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- Jou-Claus, Sònia, et al.
(författare)
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Assessing the Fate of Benzophenone-Type UV Filters and Transformation Products during Soil Aquifer Treatment : The Biofilm Compartment as Bioaccumulator and Biodegrader in Porous Media
- 2024
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Ingår i: Environmental Science and Technology. - 0013-936X .- 1520-5851. ; 58:12, s. 5472-5482
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Tidskriftsartikel (refereegranskat)abstract
- The fate of selected UV filters (UVFs) was investigated in two soil aquifer treatment (SAT) systems, one supplemented with a reactive barrier containing clay and vegetable compost and the other as a traditional SAT reference system. We monitored benzophenone-3 (BP-3) and its transformation products (TPs), including benzophenone-1 (BP-1), 4,4′-dihydroxybenzophenone (4DHB), 4-hydroxybenzophenone (4HB), and 2,2′-dihydroxy-4-methoxybenzophenone (DHMB), along with benzophenone-4 (BP-4) and avobenzone (AVO) in all involved compartments (water, aquifer sediments, and biofilm). The reactive barrier, which enhances biochemical activity and biofilm development, improved the removal of all detected UVFs in water samples. Among monitored UVFs, only 4HB, BP-4, and AVO were detected in sediment and biofilm samples. But the overall retained amounts were several orders of magnitude larger than those dissolved. These amounts were quantitatively reproduced with a specifically developed simple analytical model that consists of a mobile compartment and an immobile compartment. Retention and degradation are restricted to the immobile water compartment, where biofilm absorption was simulated with well-known compound-specific Kow values. The fact that the model reproduced observations, including metabolites detected in the biofilm but not in the (mobile) water samples, supports its validity. The results imply that accumulation ensures significant biodegradation even if the degradation rates are very low and suggest that our experimental findings for UVFs and TPs can be extended to other hydrophobic compounds. Biofilms act as accumulators and biodegraders of hydrophobic compounds.
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| 2. |
- Martinez-Landa, Lurdes, et al.
(författare)
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A methodology for the interpretation of aquifer tests : Application to CO2 residual trapping experiments at the Heletz site
- 2021
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Ingår i: International Journal of Greenhouse Gas Control. - : Elsevier. - 1750-5836 .- 1878-0148. ; 112
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Tidskriftsartikel (refereegranskat)abstract
- Estimation of trapped CO2 is essential for assessing the potential of a site for geological carbon storage. In situ residual trapping can be obtained through Residual Trapping Experiments (RTE). RTE experiments consist in performing characterization tests e.g. hydraulic, thermal and tracer tests before and after creating the residually trapped zone of CO2 and estimating residual saturation from the differences between the two tests. We introduce a methodology for interpreting residual drawdowns from hydraulic tests, and specifically those performed before and after the creation of the residually trapped zone. Martinez-Landa et al. (2013) demonstrated that the reduction of hydraulic conductivity and the increase in storativity within the trapped CO2 zone can produce early time differences that are significant. However, our interpretation is hindered by the fact that accurate measurement of early time (a few minutes) response is difficult because the large inertia of the system prevents us from rapidly establishing a controlled constant flow-rate. This is particularly true for the RTE test at Heletz, where water withdrawal during the hydraulic tests had to be performed by air-lift. To resolve this difficulty, we use the proposed methodology which avoids instabilities derived from changes in flow rates. Our approach consists of four steps: (1) filtering of natural trends in heads to ensure good definition of drawdowns; (2) transformation of residual drawdowns into constant pumping test drawdowns, by using the Agarwal or other methods, while accounting for flow rate variations during the pumping phase; (3) computation of smooth log-derivatives to prepare diagnostic plots to aid in conceptual model identification; and (4) quantitative interpretation. The application of our approach to the Heletz RTE experiment gave rise to diagnostic plots consistent with theoretical expectations and a residual CO2 saturation of about 10%.
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