| 1. |
- Kim, Seong-Min, et al.
(författare)
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High-performance, polymer-based direct cellular interfaces for electrical stimulation and recording
- 2018
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Ingår i: NPG ASIA MATERIALS. - : NATURE PUBLISHING GROUP. - 1884-4049 .- 1884-4057. ; 10, s. 255-265
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Tidskriftsartikel (refereegranskat)abstract
- Due to the trade-off between their electrical/electrochemical performance and underwater stability, realizing polymer-based, high-performance direct cellular interfaces for electrical stimulation and recording has been very challenging. Herein, we developed transparent and conductive direct cellular interfaces based on a water-stable, high-performance poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) film via solvent-assisted crystallization. The crystallized PEDOT:PSS on a polyethylene terephthalate (PET) substrate exhibited excellent electrical/electrochemical/optical characteristics, long-term underwater stability without film dissolution/delamination, and good viability for primarily cultured cardiomyocytes and neurons over several weeks. Furthermore, the highly crystallized, nanofibrillar PEDOT:PSS networks enabled dramatically enlarged surface areas and electrochemical activities, which were successfully employed to modulate cardiomyocyte beating via direct electrical stimulation. Finally, the high-performance PEDOT:PSS layer was seamlessly incorporated into transparent microelectrode arrays for efficient, real-time recording of cardiomyocyte action potentials with a high signal fidelity. All these results demonstrate the strong potential of crystallized PEDOT:PSS as a crucial component for a variety of versatile bioelectronic interfaces.
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| 2. |
- Kim, Seong-Min, et al.
(författare)
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Influence of PEDOT:PSS crystallinity and composition on electrochemical transistor performance and long-term stability
- 2018
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Ingår i: Nature Communications. - : NATURE PUBLISHING GROUP. - 2041-1723. ; 9
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Tidskriftsartikel (refereegranskat)abstract
- Owing to the mixed electron/hole and ion transport in the aqueous environment, poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate)-based organic electrochemical transistor has been regarded as one of the most promising device platforms for bioelectronics. Nonetheless, there exist very few in-depth studies on how intrinsic channel material properties affect their performance and long-term stability in aqueous environments. Herein, we investigated the correlation among film microstructural crystallinity/composition, device performance, and aqueous stability in poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) films. The highly organized anisotropic ordering in crystallized conducting polymer films led to remarkable device characteristics such as large transconductance (similar to 20 mS), extraordinary volumetric capacitance (113 F.cm(-3)), and unprecedentedly high [mu C*] value (similar to 490 F.cm(-1) V-1 s(-1)). Simultaneously, minimized poly(styrenesulfonate) residues in the crystallized film substantially afforded marginal film swelling and robust operational stability even after amp;gt;20-day water immersion, amp;gt;2000-time repeated on-off switching, or high-temperature/pressure sterilization. We expect that the present study will contribute to the development of long-term stable implantable bioelectronics for neural recording/stimulation.
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| 3. |
- Hofmann, Anna, 1987, et al.
(författare)
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All-Polymer Conducting Fibers and 3D Prints via Melt Processing and Templated Polymerization
- 2020
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Ingår i: ACS Applied Materials & Interfaces. - : American Chemical Society (ACS). - 1944-8252 .- 1944-8244. ; 12:7, s. 8713-8721
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Tidskriftsartikel (refereegranskat)abstract
- Because of their attractive mechanical properties, conducting polymers are widely perceived as materials of choice for wearable electronics and electronic textiles. However, most state-of-the-art conducting polymers contain harmful dopants and are only processable from solution but not in bulk, restricting the design possibilities for applications that require conducting micro-to-millimeter scale structures, such as textile fibers or thermoelectric modules. In this work, we present a strategy based on melt processing that enables the fabrication of nonhazardous, all-polymer conducting bulk structures composed of poly(3,4-ethylenedioxythiophene) (PEDOT) polymerized within a Nafion template. Importantly, we employ classical polymer processing techniques including melt extrusion followed by fiber spinning or fused filament 3D printing, which cannot be implemented with the majority of doped polymers. To demonstrate the versatility of our approach, we fabricated melt-spun PEDOT:Nafion fibers, which are highly flexible, retain their conductivity of about 3 S cm(-1) upon stretching to 100% elongation, and can be used to construct organic electrochemical transistors (OECTs). Furthermore, we demonstrate the precise 3D printing of complex conducting structures from OECTs to centimeter-sized PEDOT:Nafion figurines and millimeter-thick 100-leg thermoelectric modules on textile substrates. Thus, our strategy opens up new possibilities for the design of conducting, all-polymer bulk structures and the development of wearable electronics and electronic textiles.
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| 4. |
- Kim, Youngseok, et al.
(författare)
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Robust PEDOT:PSS Wet‐Spun Fibers for Thermoelectric Textiles
- 2020
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Ingår i: Macromolecular Materials and Engineering. - : Wiley. - 1439-2054 .- 1438-7492. ; 305:3, s. 1900749-
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Tidskriftsartikel (refereegranskat)abstract
- To realize thermoelectric textiles that can convert body heat to electricity, fibers with excellent mechanical and thermoelectric properties are needed. Although poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) is among the most promising organic thermoelectric materials, reports that explore its use for thermoelectric fibers are all but absent. Herein, the mechanical and thermoelectric properties of wet‐spun PEDOT:PSS fibers are reported, and their use in energy‐harvesting textiles is discussed. Wet‐spinning into sulfuric acid results in water‐stable semicrystalline fibers with a Young's modulus of up to 1.9 GPa, an electrical conductivity of 830 S cm−1, and a thermoelectric power factor of 30 μV m−1 K−2. Stretching beyond the yield point as well as repeated tensile deformation and bending leave the electrical properties of these fibers almost unaffected. The mechanical robustness/durability and excellent underwater stability of semicrystalline PEDOT:PSS fibers, combined with a promising thermoelectric performance, opens up their use in practical energy‐harvesting textiles, as illustrated by an embroidered thermoelectric fabric module.
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| 5. |
- Kimpel, Joost, 1996, et al.
(författare)
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High-mobility organic mixed conductors with a low synthetic complexity index via direct arylation polymerization
- 2024
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Ingår i: Chemical Science. - : ROYAL SOC CHEMISTRY. - 2041-6539 .- 2041-6520. ; 15:20, s. 7679-7688
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Tidskriftsartikel (refereegranskat)abstract
- Through direct arylation polymerization, a series of mixed ion-electron conducting polymers with a low synthetic complexity index is synthesized. A thieno[3,2-b]thiophene monomer with oligoether side chains is used in direct arylation polymerization together with a wide range of aryl bromides with varying electronic character from electron-donating thiophene to electron-accepting benzothiadiazole. The obtained polymers are less synthetically complex than other mixed ion-electron conducting polymers due to higher yield, fewer synthetic steps and less toxic reagents. Organic electrochemical transistors (OECTs) based on a newly synthesized copolymer comprising thieno[3,2-b]thiophene with oligoether side chains and bithiophene exhibit excellent device performance. A high charge-carrier mobility of up to μ = 1.8 cm2 V−1 s−1 was observed, obtained by dividing the figure of merit [μC*] from OECT measurements by the volumetric capacitance C* from electrochemical impedance spectroscopy, which reached a value of more than 215 F cm−3
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| 6. |
- Liu, Jian, 1985, et al.
(författare)
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Electrically Programmed Doping Gradients Optimize the Thermoelectric Power Factor of a Conjugated Polymer
- 2024
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Ingår i: Advanced Functional Materials. - 1616-3028 .- 1616-301X. ; 34:18
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Tidskriftsartikel (refereegranskat)abstract
- Functionally graded materials (FGMs) are widely explored in the context of inorganic thermoelectrics, but not yet in organic thermoelectrics. Here, the impact of doping gradients on the thermoelectric properties of a chemically doped conjugated polymer is studied. The in-plane drift of counterions in moderate electric fields is used to create lateral doping gradients in films composed of a polythiophene with oligoether side chains, doped with 2,3,5,6-tetrafluoro-tetracyanoquinodimethane (F4TCNQ). Raman microscopy reveals that a bias voltage of as little as 5 V across a 50 µm wide channel is sufficient to trigger counterion drift, resulting in doping gradients. The effective electrical conductivity of the graded channel decreases with bias voltage, while an overall increase in Seebeck coefficient is observed, yielding an up to eight-fold enhancement in power factor. Kinetic Monte Carlo simulations of graded films explain the increase in power factor in terms of a roll-off of the Seebeck coefficient at high electrical conductivities in combination with a mobility decay due to increased Coulomb scattering at high dopant concentrations. Therefore, the FGM concept is found to be a way to improve the thermoelectric performance of not yet optimally doped organic semiconductors, which may ease the screening of new materials as well as the fabrication of devices.
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| 7. |
- Mone, Mariza, 1992, et al.
(författare)
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Mechanically Adaptive Mixed Ionic-Electronic Conductors Based on a Polar Polythiophene Reinforced with Cellulose Nanofibrils
- 2023
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Ingår i: ACS Applied Materials & Interfaces. - : AMER CHEMICAL SOC. - 1944-8252 .- 1944-8244. ; 15:23, s. 28300-28309
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Tidskriftsartikel (refereegranskat)abstract
- Conjugated polymers with oligoether side chains are promising mixed ionic-electronic conductors, but they tend to feature a low glass transition temperature and hence a low elastic modulus, which prevents their use if mechanical robust materials are required. Carboxymethylated cellulose nanofibrils (CNF) are found to be a suitable reinforcing agent for a soft polythiophene with tetraethylene glycol side chains. Dry nanocomposites feature a Young’s modulus of more than 400 MPa, which reversibly decreases to 10 MPa or less upon passive swelling through water uptake. The presence of CNF results in a slight decrease in electronic mobility but enhances the ionic mobility and volumetric capacitance, with the latter increasing from 164 to 197 F cm-3 upon the addition of 20 vol % CNF. Overall, organic electrochemical transistors (OECTs) feature a higher switching speed and a transconductance that is independent of the CNF content up to at least 20 vol % CNF. Hence, CNF-reinforced conjugated polymers with oligoether side chains facilitate the design of mechanically adaptive mixed ionic-electronic conductors for wearable electronics and bioelectronics.
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| 8. |
- Paleti, Sri Harish Kumar, 1992, et al.
(författare)
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Impact of doping on the mechanical properties of conjugated polymers
- 2024
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Ingår i: Chemical Society Reviews. - 1460-4744 .- 0306-0012. ; 53:4, s. 1702-1729
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Forskningsöversikt (refereegranskat)abstract
- Conjugated polymers exhibit a unique portfolio of electrical and electrochemical behavior, which - paired with the mechanical properties that are typical for macromolecules - make them intriguing candidates for a wide range of application areas from wearable electronics to bioelectronics. However, the degree of oxidation or reduction of the polymer can strongly impact the mechanical response and thus must be considered when designing flexible or stretchable devices. This tutorial review first explores how the chain architecture, processing as well as the resulting nano- and microstructure impact the rheological and mechanical properties. In addition, different methods for the mechanical characterization of thin films and bulk materials such as fibers are summarized. Then, the review discusses how chemical and electrochemical doping alter the mechanical properties in terms of stiffness and ductility. Finally, the mechanical response of (doped) conjugated polymers is discussed in the context of (1) organic photovoltaics, representing thin-film devices with a relatively low charge-carrier density, (2) organic thermoelectrics, where chemical doping is used to realize thin films or bulk materials with a high doping level, and (3) organic electrochemical transistors, where electrochemical doping allows high charge-carrier densities to be reached, albeit accompanied by significant swelling. In the future, chemical and electrochemical doping may not only allow modulation and optimization of the electrical and electrochemical behavior of conjugated polymers, but also facilitate the design of materials with a tunable mechanical response.
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