| 1. |
- Detlef, Henrieka, et al.
(författare)
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Holocene sea-ice dynamics in Petermann Fjord in relation to ice tongue stability and Nares Strait ice arch formation
- 2021
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Ingår i: The Cryosphere. - : Copernicus GmbH. - 1994-0416 .- 1994-0424. ; 15:9, s. 4357-4380
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Tidskriftsartikel (refereegranskat)abstract
- The Petermann 2015 expedition to Petermann Fjord and adjacent Hall Basin recovered a transect of cores, extending from Nares Strait to underneath the 48 km long ice tongue of Petermann glacier, offering a unique opportunity to study ice-ocean-sea ice interactions at the interface of these realms. First results suggest that no ice tongue existed in Petermann Fjord for large parts of the Holocene, raising the question of the role of the ocean and the marine cryosphere in the collapse and re-establishment of the ice tongue. Here we use a multi-proxy approach (sea-ice-related biomarkers, total organic carbon and its carbon isotopic composition, and benthic and planktonic foraminiferal abundances) to explore Holocene sea ice dynamics at OD1507-03TC-41GC-03PC in outer Petermann Fjord. Our results are in line with a tight coupling of the marine and terrestrial cryosphere in this region and, in connection with other regional sea ice reconstructions, give insights into the Holocene evolution of ice arches and associated landfast ice in Nares Strait. The late stages of the regional Holocene Thermal Maximum (6900-5500 cal yr BP) were marked by reduced seasonal sea ice concentrations in Nares Strait and the lack of ice arch formation. This was followed by a transitional period towards Neoglacial cooling from 5500-3500 cal yr BP, where a southern ice arch might have formed, but an early seasonal breakup and late formation likely caused a prolonged open water season and enhanced pelagic productivity in Nares Strait. Between 3500 and 1400 cal yr BP, regional records suggest the formation of a stable northern ice arch only, with a short period from 2500-2100 cal yr BP where a southern ice arch might have formed intermittently in response to atmospheric cooling spikes. A stable southern ice arch, or even double arching, is also inferred for the period after 1400 cal yr BP. Thus, both the inception of a small Petermann ice tongue at similar to 2200 cal yr BP and its rapid expansion at similar to 600 cal yr BP are preceded by a transition towards a southern ice arch regime with landfast ice formation in Nares Strait, suggesting a stabilizing effect of landfast sea ice on Petermann Glacier.
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| 2. |
- Detlef, Henrieka, et al.
(författare)
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Seasonal sea-ice in the Arctic's last ice area during the Early Holocene
- 2023
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Ingår i: Communications Earth & Environment. - : Springer Science and Business Media LLC. - 2662-4435. ; 4:1
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Tidskriftsartikel (refereegranskat)abstract
- According to climate models, the Lincoln Sea, bordering northern Greenland and Canada, will be the final stronghold of perennial Arctic sea-ice in a warming climate. However, recent observations of prolonged periods of open water raise concerns regarding its long-term stability. Modelling studies suggest a transition from perennial to seasonal sea-ice during the Early Holocene, a period of elevated global temperatures around 10,000 years ago. Here we show marine proxy evidence for the disappearance of perennial sea-ice in the southern Lincoln Sea during the Early Holocene, which suggests a widespread transition to seasonal sea-ice in the Arctic Ocean. Seasonal sea-ice conditions were tightly coupled to regional atmospheric temperatures. In light of anthropogenic warming and Arctic amplification our results suggest an imminent transition to seasonal sea-ice in the southern Lincoln Sea, even if the global temperature rise is kept below a threshold of 2 °C compared to pre-industrial (1850–1900).
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| 3. |
- Rosati, Bernadette, et al.
(författare)
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Hygroscopicity and CCN potential of DMS-derived aerosol particles
- 2022
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Ingår i: Atmospheric Chemistry And Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 22:20, s. 13449-13466
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Tidskriftsartikel (refereegranskat)abstract
- Dimethyl sulfide (DMS) is emitted by phytoplankton species in the oceans and constitutes the largest source of naturally emitted sulfur to the atmosphere. The climate impact of secondary particles, formed through the oxidation of DMS by hydroxyl radicals, is still elusive. This study investigates the hygroscopicity and cloud condensation nuclei activity of such particles and discusses the results in relation to their chemical composition. We show that mean hygroscopicity parameters, κ, during an experiment for particles of 80 nm in diameter range from 0.46 to 0.52 or higher, as measured at both sub- and supersaturated water vapour conditions. Ageing of the particles leads to an increase in κ from, for example, 0.50 to 0.58 over the course of 3 h (Exp. 7). Aerosol mass spectrometer measurements from this study indicate that this change most probably stems from a change in chemical composition leading to slightly higher fractions of ammonium sulfate compared to methanesulfonic acid (MSA) within the particles with ageing time. Lowering the temperature to 258 K increases κ slightly, particularly for small particles. These κ values are well comparable to previously reported model values for MSA or mixtures between MSA and ammonium sulfate. Particle nucleation and growth rates suggest a clear temperature dependence, with slower rates at cold temperatures. Quantum chemical calculations show that gas-phase MSA clusters are predominantly not hydrated, even at high humidity conditions, indicating that their gas-phase chemistry should be independent of relative humidity.
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| 4. |
- Rosati, Bernadette, et al.
(författare)
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New Particle Formation and Growth from Dimethyl Sulfide Oxidation by Hydroxyl Radicals
- 2021
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Ingår i: ACS Earth and Space Chemistry. - : American Chemical Society (ACS). - 2472-3452. ; 5:4, s. 801-811
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Tidskriftsartikel (refereegranskat)abstract
- Dimethyl sulfide (DMS) is produced by plankton in oceans and constitutes the largest natural emission of sulfur to the atmosphere. In this work, we examine new particle formation from the primary pathway of oxidation of gas-phase DMS by OH radicals. We particularly focus on particle growth and mass yield as studied experimentally under dry conditions using the atmospheric simulation chamber AURA. Experimentally, we show that aerosol mass yields from oxidation of 50-200 ppb of DMS are low (2-7%) and that particle growth rates (8.2-24.4 nm/h) are comparable with ambient observations. An HR-ToF-AMS was calibrated using methanesulfonic acid (MSA) to account for fragments distributed across both the organic and sulfate fragmentation table. AMS-derived chemical compositions revealed that MSA was always more dominant than sulfate in the secondary aerosols formed. Modeling using the Aerosol Dynamics, gas- and particle-phase chemistry kinetic multilayer model for laboratory CHAMber studies (ADCHAM) indicates that the Master Chemical Mechanism gas-phase chemistry alone underestimates experimentally observed particle formation and that DMS multiphase and autoxidation chemistry is needed to explain observations. Based on quantum chemical calculations, we conclude that particle formation from DMS oxidation in the ambient atmosphere will most likely be driven by mixed sulfuric acid/MSA clusters clustering with both amines and ammonia.
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