2. |
- Lupina, Grzegorz, et al.
(författare)
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Residual Metallic Contamination of Transferred Chemical Vapor Deposited Graphene
- 2015
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-0851 .- 1936-086X. ; 9:5, s. 4776-4785
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Tidskriftsartikel (refereegranskat)abstract
- Integration of graphene with Si microelectronics is very appealing by offering a potentially broad range of new functionalities. New materials to be integrated with the Si platform must conform to stringent purity standards. Here, we investigate graphene layers grown on copper foils by chemical vapor deposition and transferred to silicon wafers by wet etching and electrochemical delamination methods with respect to residual submonolayer metallic contaminations. Regardless of the transfer method and associated cleaning scheme, time-of-flight secondary ion mass spectrometry and total reflection X-ray fluorescence measurements indicate that the graphene sheets are contaminated with residual metals (copper, iron) with a concentration exceeding 10(13) atoms/cm(2). These metal impurities appear to be partially mobile upon thermal treatment, as shown by depth profiling and reduction of the minority charge carrier diffusion length in the silicon substrate. As residual metallic impurities can significantly alter electronic and electrochemical properties of graphene and can severely impede the process of integration with silicon microelectronics, these results reveal that further progress in synthesis, handling, and cleaning of graphene is required to advance electronic and optoelectronic applications.
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3. |
- Prinoth, Bibiana, et al.
(författare)
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Titanium oxide and chemical inhomogeneity in the atmosphere of the exoplanet WASP-189 b
- 2022
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Ingår i: Nature Astronomy. - : Springer Science and Business Media LLC. - 2397-3366. ; 6:4, s. 449-457
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Tidskriftsartikel (refereegranskat)abstract
- The temperature of an atmosphere decreases with increasing altitude, unless a shortwave absorber that causes a temperature inversion exists. Ozone plays this role in the Earth’s atmosphere. In the atmospheres of highly irradiated exoplanets, the shortwave absorbers are predicted to be titanium oxide (TiO) and vanadium oxide (VO). Detections of TiO and VO have been claimed using both low-, and high- spectral-resolution observations, but subsequent observations have failed to confirm these claims or overturned them. Here we report the unambiguous detection of TiO in the ultra-hot Jupiter WASP-189 b using high-resolution transmission spectroscopy. This detection is based on applying the cross-correlation technique to many spectral lines of TiO from 460 to 690 nm. Moreover, we report detections of metals, including neutral and singly ionized iron and titanium, as well as chromium, magnesium, vanadium and manganese (Fe, Fe+, Ti, Ti+, Cr, Mg, V, Mn). The line positions of the detected species differ, which we interpret as a consequence of spatial gradients in their chemical abundances, such that they exist in different regions or dynamical regimes. This is direct observational evidence for the three-dimensional thermochemical stratification of an exoplanet atmosphere derived from high-resolution ground-based spectroscopy.
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