| 1. |
- Brinkmann, Inda, et al.
(author)
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Drought recorded by Ba/Ca in coastal benthic foraminifera
- 2022
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In: Biogeosciences. - : Copernicus GmbH. - 1726-4170 .- 1726-4189. ; 19:9, s. 2523-2535
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Journal article (peer-reviewed)abstract
- Increasing occurrences of extreme weather events, such as the 2018 drought over northern Europe, are a concerning issue under global climate change. High-resolution archives of natural hydroclimate proxies, such as rapidly accumulating sediments containing biogenic carbonates, offer the potential to investigate the frequency and mechanisms of such events in the past. Droughts alter the barium (Ba) concentration of near-continent seawater through the reduction in Ba input from terrestrial runoff, which in turn may be recorded as changes in the chemical composition (Ba/Ca) of foraminiferal calcium carbonates accumulating in sediments. However, so far the use of Ba/Ca as a discharge indicator has been restricted to planktonic foraminifera, despite the high relative abundance of benthic species in coastal, shallow-water sites. Moreover, benthic foraminiferal Ba/Ca has mainly been used in open-ocean records as a proxy for paleo-productivity. Here we report on a new geochemical data set measured from living (CTG-labeled) benthic foraminiferal species to investigate the capability of benthic Ba/Ca to record changes in river runoff over a gradient of contrasting hydroclimatic conditions. Individual foraminifera (Bulimina marginata, Nonionellina labradorica) were analyzed by laser-ablation ICP-MS over a seasonal and spatial gradient within Gullmar Fjord, Swedish west coast, during 2018-2019. The results are compared to an extensive meteorological and hydrological data set, as well as sediment and pore-water geochemistry. Benthic foraminiferal Ba/Ca correlates significantly to riverine runoff; however, the signals contain both spatial trends with distance to Ba source and species-specific influences such as micro-habitat preferences. We deduce that shallow-infaunal foraminifera are especially suitable as proxy for terrestrial Ba input and discuss the potential influence of water-column and pore-water Ba cycling. While distance to Ba source, water depth, pore-water geochemistry, and species-specific effects need to be considered in interpreting the data, our results demonstrate confidence in the use of Ba/Ca of benthic foraminifera from near-continent records as a proxy for past riverine discharge and to identify periods of drought.
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| 2. |
- Chaves, Alexandre de Oliveira, et al.
(author)
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The 920–900 Ma Bahia-Gangila LIP of the São Francisco and Congo cratons and link with Dashigou-Chulan LIP of North China craton : New insights from U-Pb geochronology and geochemistry
- 2019
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In: Precambrian Research. - : Elsevier BV. - 0301-9268. ; 329, s. 124-137
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Journal article (peer-reviewed)abstract
- A widespread mafic sill and dyke unit (the Pedro Lessa suite) adjacent to the southeastern São Francisco (SF) craton (eastern South America) is dated as 940 ± 42 Ma, 912 ± 17 Ma, and 986 ± 64 Ma (based on combined ID-TIMS and LA-ICPMS analyses on baddeleyite grains) on the Santa Maria de Itabira gabbroic intrusion. These ages suggest membership in the previously defined ca. 920–900 Ma Large Igneous Province (LIP) (herein referred to as the Bahia-Gangila LIP) of the reconstructed São Francisco and formerly adjacent Congo craton (Africa). Additional mafic and felsic units throughout the SF craton are also linked (based on a literature review), thus expanding the size of the reconstructed LIP to ca. 1,500,000 km2. Geochemistry reveals high Ti OIB signature for most units and low Ti E-MORB composition for the Gangila flood basalts, marking the initiation of attempted ocean opening. Geochemistry of the Bahia-Gangila LIP is also compared with the ca. 920–900 Ma Dashigou-Chulan LIP of the North China craton, and implications for three possible reconstructions of SF/Congo craton with the North China craton are considered.
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| 3. |
- Gumsley, Ashley, et al.
(author)
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Neoarchean large igneous provinces on the Kaapvaal Craton in southern Africa re-define the formation of the Ventersdorp Supergroup and its temporal equivalents
- 2020
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In: Geological Society of America Bulletin. - 0016-7606. ; 132:9-10, s. 1829-1844
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Journal article (peer-reviewed)abstract
- U-Pb geochronology on baddeleyite is a powerful technique that can be applied effectively to chronostratigraphy. In southern Africa, the Kaapvaal Craton hosts a well-preserved Mesoarchean to Paleoproterozoic geological record, including the Neoarchean Ventersdorp Supergroup. It overlies the Witwatersrand Supergroup and its world-class gold deposits. The Ventersdorp Supergroup comprises the Klipriviersberg Group, Platberg Group, and Pniel Group. However, the exact timing of formation of the Ventersdorp Supergroup is controversial. Here we present 2789 ± 4 Ma and 2787 ± 2 Ma U-Pb isotope dilution- thermal ionization mass spectrometry (ID-TIMS) baddeleyite ages and geochemistry on mafic sills intruding the Witwatersrand Supergroup, and we interpret these sills as feeders to the overlying Klipriviersberg Group flood basalts. This constrains the age of the Witwatersrand Supergroup and gold mineralization to at least ca. 2.79 Ga. We also report 2729 ± 5 Ma and 2724 ± 7 Ma U-Pb ID-TIMS baddeleyite ages and geochemistry from a mafic sill intruding the Pongola Supergroup and on an east-northeast-trending mafic dike, respectively. These new ages distinguish two of the Ventersdorp Supergroup magmatic events: the Klipriviersberg and Platberg. The Ventersdorp Supergroup can now be shown to initiate and terminate with two large igneous provinces (LIPs), the Klipriviersberg and Allanridge, which are separated by Platberg volcanism and sedimentation. The age of the Klipriviersberg LIP is 2791-2779 Ma, and Platberg volcanism occurred at 2754-2709 Ma. The Allanridge LIP occurred between 2709-2683 Ma. Klipriviersberg, Platberg, and Allanridge magmatism may be genetically related to mantle plume(s). Higher heat flow and crustal melting resulted as a mantle plume impinged below the Kaapvaal Craton lithosphere, and this was associated with rifting and the formation of LIPs.
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| 4. |
- Herrmann, Maria, et al.
(author)
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The effect of low-temperature annealing on discordance of U–Pb zircon ages
- 2021
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In: Scientific Reports. - : Springer Science and Business Media LLC. - 2045-2322. ; 11:1
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Journal article (peer-reviewed)abstract
- Discordant U–Pb data of zircon are commonly attributed to Pb loss from domains with variable degree of radiation damage that resulted from α-decay of U and Th, which often complicates the correct age interpretation of the sample. Here we present U–Pb zircon data from 23 samples of ca. 1.7–1.9 Ga granitoid rocks in and around the Siljan impact structure in central Sweden. Our results show that zircon from rocks within the structure that form an uplifted central plateau lost significantly less radiogenic Pb compared to zircon grains in rocks outside the plateau. We hypothesize that zircon in rocks within the central plateau remained crystalline through continuous annealing of crystal structure damages induced from decay of U and Th until uplifted to the surface by the impact event ca. 380 Ma ago. In contrast, zircon grains distal to the impact have accumulated radiation damage at shallow and cool conditions since at least 1.26 Ga, making them vulnerable to fluid-induced Pb-loss. Our data are consistent with studies on alpha recoil and fission tracks, showing that annealing in zircon occurs at temperatures as low as 200–250 °C. Zircon grains from these samples are texturally simple, i.e., neither xenocrysts nor metamorphic overgrowths have been observed. Therefore, the lower intercepts obtained from regression of variably discordant zircon data are more likely recording the age of fluid-assisted Pb-loss from radiation-damaged zircon at shallow levels rather than linked to regional magmatic or tectonic events.
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| 5. |
- Hoffmann, J. Elis, et al.
(author)
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Constraining the process of Eoarchean TTG formation in the Itsaq Gneiss Complex, southern West Greenland
- 2014
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In: Earth and Planetary Science Letters. - : Elsevier BV. - 1385-013X .- 0012-821X. ; 388, s. 374-386
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Journal article (peer-reviewed)abstract
- We present new major and trace element, high-precision high-field-strength-element, hafnium and neodymium isotope data for well preserved Eoarchean TTGs within the Itsaq Gneiss Complex (IGC) of southern West Greenland. These data are combined with thermodynamic model predictions of partial melting and fractional crystallization to gain new insights into continental crust formation in the Archean. Our results show that the observed compositional range of Eoarchean TTGs can be explained by a combination two processes: (1) 5-25% partial melting of amphibolite within thickened mafic crust and (2) subsequent fractional crystallization processes. The Eoarchean TTG suite of SW Greenland probably formed through mixing of melt batches that originally formed at different source depths between 10 and 14 kbar and ponded as plutons at mid-crustal levels. The trace element compositions of some TTGs point to subsequent fractional crystallization processes involving plagioclase, clinopyroxene, amphibole and garnet. Our model is consistent with recent studies proposing that the Eoarchean Itsaq Gneiss Complex TTGs from the IGC formed by re-working of mafic protocrust that stabilized as accreted juvenile crustal terranes in the Eoarchean. The model is also in good agreement with field observations from the area. (C) 2013 Elsevier B.V. All rights reserved.
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| 6. |
- Hoffmann, J. Elis, et al.
(author)
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Mechanisms of Archean crust formation inferred from high-precision HFSE systematics in TTGs
- 2011
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In: Geochimica et Cosmochimica Acta. - : Elsevier BV. - 0016-7037 .- 1872-9533. ; 75:15, s. 4157-4178
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Journal article (peer-reviewed)abstract
- It has been proposed that Archean tonalitic-trondhjemitic-granodioritic magmas (TTGs) formed by melting of mafic crust at high pressures. The residual mineralogy of the TTGs (either (garnet)-amphibolite or rutile-bearing eclogite) is believed to control the trace element budget of TTGs. In particular, ratios of high-field-strength elements (HFSE) can help to discriminate between the different residual lithologies. In order to place constraints on the source mineralogy of TTGs, we performed high-precision HFSE measurements by isotope dilution (Nb, Ta, Zr, Hf) together with Lu-Hf and Sm-Nd measurements on representative, ca. 3.85-2.8 Ga TTGs and related rock types from southern West Greenland, W-India and from the Superior Province. These measurements are complemented by major and trace element data for the TTGs. Texturally homogeneous early Archean (3.85-3.60 Ga old) and Mesoarchean (ca. 3.1-2.8 Ga old) TTGs have both low Ni (<11 ppm) and Cr contents (<20 ppm), indicating that there was little or no interaction with mantle peridotite during ascent. Ratios of Nb/Ta in juvenile Eoarchean TTGs range from ca. 7 to ca. 24, and in juvenile Mesoarchean TTGs from ca. 14 to ca. 27. Even higher Nb/Ta (14-42) were obtained for mig-matitic TTGs and intra-crustal differentiates, most likely mirroring further fractionation of Nb from Ta as a consequence of partial melting, fluid infiltration and migmatisation. In the juvenile TTGs, positive correlations between Nb/Ta and Gd/Yb, La/Yb, Sr/Y, Zr/Sm and Zr/Nb are observed. These compositional arrays are best explained by melting of typical Isua tholeiites in both, the rutile-bearing eclogite stability field (>15 kbar, high Nb/Ta) and the garnet-amphibolite stability field (10-15 kbar, low Nb/Ta). With respect to the low end of Nb/Ta found for TTGs, there is currently some uncertainty between the available experimental datasets for amphibole. Independent of these uncertainties, the TTG compositions found here still require the presence of both endmember residues. A successful geological model for the TTGs therefore has to account for the co-occurrence of both low-and high-Nb/Ta TTGs within the same geologic terrane. An additional feature observed in the Eoarchean samples from Greenland is a systematic co-variation between Nb/Ta and initial epsilon Hf(t), which is best explained by a model where TTG-melting occured at progressively increasing pressures in a pile of tectonically thickened mafic crust. The elevated Nb/Ta in mig-matitic TTGs and intra-crustal differentiates can shed further light on the role of intra-crustal differentiation processes in the global Nb/Ta cycle. Lower crustal melting processes at granulite facies conditions may generate high-Nb/Ta domains in the middle crust, whereas mid-crustal melting at amphibolite facies conditions may account for the low Nb/Ta generally observed in upper crustal rocks.
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| 7. |
- Hüssy, Karin, et al.
(author)
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It’s elemental, my dear watson : Validating seasonal patterns in otolith chemical chronologies
- 2021
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In: Canadian Journal of Fisheries and Aquatic Sciences. - : Canadian Science Publishing. - 0706-652X .- 1205-7533. ; 78:5, s. 551-566
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Journal article (peer-reviewed)abstract
- Accurate age data are essential for reliable fish stock assessment. Yet many stocks suffer from inconsistencies in age interpretation. A new approach to obtain age makes use of the chemical composition of otoliths. This study validates the periodicity of recurrent patterns in25 Mg,31 P,34 K,55 Mn,63 Cu,64 Zn,66 Zn,85 Rb,88 Sr,138 Ba, and208 Pb in Baltic cod (Gadus morhua) otoliths from tag–recapture and known-age samples. Otolith P concentrations showed the highest consistency in seasonality over the years, with minima co-occurring with otolith winter zones in the known-age otoliths and in late winter – early spring when water temperatures are coldest in tagged cod . The timing of minima differs between stocks, occurring around February in western Baltic cod and 1 month later in eastern Baltic cod; seasonal maxima are also stock-specific, occurring in August and October, respectively. The amplitude in P is larger in faster-growing western compared with eastern Baltic cod. Seasonal patterns with minima in winter – late spring were also evident in Mg and Mn, but less consistent over time and fish size than P. Chronological patterns in P, and to a lesser extent Mg and Mn, may have the potential to supplement traditional age estimation or to guide the visual identification of translucent and opaque otolith patterns used in traditional age estimation.
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| 8. |
- Keulen, Nynke, et al.
(author)
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Meso- and Neoarchaean geological history of the Bjornesund and Ravns Storo Supracrustal Belts, southern West Greenland: Settings for gold enrichment and corundum formation
- 2014
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In: Precambrian Research. - : Elsevier BV. - 0301-9268. ; 254, s. 36-58
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Journal article (peer-reviewed)abstract
- To understand the Mesa- and Neoarchaean geological history of the Bjornesund region, southern West Greenland (ca. 62-63 degrees N), we have undertaken an integrated study combining field observations with U-Pb zircon geochronology by LA-ICP-MS, metamorphic petrology, and microstructural analyses. The Bjornesund region links the southern part of the Fiskenaesset anorthosite complex to the well-preserved metavolcanic rocks of the Ravn Story Supracrustal Belt and the Bjornesund Supracrustal Belt, so the development of this region is of key interest to unravelling the Archaean geology of the entire region. In this study, we couple the observed phases of gold-enrichment and corundum formation to the geological history. The leucogabbroic rocks of the Bjornesund region, which are part of the Fiskenaesset complex, intruded at ca. 2.95 Ga into the tholeiitic and calc-alkaline metavolcanic rocks of the two studied belts. Following isoclinal folding, the rocks were intruded by diorite (2.92 Ga) and granodiorite (2.91 and 2.88 Ga), which are now texturally orthogneisses. The area was affected by three major phases of folding; F1 (undated), F2 at 2.85-2.83 Ga, and F3 at 2.71-2.70 Ga. The former deformation event is associated with the gold-enrichment in alteration zones in shear folds in metavolcanic amphibolite near the contact with the orthogneiss. Intrusion of granitic sheets during the F3 deformation triggered the formation of corundum, which is locally of gem quality, at the contact between leucogabbroic and ultramafic rocks. Peak metamorphic conditions were calculated as 580-630 degrees C and 6-4 kbar at 2.85-2.83 Ga. Later retrogression in the southern part of the area at ca. 500-450 degrees C and 4.5-3 kbar, and extensional fault reactivation overprinted some of the older structures. (C) 2014 Elsevier B.V. All rights reserved.
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