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- Maksimov, Igor S., et al.
(författare)
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Pressure effects in granular La0.7Ca0.3-xSrxMnO3.
- 2002
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Ingår i: Physica Status Solidi A, Applied Research vol. 189, issue 2. - : Wiley Interscience. ; , s. 281-285
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Konferensbidrag (refereegranskat)abstract
- This paper discusses the effect of hydrostatic pressure up to 0.8 GPa on magnetic properties of manganites La0.7Ca0.3 - xSrxMnO3 (0 x 0.3, x = 0.03) and magnetoresistance data in an applied magnetic field of 5.0 T. Application of pressure enlarges the temperature range of the ferromagnetic phase. Curie temperature, TC, as a function of pressure and the temperature of resistance maximum, Tp, showed an anomaly for x = 0.15. The slope of pressure dependence of TC for x < 0.15 and x > 0.15 is higher than for x = 0.15. Dependence of temperature Tp on x consists of two curves: for x 0.15 and for x 0.15. There is a sharp bend on the Tp curve at x = 0.15. The structural phase transition from orthorhombic phase (x < 0.15) to rhombohedral one (x 0.15) corresponds to that concentration.
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- Pashchenko, V. P., et al.
(författare)
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Structure and properties of La0.6Sr0.4-xBaxMnO3 (0 <= x <= 0.4) magnetoresistive ceramics
- 2002
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Ingår i: Inorganic Materials (Neorganicheskie materialy). - 0020-1685 .- 1608-3172. ; 38:3, s. 302-307
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Tidskriftsartikel (refereegranskat)abstract
- The effect of Ba content on the phase composition, lattice parameter, Mn-55 NMR spectrum, resistance, and magnetoresistance of La0.6Sr0.4-xBaxMnO3 perovskites was studied. The lattice parameter of the single-phase ceramic samples was found to increase with increasing x. The tolerance factor increases and the ionic field strength decreases as x increases from 0 to 0.4. The Mn-55 NMR results obtained at 77 K indicate a high-frequency electron exchange between Mn3+ and Mn4+ in the ferromagnetic phase. The peak-magnetoresistance temperature tends to decrease with increasing x. The magnetoresistance of the ceramics is correlated with the bond covalence. It is inferred that the ceramics contain inhomogeneities differing in nature and length scale (macroscopic, mesoscopic, and microscopic), which influence their magnetoresistance.
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