| 1. |
- Kikas, A., et al.
(författare)
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Effect of phase composition on X-ray absorption spectra of ZrO2 thin films
- 2007
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Ingår i: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048. ; 156, s. 303-306
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Tidskriftsartikel (refereegranskat)abstract
- The X-ray photoabsorption spectra of ZrO2 films with different phase compositions were measured. The analysis of the results obtained shows that due to the site-sensitivity the X-ray photoabsorption spectroscopy is an attractive method for characterization of the ZrO2 structure. This allows application of the X-ray spectroscopy in investigation of the crystal structure in the various stages of the thin film growth including the initial stage of the ZrO2 growth. (c) 2006 Elsevier B.V. All rights reserved.
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| 2. |
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| 3. |
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| 4. |
- Seppet, E. K., et al.
(författare)
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Functional complexes of mitochondria with MgATPase of myofibrils and sarcoplasmic reticulum in muscle cells
- 2001
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Ingår i: Biochimica et Biophysica Acta - Bioenergetics. - Amsterdam : Elsevier. - 0005-2728 .- 1879-2650. ; 1504:2-3, s. 379-395
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Tidskriftsartikel (refereegranskat)abstract
- Regulation of mitochondrial respiration in situ in the muscle cells was studied by using fully permeabilized muscle fibers and cardiomyocytes. The results show that the kinetics of regulation of mitochondrial respiration in situ by exogenous ADP are very different from the kinetics of its regulation by endogenous ADP. In cardiac and m. soleus fibers apparent Km for exogenous ADP in regulation of respiration was equal to 300–400 µM. However, when ADP production was initiated by intracellular ATPase reactions, the ADP concentration in the medium leveled off at about 40 µM when about 70% of maximal rate of respiration was achieved. Respiration rate maintained by intracellular ATPases was suppressed about 20–30% during exogenous trapping of ADP with excess pyruvate kinase (PK, 20 IU/ml) and phosphoenolpyruvate (PEP, 5 mM). ADP flux via the external PK+PEP system was decreased by half by activation of mitochondrial oxidative phosphorylation. Creatine (20 mM) further activated the respiration in the presence of PK+PEP. It is concluded that in oxidative muscle cells mitochondria behave as if they were incorporated into functional complexes with adjacent ADP producing systems – with the MgATPases in myofibrils and Ca,MgATPases of sarcoplasmic reticulum.
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| 5. |
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| 6. |
- Galnander, B, et al.
(författare)
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Non-destructive chemical analysis of sandwich structures by means of soft X-ray emission
- 1999
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Ingår i: THIN SOLID FILMS. - : ELSEVIER SCIENCE SA. - 0040-6090. ; 344, s. 35-38
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- Soft X-ray emission spectroscopy provides information about elemental composition, including the light elements, as well as the chemical bonding. The probe depth reaches hundreds of nanometers but under certain conditions considerable surface sensitivity
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| 7. |
- Kaambre, T., et al.
(författare)
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Resonant inelastic X-ray scattering at the Be 1s edge in BeO
- 2007
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Ingår i: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048. ; 156, s. 299-302
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Tidskriftsartikel (refereegranskat)abstract
- We present the resonant inelastic X-ray scattering (RIXS) spectra of BeO at the Be 1s photoabsorption edge. The RIXS spectra excited in the vicinity of the core exciton resonance show two principal features: the scattering on a valence exciton (which at higher excitation energies verges into the characteristic K alpha emission), and a remarkably strong energy loss side-band to the elastic scattering peak, which has a maximum width of 6 eV and has intensity, at resonance, comparable to the valence scattering. The energy loss side-band appears to result from rapid lattice relaxation at the absorption site on the X-ray scattering time-span. (c) 2006 Elsevier B.V. All rights reserved.
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| 8. |
- Kikas, A., et al.
(författare)
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Resonant inelastic x-ray scattering and UV-VUV luminescence at the Be 1s edge in BeO
- 2010
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Ingår i: Journal of Physics: Condensed Matter. - : IOP Publishing. - 1361-648X .- 0953-8984. ; 22:37
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Tidskriftsartikel (refereegranskat)abstract
- We carried out a combined study of UV-VUV luminescence and resonant x-ray emission from BeO single crystals with incident photon energies in the vicinity of the Be 1s absorption edge. The x-ray emission spectra show that at the Be 1s photoabsorption edge the lattice relaxation processes in the excitation site take place already on the timescale of the radiative decay of the core excitation. Comparison of the x-ray emission and the luminescence spectra indicates that the maximum energy loss of the process of lattice relaxation during the decay of inner-shell holes is similar to the loss that occurs in the self-trapping process of valence excitons. The possible decay channels of core excitations have been discussed and the mechanism for the creation of 5.2 eV luminescence at the photoabsorption resonances has been suggested.
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| 9. |
- Kikas, A, et al.
(författare)
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Resonant photoemission of CoCl2
- 1999
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Ingår i: JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA. - : ELSEVIER SCIENCE BV. - 0368-2048. ; 103, s. 745-749
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- We present the results of a study of the resonant photoemission from polycrystalline in situ evaporated thin him of CoCl2 excited at 2p photoabsorption edges of Co and Cl. At the Co 2p-->3d resonance strong enhancement was observed for the Co 3p, valence
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| 10. |
- Nyberg, M., et al.
(författare)
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Bond formation in titanium fulleride compounds studied through x-ray emission spectroscopy
- 2001
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Ingår i: Physical Review B. Condensed Matter and Materials Physics. - 1098-0121 .- 1550-235X. ; 63:11, s. art. no.-115117
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Tidskriftsartikel (refereegranskat)abstract
- The geometric and electronic structures of titanium fulleride complexes have been studied at the gradient corrected density-functional theory level by using various C60Tix (x=1,2) clusters. The cluster with the Ti atom binding on the six-ring site (eta (6)) Of the fullerene is shown to be lower in energy than those with Ti atom adsorbed on either five-ring (eta (5)) Or bridge(eta (2)) sites. The bond formation for titanium fulleride has further been examined by calculated nonresonant, resonant, and off-resonant . x-ray emission spectra of the clusters, and a comparison to the experimental counterpart. The examination shows that only the theoretical spectra of clusters with a six-ring adsorption site are in close agreement with the experimental x-ray emission spectra of titanium fulleride films. Our results indicate that off-resonant x-ray emission spectra provide an excellent basis for the probing of the bonding between metals and organic molecules.
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