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- Olsson Månsson, Emma, 1992, et al.
(författare)
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Removal of Inorganic Impurities in the Fast Pyrolysis Bio-oil Using Sorbents at Ambient Temperature
- 2024
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Ingår i: Energy & Fuels. - 1520-5029 .- 0887-0624. ; 38:1, s. 414-4254
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Tidskriftsartikel (refereegranskat)abstract
- Fast pyrolysis bio-oil (FPBO) sourced from residual biomass waste (such as sawdust) is a promising feedstock that may be used for biofuel production. Their inorganic elements may, however, vary and cause deactivation of the catalysts in the hydrodeoxygenation (HDO) upgrading biorefinery unit. It was found that the use of zeolite Y and strong acidic ion-exchange resins as adsorbents was almost equally efficient in lowering the concentrations of Ca from <10 to <1 ppm and of Fe, K, and Mg to <0.3 ppm in FPBO at 30 °C, atmospheric pressure, and 4 h adsorption time. The removal efficiency of zeolite and resins exceeded 85–98% (detection limit) of these particular elements. For the first time for the FPBO, phosphorus was reported as being successfully targeted by aluminum oxide, being lowered from 1 ppm to <0.1 ppm, which is a reduction of at least 90%. Characterization of the oil and sorbents suggests that the surface acidity affects the removal efficiency of these elements from FPBO. Organic compounds in the pyrolysis oil, including isopropanol, lactic acid, hydroxy acetone, furfural, guaiacol, and levoglucosan, were semiquantified using two-dimensional gas chromatography coupled with mass spectrometry (GCxGC-MS). Compared to the fresh oil, the compositions and contents of these organic compounds were not impacted significantly by the sorbents under these mild operating conditions. This research indicates that inorganic impurities present in bio-oils can be removed, and thus, they may be considered feedstocks for producing biofuels with less deactivation of HDO catalysts.
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| 2. |
- Dhakal, Prabin, 1994, et al.
(författare)
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Producing upgradeable bio-oil from food bio-waste via hybrid-assisted pretreatment coupled with catalytic hydrotreatment
- 2023
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Ingår i: Bioresource Technology Reports. - 2589-014X. ; 24
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Tidskriftsartikel (refereegranskat)abstract
- Slurry food waste sourced from Renova (Gothenburg, Sweden) was investigated as a model for generating upgradeable bio-oil via a hybrid-assisted pretreatment along with a catalytic hydrotreatment process. Hybrid-assisted pretreatment has been examined for extracting and stabilizing of reactive-derived substances. For the resulting bio-crude and residual solids, the properties of the heteroatoms were also examined prior to the catalytic hydrotreatment experiments. Hybrid-assisted pretreatment is an interesting solution in that it maximizes the bio-crude yield and transfers significant amounts of the nitrogenous content (De-N ∼83.3 %, dry basis) into the residual solids. Nearly 87 wt% of the oxygenated monomers were found in the obtained bio-crude, which possessed 52.0 wt% of alcohols. The highest upgradeable bio-oil of 86.0 wt% was achieved during catalytic hydrotreatment of the bio-crude and residual solids jointly: producing blends of up to 78 wt% of hydrocarbons, 14 wt% oxygenated and <6 wt% of cyclic, aromatics, N-containing components.
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