| 1. |
- Chen, Yifeng, et al.
(författare)
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Kinetics study and performance evaluation of a hybrid choline-glycine/polyethylene glycol/water absorbent for CO2 separation
- 2023
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Ingår i: Separation and Purification Technology. - : Elsevier B.V.. - 1383-5866 .- 1873-3794. ; 304
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Tidskriftsartikel (refereegranskat)abstract
- Thermodynamic and kinetic properties of absorbents are beneficial in evaluating their CO2 separation performance. In this study, the kinetic properties of CO2 in a hybrid choline-glycine/polyethylene glycol/water absorbent, including the liquid-side mass-transfer coefficient, enhancement factor, and reaction rate constant, were systematically determined through experimental measurements and data processing. Furthermore, an index referred to as “absorbility” was proposed to combine the kinetic properties determined in this study with the thermodynamic properties obtained in our previous study to evaluate the CO2 separation performance. Additionally, the regeneration performance of the hybrid absorbent was also conducted. The results show that the performance of the hybrid absorbent (30 wt% [Cho][Gly] + 10 wt% PEG200 + 60 wt% H2O) is comparable to that of aqueous monoethanolamine, and is thus promising for CO2 separation, considering its low regeneration temperature and low environmental impact.
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| 2. |
- Liu, Sida, et al.
(författare)
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Improved CO2 separation performance of aqueous choline-glycine solution by partially replacing water with polyethylene glycol
- 2019
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Ingår i: Fluid Phase Equilibria. - : Elsevier. - 0378-3812 .- 1879-0224. ; 495, s. 12-20
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Tidskriftsartikel (refereegranskat)abstract
- Aqueous choline-glycine ([Cho][Gly]) solution is a potential candidate for CO2separation owing to its excellent absorption performance and biodegradability. Moreover, the aqueous solution is easy to volatilize at high temperatures. In this work, H2O was partially replaced with polyethylene glycol (PEG200) and the effect of PEG200 on the CO2 separation performance in [Cho][Gly])/H2O was investigated. The viscosity of [Cho][Gly]/H2O/PEG200 and CO2 solubility in the solution were determined experimentally in the temperature range 308.15–338.15 K at pressures ≤6.5 bar. Further, the measured CO2 solubility was fitted with the reaction equilibrium thermodynamic model and the CO2 desorption enthalpy was estimated. The regeneration performance of [Cho][Gly]/H2O/PEG200 was also evaluated. The results revealed that [Cho][Gly]/H2O/PEG200 has a low CO2desorption enthalpy and high regeneration efficiency. Particularly, [Cho][Gly]/H2O/PEG200 with 30 wt% PEG200 has a high regeneration efficiency of 95%. Owing to its physical-chemical properties and CO2 separation performance, [Cho][Gly]/H2O/PEG200 shows great potential as an absorbent for CO2 separation.
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| 3. |
- Liu, Sida, et al.
(författare)
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Modeling of metastable phase formation for sputtered Ti1-xAlxN thin films
- 2019
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Ingår i: Acta Materialia. - : PERGAMON-ELSEVIER SCIENCE LTD. - 1359-6454 .- 1873-2453. ; 165, s. 615-625
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Tidskriftsartikel (refereegranskat)abstract
- Metastable titanium aluminum nitride coatings are widely applied in cutting and forming applications. Although it is generally accepted that the phase formation of metastable TiAIN is governed by kinetic factors, modeling attempts today are based solely on energetics. In this work, the metastable phase formation of TiAIN is predicted based on one combinatorial magnetron sputtering experiment, the activation energy for surface diffusion, the critical diffusion distance, as well as thermodynamic calculations. The phase formation data obtained from further combinatorial growth experiments varying chemical composition, deposition temperature, and deposition rate are in good agreement with the model. Furthermore, it is demonstrated that a significant extension of the predicted critical solubility range is enabled by taking kinetic factors into account. Explicit consideration of kinetics extends the Al solubility limit to lower values, previously unobtainable by energetics, but accessible experimentally. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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| 4. |
- Liu, Sida, et al.
(författare)
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Stress-dependent prediction of metastable phase formation for magnetron-sputtered V1-xAlxN and Ti1-xAlxN thin films
- 2020
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Ingår i: Acta Materialia. - : PERGAMON-ELSEVIER SCIENCE LTD. - 1359-6454 .- 1873-2453. ; 196, s. 313-324
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Tidskriftsartikel (refereegranskat)abstract
- Metastable transition metal aluminum nitride (TMAlN, TM = Ti, V) thin films are today deposited utilizing ionized vapor phase condensation techniques where variations in ion flux and ion energy cause compressive film stress, in turn affecting Al solubility. While the metastable phase formation of TiAlN has been modeled, the influence of film stresses on phase formation has so far been overlooked. Using combinatorial deposition via magnetron sputtering, thermodynamic modeling and density functional theory calculations, we investigated the phase formation of V1-xAlxN and Ti1-xAlxN thin films at various substrate temperatures and deposition rates. Ab initio calculations indicate that the maximum solid solubility of Al in face-centered cubic (fcc) V1-xAlxN or fcc-Ti1-xAlxN shows a linear trend as a function of the magnitude of compressive stress. Here, we consider the influence of film stresses on the metastable phase formation of fcc-V1-xAlxN and fcc-Ti1-xAlxN for the first time. Specifically, experimental data from a single combinatorial deposition is utilized to predict the stress-dependent formation of metastable phases based on thermodynamic and ab initio data. Explicit consideration of stress extends the Al solubility limit to higher values for both Ti1-xAlxN and V1-xAlxN thin films, previously unobtainable by energetics, but accessible experimentally. These predictions are experimentally verified and thus provide guidance for experimental efforts with the goal of increasing the Al concentration in fcc-TMAlN thin films. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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| 5. |
- Sun, Tao, et al.
(författare)
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Geometric accuracy design and error compensation of a one-translational and three-rotational parallel mechanism with articulated traveling plate
- 2018
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Ingår i: Proceedings of the Institution of mechanical engineers. Part B, journal of engineering manufacture. - : Sage Publications. - 0954-4054 .- 2041-2975. ; 232:12, s. 2083-2097
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Tidskriftsartikel (refereegranskat)abstract
- The demands for advanced and flexible docking equipment are increasing in the fields of aerospace, shipbuilding and construction machinery. Position and orientation accuracy is one of the most important criteria, which would directly affect the docking quality. Taking a novel one-translational and three-rotational docking equipment, referred to as PaQuad parallel mechanism as example, this article proposed an accuracy improvement strategy by geometric accuracy design and error compensation. Drawing mainly on screw theory, geometric error modeling of PaQuad parallel mechanism was first carried out via four independent routes. Joint perturbations and geometric errors were included in each route error twist. Wrenches due to articulated traveling plate were applied to eliminate joint perturbations. Then, geometric accuracy design was implemented at component and substructure levels. The basic principle was to transfer geometric errors into dimensional or geometric tolerance. High-precision machining/assembling techniques were applied to satisfy the tolerance. Finally, error compensation resorting to kinematic calibration was implemented at mechanism level. It can be summarized as identification modeling, measurement planning, and parameter identification and modification. Maximum deviations of PaQuad parallel mechanism before calibration experiment were 0.01mm, 0.027 after kinematic calibration. Orientation accuracy of PaQuad parallel mechanism has improved one order of magnitude. It proves the effectiveness of accuracy improvement in terms of geometric accuracy design and error compensation.
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