SwePub
Sök i SwePub databas

  Utökad sökning

Träfflista för sökning "WFRF:(Meggiolaro Daniele) "

Sökning: WFRF:(Meggiolaro Daniele)

  • Resultat 1-2 av 2
Sortera/gruppera träfflistan
   
NumreringReferensOmslagsbildHitta
1.
  • Zhou, Yang, et al. (författare)
  • How Photogenerated I2 Induces I-Rich Phase Formation in Lead Mixed Halide Perovskites
  • 2023
  • Ingår i: Advanced Materials. - : WILEY-V C H VERLAG GMBH. - 0935-9648 .- 1521-4095.
  • Tidskriftsartikel (refereegranskat)abstract
    • Bandgap tunability of lead mixed halide perovskites (LMHPs) is a crucial characteristic for versatile optoelectronic applications. Nevertheless, LMHPs show the formation of iodide-rich (I-rich) phase under illumination, which destabilizes the semiconductor bandgap and impedes their exploitation. Here, it is shown that how I-2, photogenerated upon charge carrier trapping at iodine interstitials in LMHPs, can promote the formation of I-rich phase. I-2 can react with bromide (Br-) in the perovskite to form a trihalide ion I2Br- (I delta--I delta+-Br delta-), whose negatively charged iodide (I delta-) can further exchange with another lattice Br- to form the I-rich phase. Importantly, it is observed that the effectiveness of the process is dependent on the overall stability of the crystalline perovskite structure. Therefore, the bandgap instability in LMHPs is governed by two factors, i.e., the density of native defects leading to I-2 production and the Br- binding strength within the crystalline unit. Eventually, this study provides rules for the design of chemical composition in LMHPs to reach their full potential for optoelectronic devices.
  •  
2.
  • Cinquanta, Eugenio, et al. (författare)
  • Ultrafast THz Probe of Photoinduced Polarons in Lead-Halide Perovskites
  • 2019
  • Ingår i: Physical Review Letters. - 0031-9007. ; 122:16
  • Tidskriftsartikel (refereegranskat)abstract
    • We study the nature of photoexcited charge carriers in CsPbBr3 nanocrystal thin films by ultrafast optical pump-THz probe spectroscopy. We observe a deviation from a pure Drude dispersion of the THz dielectric response that is ascribed to the polaronic nature of carriers; a transient blueshift of observed phonon frequencies is indicative of the coupling between photogenerated charges and stretching-bending modes of the deformed inorganic sublattice, as confirmed by DFT calculations.
  •  
Skapa referenser, mejla, bekava och länka
  • Resultat 1-2 av 2

Kungliga biblioteket hanterar dina personuppgifter i enlighet med EU:s dataskyddsförordning (2018), GDPR. Läs mer om hur det funkar här.
Så här hanterar KB dina uppgifter vid användning av denna tjänst.

 
pil uppåt Stäng

Kopiera och spara länken för att återkomma till aktuell vy