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- Adbo, Karina, et al.
(författare)
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Study of the kinetics of enantioselective solid-phase extraction on Tröger’s base molecularly imprinted polymers
- 2001
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Ingår i: Analytica Chimica Acta. - : Elsevier. - 0003-2670 .- 1873-4324. ; 435:1, s. 115-120
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Tidskriftsartikel (refereegranskat)abstract
- Molecularly imprinted polymers (MIPs) selective for Tröger’s base were designed and synthesised, and HPLC-chromatographic evaluation of polymer recognition characteristics was undertaken. Baseline separation of racemic Tröger’s base was readily achieved, and enantioseparation factors (α) of up to 4.8±0.2 were obtained. The high enantioselectivity demonstrated by these materials prompted their use to examine the kinetics and thermodynamics of individual enantiomers in a solid-phase extraction (SPE) process. Enantiomer-dependent differences in the rates and extent of adsorption were observed. Furthermore, the enantiomeric enrichment of racemates was demonstrated in batch studies.
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- Andersson, L I, et al.
(författare)
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Immunoassays using molecularly imprinted polymers
- 1995
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Ingår i: Immunoanalysis of agrochemicals. - : American Chemical Society (ACS). - 0841231494 ; , s. 89-97
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Konferensbidrag (övrigt vetenskapligt/konstnärligt)
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