| 1. |
- Itala, E, et al.
(författare)
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Molecular fragmentation of pyrimidine derivatives following site-selective carbon core ionization
- 2011
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Ingår i: Journal of Electron Spectroscopy and Related Phenomena. - : Elsevier BV. - 0368-2048 .- 1873-2526. ; 184:3-6, s. 119-124
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Tidskriftsartikel (refereegranskat)abstract
- Ionization-site-dependent fragmentation of three cyclic biomolecules - uracil, 5-bromouracil and thymine - has been studied using electron-energy-resolved photoelectronphotoion-photoion coincidence spectroscopy. Previous studies concerning ionization site dependent fragmentation have mainly been carried out with linear molecules. The results reported here show that all studied molecules have dicationic fragmentation channels whose intensity depends on the initial core-ionization site, although these channels cover only a relatively small fraction of the total fragment yield. The present study shows on one hand, that it is often the surrounding bond(s) of the ionized atom that will break following the initial core ionization, and on the other hand, that some specific fragmentation channels can display strong site-dependency where there is no direct correlation between the ionization site and the bond breakage locations.
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| 2. |
- AKSELA, H, et al.
(författare)
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PARTIAL AUGER DECAY-RATES OF CORE-IONIZED MOLECULAR-STATES IN HCL AND DCL
- 1995
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Ingår i: JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS. - : IOP PUBLISHING LTD. - 0953-4075. ; 28:19, s. 4259-4268
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- The Cl 2p ionization and the subsequent 2p(-1) --> 2 pi(-2) Auger decay in HCl and DCl molecules have been studied using synchrotron radiation. The Anger spectra have been decomposed and assigned to the transitions from the (2) Pi(1/2), (2) Sigma(1/2) and
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| 3. |
- Kikas, A., et al.
(författare)
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Resonant inelastic x-ray scattering and UV-VUV luminescence at the Be 1s edge in BeO
- 2010
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Ingår i: Journal of Physics: Condensed Matter. - : IOP Publishing. - 1361-648X .- 0953-8984. ; 22:37
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Tidskriftsartikel (refereegranskat)abstract
- We carried out a combined study of UV-VUV luminescence and resonant x-ray emission from BeO single crystals with incident photon energies in the vicinity of the Be 1s absorption edge. The x-ray emission spectra show that at the Be 1s photoabsorption edge the lattice relaxation processes in the excitation site take place already on the timescale of the radiative decay of the core excitation. Comparison of the x-ray emission and the luminescence spectra indicates that the maximum energy loss of the process of lattice relaxation during the decay of inner-shell holes is similar to the loss that occurs in the self-trapping process of valence excitons. The possible decay channels of core excitations have been discussed and the mechanism for the creation of 5.2 eV luminescence at the photoabsorption resonances has been suggested.
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| 4. |
- Kukk, E, et al.
(författare)
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Auger decay of the dissociating core-excited states in the HCl and DCl molecules
- 1996
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Ingår i: JOURNAL OF CHEMICAL PHYSICS. - : AMER INST PHYSICS. ; 104:12, s. 4475-4480
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- High-resolution Auger electron spectra from the decay of the Cl 2p-->sigma* excitation in HCl and DCl have been measured. The spectra are analyzed, separating molecular and atomic features, which are assigned to transitions to the HCl (5 sigma 2 pi)(4) si
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| 5. |
- Kukk, E, et al.
(författare)
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Core-to-Rydberg excitations and their Auger decay in the HCl and DCl molecules
- 1996
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Ingår i: PHYSICAL REVIEW A. - : AMER INST PHYSICS. - 1050-2947. ; 54:3, s. 2121-2126
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Tidskriftsartikel (övrigt vetenskapligt/konstnärligt)abstract
- The resonant Anger electron spectra of the HCl and DCl molecules have been measured at the first core-to-Rydberg resonances. The low binding energy region of the spectra has been decomposed into transitions to different bound states and their vibrational
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| 6. |
- Levola, H., et al.
(författare)
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Fragmentation of thymidine induced by ultraviolet photoionization and thermal degradation
- 2013
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Ingår i: International Journal of Mass Spectrometry. - : Elsevier BV. - 1387-3806 .- 1873-2798. ; 353, s. 7-11
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Tidskriftsartikel (refereegranskat)abstract
- Fragmentation of gas phase thymidine at different temperatures was studied with vacuum ultraviolet radiation and time-of-flight spectroscopy. Partial ion yield measurements were carried out in order to study the appearance energies of thymidine and its main fragments. The appearance energies of thymidine and its deoxyribose- and thymine-based fragments were determined to be 8.39, 8.77 and 8.81 eV, independently of temperature. The thermal decomposition of the sample was observed to start around 138-139 C and it was explained by the breakage of the glycosidic bond, accompanied by hydrogen transfer from the deoxyribose ring to the thymine base.
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| 7. |
- Patanen, M., et al.
(författare)
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High-resolution study of K 3p photoabsorption and resonant Auger decay in KF
- 2009
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Ingår i: Physical Review A (Atomic, Molecular and Optical Physics). - 1050-2947. ; 80:1
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Tidskriftsartikel (refereegranskat)abstract
- High-resolution (K3p sigma and pi)->sigma absorption spectrum of KF in the photon energy range of 18.2-19.4 eV was measured at the new FINEST beamline branch on the I3 beamline on MAX III. The experimental spectrum is presented and interpreted using nonrelativistic ab initio molecular calculations corrected with perturbation theory treatment to account for spin-orbit interaction. Resonant Auger decay recorded at the strongest resonances is also presented and reproduced by theoretical calculations. Also a brief introduction to the FINEST beamline branch is presented.
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| 8. |
- Pärna, R., et al.
(författare)
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FinEstBeaMS – A wide-range Finnish-Estonian Beamline for Materials Science at the 1.5 GeV storage ring at the MAX IV Laboratory
- 2017
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Ingår i: Nuclear Instruments and Methods in Physics Research, Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. - : Elsevier BV. - 0168-9002. ; 859, s. 83-89
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Tidskriftsartikel (refereegranskat)abstract
- The FinEstBeaMS beamline is under construction at the 1.5 GeV storage ring of the MAX IV Laboratory at Lund, Sweden. It has been designed to cover an unusually wide energy range from ultraviolet (4.3 eV) to soft X-rays (1000 eV) but experiments will also be possible at the Mg and Al Kα energies. Instead of having two different insertion devices and optical schemes for low and high photon energy regions, we have based our design on a single long-period, elliptically polarizing undulator and a plane grating monochromator. This solution will provide very good conditions for planned experiments in the whole photon energy region. The beamline will have two branches: one will mainly be used to investigate free atoms, molecules and clusters with photoelectron/photoion coincidence spectroscopy as well as solids with photoluminescence spectroscopy whereas the other one will be dedicated to ultra-high vacuum studies of surfaces and interfaces, utilizing X-ray photoelectron spectroscopy and X-ray absorption spectroscopy. This paper focuses on the optical design of the beamline and general design concepts of the gas phase and solid state end stations.
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| 9. |
- Urpelainen, S., et al.
(författare)
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FINEST:A high performance branch-line for VUV photon energy range gas phase studies at MAX-lab
- 2010
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Ingår i: AIP Conference Proceedings. - : AIP. - 0094-243X. - 9780735407824 ; 1234, s. 411-414
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Konferensbidrag (refereegranskat)abstract
- We present a dedicated beamline branch for high flux and ultra-high resolution (R>100000) gas and vapor phase studies in the vacuum-ultra-violet (VUV) region of light on the undulator beamline I3, located on the 700 MeV MAX-III storage ring. The mechanical and optical design of the branch-line, the differential pumping setup as well as performance characteristics are presented.
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| 10. |
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