016.
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| 4. |
- Robba, Chiara, et al.
(författare)
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Ventilatory settings in the initial 72 h and their association with outcome in out-of-hospital cardiac arrest patients : a preplanned secondary analysis of the targeted hypothermia versus targeted normothermia after out-of-hospital cardiac arrest (TTM2) trial
- 2022
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Ingår i: Intensive Care Medicine. - : Springer Science and Business Media LLC. - 0342-4642 .- 1432-1238. ; 48:8, s. 1024-1038
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Tidskriftsartikel (refereegranskat)abstract
- Purpose: The optimal ventilatory settings in patients after cardiac arrest and their association with outcome remain unclear. The aim of this study was to describe the ventilatory settings applied in the first 72 h of mechanical ventilation in patients after out-of-hospital cardiac arrest and their association with 6-month outcomes. Methods: Preplanned sub-analysis of the Target Temperature Management-2 trial. Clinical outcomes were mortality and functional status (assessed by the Modified Rankin Scale) 6 months after randomization. Results: A total of 1848 patients were included (mean age 64 [Standard Deviation, SD = 14] years). At 6 months, 950 (51%) patients were alive and 898 (49%) were dead. Median tidal volume (VT) was 7 (Interquartile range, IQR = 6.2–8.5) mL per Predicted Body Weight (PBW), positive end expiratory pressure (PEEP) was 7 (IQR = 5–9) cmH20, plateau pressure was 20 cmH20 (IQR = 17–23), driving pressure was 12 cmH20 (IQR = 10–15), mechanical power 16.2 J/min (IQR = 12.1–21.8), ventilatory ratio was 1.27 (IQR = 1.04–1.6), and respiratory rate was 17 breaths/minute (IQR = 14–20). Median partial pressure of oxygen was 87 mmHg (IQR = 75–105), and partial pressure of carbon dioxide was 40.5 mmHg (IQR = 36–45.7). Respiratory rate, driving pressure, and mechanical power were independently associated with 6-month mortality (omnibus p-values for their non-linear trajectories: p < 0.0001, p = 0.026, and p = 0.029, respectively). Respiratory rate and driving pressure were also independently associated with poor neurological outcome (odds ratio, OR = 1.035, 95% confidence interval, CI = 1.003–1.068, p = 0.030, and OR = 1.005, 95% CI = 1.001–1.036, p = 0.048). A composite formula calculated as [(4*driving pressure) + respiratory rate] was independently associated with mortality and poor neurological outcome. Conclusions: Protective ventilation strategies are commonly applied in patients after cardiac arrest. Ventilator settings in the first 72 h after hospital admission, in particular driving pressure and respiratory rate, may influence 6-month outcomes.
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| 5. |
- Allum, Felix, et al.
(författare)
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Coulomb explosion imaging of CH3I and CH2CII photodissociation dynamics
- 2018
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Ingår i: Journal of Chemical Physics. - : AIP Publishing. - 0021-9606 .- 1089-7690. ; 149:20
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Tidskriftsartikel (refereegranskat)abstract
- The photodissociation dynamics of CH3I and CH2CII at 272 nm were investigated by time-resolved Coulomb explosion imaging, with an intense non-resonant 815nmprobe pulse. Fragment ion momenta over a widem/z range were recorded simultaneously by coupling a velocity map imaging spectrometer with a pixel imaging mass spectrometry camera. For both molecules, delay-dependent pump-probe features were assigned to ultraviolet-induced carbon-iodine bond cleavage followed by Coulomb explosion. Multi-mass imaging also allowed the sequential cleavage of both carbon-halogen bonds in CH2ClI to be investigated. Furthermore, delay-dependent relative fragment momenta of a pair of ions were directly determined using recoil-frame covariance analysis. These results are complementary to conventional velocity map imaging experiments and demonstrate the application of time-resolved Coulomb explosion imaging to photoinduced real-time molecular motion.
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| 6. |
- Biermann, Max, 1989, et al.
(författare)
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Partial capture from refineries through utilization of existing site energy systems
- 2021
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Ingår i: 15th Greenhouse Gas Control Technologies Conference 2021, GHGT 2021. - : Elsevier BV.
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Konferensbidrag (refereegranskat)abstract
- Many studies indicate that carbon capture and storage operations need to be ramped up in the coming decades to limit global warming to well-below 2°C. Partial CO2 capture from carbon-intensive industrial processes is a promising starting point for initial CO2 transport and storage infrastructure projects, such as the Norwegian full-chain CCS project “Northern Lights”, since specific capture cost (€/t CO2) for single-stack capture can be kept low compared to full capture from all, often less suitable stacks. This work highlights the importance of utilizing existing site energy systems to avoid significant increase in marginal abatement cost when moving from partial to full capture. A systematic and comprehensive techno-economic approach is applied that identifies a mix of heat supply sources with minimum cost based on a detailed analysis of available heat and capacity within the existing site energy system. Time-dependent variations are considered via multi-period, linear optimization. For single-stack capture from the hydrogen production unit (~0.5 Mt CO2 p.a.) of a Swedish refinery in the context of the current energy system, we find avoidance cost for the capture plant (liquefaction, ship transport, and storage excluded)of 42 €/t CO2-avoided that is predominantly driven by steam raised from available process heat in existing coolers (~6 €/t steam). For full capture from all major stacks (~1.4 Mt CO2 p.a.), the avoidance cost becomes twice as high (86 €/t CO2-avoided) due to heat supply from available heat and existing boiler capacity (combustion of natural gas) at costs of ~20€/t steam. The analysis shows that very few investments in new steam capacity are required, and thus, that the utilization of existing site energy systems is important for lowering capture cost significantly, and thus the whole-chain cost for early CCS projects.
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| 7. |
- Brasse, Felix, et al.
(författare)
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Time-resolved inner-shell photoelectron spectroscopy : From a bound molecule to an isolated atom
- 2018
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Ingår i: Physical Review A: covering atomic, molecular, and optical physics and quantum information. - 2469-9926 .- 2469-9934. ; 97:4
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Tidskriftsartikel (refereegranskat)abstract
- Due to its element and site specificity, inner-shell photoelectron spectroscopy is a widely used technique to probe the chemical structure of matter. Here, we show that time-resolved inner-shell photoelectron spectroscopy can be employed to observe ultrafast chemical reactions and the electronic response to the nuclear motion with high sensitivity. The ultraviolet dissociation of iodomethane (CH3I) is investigated by ionization above the iodine 4d edge, using time-resolved inner-shell photoelectron and photoion spectroscopy. The dynamics observed in the photoelectron spectra appear earlier and are faster than those seen in the iodine fragments. The experimental results are interpreted using crystal-field and spin-orbit configuration interaction calculations, and demonstrate that time-resolved inner-shell photoelectron spectroscopy is a powerful tool to directly track ultrafast structural and electronic transformations in gas-phase molecules.
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| 8. |
- Burt, Michael, et al.
(författare)
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Coulomb-explosion imaging of concurrent CH2BrI photodissociation dynamics
- 2017
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Ingår i: Physical Review A: covering atomic, molecular, and optical physics and quantum information. - 2469-9926 .- 2469-9934. ; 96:4
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Tidskriftsartikel (refereegranskat)abstract
- The dynamics following laser-induced molecular photodissociation of gas-phase CH2BrI at 271.6 nm were investigated by time-resolved Coulomb-explosion imaging using intense near-IR femtosecond laser pulses. The observed delay-dependent photofragment momenta reveal that CH2BrI undergoes C-I cleavage, depositing 65.6% of the available energy into internal product states, and that absorption of a second UV photon breaks the C-Br bond of C(H)2Br. Simulations confirm that this mechanism is consistent with previous data recorded at 248 nm, demonstrating the sensitivity of Coulomb-explosion imaging as a real-time probe of chemical dynamics.
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| 9. |
- Haraldsson, Joakim, 1990-, et al.
(författare)
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Taxonomy, Saving Potentials and Key Performance Indicators for Energy End-Use and Greenhouse Gas Emissions in the Aluminium Industry and Aluminium Casting Foundries
- 2021
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Ingår i: Energies. - : MDPI. - 1996-1073. ; 14:12
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Tidskriftsartikel (refereegranskat)abstract
- Increasing energy efficiency within the industrial sector is one of the main approachesin order to reduce global greenhouse gas emissions. The production and processing of aluminiumis energy and greenhouse gas intensive. To make well-founded decisions regarding energy effi-ciency and greenhouse gas mitigating investments, it is necessary to have relevant key performanceindicators and information about energy end-use. This paper develops a taxonomy and key perfor-mance indicators for energy end-use and greenhouse gas emissions in the aluminium industry andaluminium casting foundries. This taxonomy is applied to the Swedish aluminium industry andtwo foundries. Potentials for energy saving and greenhouse gas mitigation are estimated regardingstatic facility operation. Electrolysis in primary production is by far the largest energy using andgreenhouse gas emitting process within the Swedish aluminium industry. Notably, almost half of thetotal greenhouse gas emissions from electrolysis comes from process-related emissions, while theother half comes from the use of electricity. In total, about 236 GWh/year (or 9.2% of the total energyuse) and 5588–202,475 tonnes CO2eq/year can be saved in the Swedish aluminium industry and twoaluminium casting foundries. The most important key performance indicators identified for energyend-use and greenhouse gas emissions are MWh/tonne product and tonne CO2-eq/tonne product.The most beneficial option would be to allocate energy use and greenhouse gas emissions to boththe process or machine level and the product level, as this would give a more detailed picture of thecompany’s energy use and greenhouse gas emissions.
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| 10. |
- Ingvarsson, Simon, 1992, et al.
(författare)
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Lignin extraction in chemical pulp mills: The role of flexible operation
- 2024
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Ingår i: Sustainable Chemistry for the Environment. - 2949-8392. ; 7
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Tidskriftsartikel (refereegranskat)abstract
- Lignin extracted from black liquor in chemical pulp mills can potentially replace fossil carbon feedstocks in fuels and materials, thereby increasing the economic and environmental added values of woody biomass. However, since lignin extraction reduces the electricity generation of the mill, the added value depends on the characteristics of the electricity market in which the mill operates. In this study, a model mill is exposed to two different electricity price profiles: the low and steady prices of south-central Sweden in Year 2019; and the high and volatile prices of the same region in Year 2022. For the model mill, investments in lignin extraction designed to increase pulp production are economically viable and have low levels of sensitivity to electricity price levels and price volatility. The viability of lignin extraction without increased pulp production depends on the relationship between the electricity and lignin prices. With stable electricity prices, or steady mill operation, a rule-of-thumb holds that for lignin extraction to be viable, the lignin price (€/t) must be 1.8-times the average electricity price (€/MWh) plus 40 €/t for the supply of chemicals. With volatile electricity prices and flexible operation of the recovery boiler, the mill can shift the loss in electricity sales to low-price hours, thereby saving 15–70 % of the operational costs of lignin extraction, as compared to steady operation. This effect can be further enhanced by increasing the capacity of the lignin extraction process or extending the size of the black liquor storage tank. The proposed flexibility measures allow the market-integrated pulp mill to export lignin to replace fossil carbon supplies in other sectors, while supporting the electricity system during hours with high demand and low supply.
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