| 1. |
- Vilardell, A. M., et al.
(författare)
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B2-structured Fe3Al alloy manufactured by laser powder bed fusion : Processing, microstructure and mechanical performance
- 2023
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Ingår i: Intermetallics (Barking). - : Elsevier. - 0966-9795 .- 1879-0216. ; 156
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Tidskriftsartikel (refereegranskat)abstract
- Prealloyed Fe3Al was successfully manufactured by laser powder bed fusion. The best set of process parameters led to parts with a relative density of 99.5 %, a surface roughness, Sa, of 31.5 ± 5.6 μm and a hardness of 319 ± 14 HV0.1. Its microstructure as well as its mechanical properties at room and high temperatures were analyzed. The results of the chemical composition showed minor variations in aluminum content oscillating between 21 and 28 at.% along the melt pool. Additionally, elongated grains were observed to grow parallel to the building direction, as well as the development of a weak 001 texture along the building direction. The mechanical properties were influenced by the temperature. Compression tests showed a loss in strength with the increase in temperature, from a yield strength of 621 ± 40 MPa at room temperature to 89 ± 20 MPa at 650 °C. Reciprocating sliding wear tests showed that fragmentation of the intermetallic at room temperature occurs, whereas plastic deformation dominated at higher temperatures. For all temperatures, tribochemical wear was also present due to the oxidation of wear debris.
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| 2. |
- Vilardell, Anna M., et al.
(författare)
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Manufacturing and characterization of in-situ alloyed Ti6Al4V(ELI)-3 at.% Cu by laser powder bed fusion
- 2020
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Ingår i: Additive Manufacturing. - : Elsevier. - 2214-8604 .- 2214-7810. ; 36, s. 1-14
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Tidskriftsartikel (refereegranskat)abstract
- Biofunctionalization of Ti6Al4V alloy with metallic agents like Ag or Cu is a promising approach to add antibacterial properties and thus to reduce the risk of implant failure. This research investigates the in-situ alloying of Ti6Al4V(ELI) with 3 at.% Cu powders using Laser Powder Bed Fusion (L-PBF). The morphology and geometrical characteristics of the single tracks and layers were studied. Laser powers of 170 W and 340 W, and scanning speeds ranging from 0.4 to 1.4 m/s and 0.8-2.8 m/s were implemented. Single track results showed balling effect and humping at high scanning speeds, 1.4 m/s and 1.6 m/s, for each laser powder respectively. Conversely, keyhole formation occurred at lower scanning speeds of 0.4-0.6 m/s for 170 W laser power, and below and 0.8 m/s for 340 W laser power. For both laser powers, single layers resulted in smoother surfaces at lower scanning speeds. These results were used for the development of optimal process parameters for 3D cubes with 99.9 % density. Optimal process parameters were found for 170 W and 340W laser powders at 0.7-0.9 and 1.0-1.2 m/s scanning speeds, respectively.In-situ alloying by L-PBF was challenging and a homogeneous distribution of Cu within the alloy was hard to achieve. The increase in laser power from 170 to 340 W resulted in small increase in homogenization. Microstructural analyses after stress-relieving treatment showed the presence of alpha' and beta phases, as well as CuTi2 intermetallic precipitates. The finer microstructure together with CuTi2 intermetallic precipitates resulted in an increase in hardness. This study demonstrates the potential for printing in-situ alloyed Ti6Al4V(ELI)- 3 at.% Cu for biomedical applications. However, further studies are required to determine the effectiveness of antibacterial properties.
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| 3. |
- Vilardell, Anna M., et al.
(författare)
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Mechanical behavior of in-situ alloyed Ti6Al4V(ELI)-3 at.% Cu lattice structures manufactured by laser powder bed fusion and designed for implant applications
- 2021
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Ingår i: Journal of The Mechanical Behavior of Biomedical Materials. - : Elsevier. - 1751-6161 .- 1878-0180. ; 113, s. 1-9
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Tidskriftsartikel (refereegranskat)abstract
- In the present study, cellular lattice structures for implant applications are reported for the first-time incorporating copper directly by in-situ alloying in the laser powder bed fusion process. The aim to incorporate 3 at.% Cu into Ti6Al4V(ELI) is selected for improved antibacterial properties while maintaining appropriate mechanical properties. Previously, topologically optimized Ti6Al4V(ELI) lattice structures were successfully designed, manufactured and studied for implant applications. The development of a new alloy produced by in-situ alloying of elemental powder mixture of Ti6Al4V(ELI) and pure Cu powders was used here for the production of identical lattice structures with improved antibacterial properties. One of the same as-designed CAD models was used for the manufacturing of these lattices compared to previous work on pure Ti6Al4V(ELI) lattices, making direct comparison of mechanical properties possible. Similar manufacturability highlights the applicability of this alloying technique to other lattice designs. Microstructural characterization was performed by optical and electron microscopies, as well as microCT. Mechanical characterization was performed by means of compression tests and hardness measurements. Results showed that in-situ alloying with copper leads to the formation of localized Cu-rich regions, refinement of martensitic phase and the formation of CuTi2 intermetallic precipitates, which increased the hardness and strength of the material. Deviations in wall thickness between the as-designed and as-manufactured lattices led to anisotropy of the mechanical properties of the lattices. Higher compressive strength values were obtained when thicker walls were oriented along the loading direction. Nevertheless, alloying with Cu had a higher impact on the compressive strength of lattice structure than the wall thickness deviations. The direct in-situ alloying of copper in Ti6Al4V(ELI) is a promising mute for direct manufacturing of antibacterial implants.
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| 4. |
- Vilardell, Anna M., et al.
(författare)
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Topology optimization and characterization of Ti6A14V ELI cellular lattice structures by laser powder bed fusion for biomedical applications
- 2019
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Ingår i: Materials Science & Engineering. - : Elsevier. - 0921-5093 .- 1873-4936. ; 766, s. 1-11
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Tidskriftsartikel (refereegranskat)abstract
- Topology optimization approach was used for the design of Ti6A14V ELI lattice structures with stiffness and density close to the human bone for implant applications. Three lattice designs with volume densities of 350/0, 40 % and 45 % and corresponding elastic modulus of 18.6 GPa, 23.1 GPa 27.4 GPa close to the human bone were generated. Laser powder bed fusion (LPBF) technique was used for the manufacturing of the specimens. Physical measurements and mechanical characterization of specimens were assessed by microCT analyses and compression test, perpendicular and parallel to the building direction of the specimens. LPBF Ti6A14V ELI manufactured lattice structures showed deviations in wall thickness in comparison with the generated designs, leading to an increase in relative porosity but also a decrease in elastic modulus in comparison with the original designs. Horizontal walls of the lattice structures showed higher wall thickness in comparison with the vertical walls, leading to anisotropic behaviour of the lattice structures. Higher elastic modulus and compression strength were obtained when thicker walls were oriented along the loading direction of the compression test, showing a complete failure by dividing the specimens into two neighbouring halves. All specimens showed 45 degrees diagonal shear fracture along the structure. On the other hand, higher energy absorption at first maximum compression strength peak was observed when samples were tested parallel to the building direction (when thinner walls were oriented along the loading compression direction). Results showed that designed lattice structures can possess the levels of human bones' stiffness and therefore can reduce/avoid stress shielding on implant applications.
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| 5. |
- Kobashi, Takuro, et al.
(författare)
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Volcanic influence on centennial to millennial Holocene Greenland temperature change
- 2017
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Ingår i: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322. ; 7:1
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Tidskriftsartikel (refereegranskat)abstract
- Solar variability has been hypothesized to be a major driver of North Atlantic millennial-scale climate variations through the Holocene along with orbitally induced insolation change. However, another important climate driver, volcanic forcing has generally been underestimated prior to the past 2,500 years partly owing to the lack of proper proxy temperature records. Here, we reconstruct seasonally unbiased and physically constrained Greenland Summit temperatures over the Holocene using argon and nitrogen isotopes within trapped air in a Greenland ice core (GISP2). We show that a series of volcanic eruptions through the Holocene played an important role in driving centennial to millennial-scale temperature changes in Greenland. The reconstructed Greenland temperature exhibits significant millennial correlations with K+ and Na+ ions in the GISP2 ice core (proxies for atmospheric circulation patterns), and δ18O of Oman and Chinese Dongge cave stalagmites (proxies for monsoon activity), indicating that the reconstructed temperature contains hemispheric signals. Climate model simulations forced with the volcanic forcing further suggest that a series of large volcanic eruptions induced hemispheric-wide centennial to millennial-scale variability through ocean/sea-ice feedbacks. Therefore, we conclude that volcanic activity played a critical role in driving centennial to millennial-scale Holocene temperature variability in Greenland and likely beyond.
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