| 1. |
- Lindh, Linnea, et al.
(författare)
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Dye-sensitized solar cells based on Fe N-heterocyclic carbene photosensitizers with improved rod-like push-pull functionality
- 2021
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Ingår i: Chemical Science. - : Royal Society of Chemistry (RSC). - 2041-6520 .- 2041-6539. ; 12:48, s. 16035-16053
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Tidskriftsartikel (refereegranskat)abstract
- A new generation of octahedral iron(ii)-N-heterocyclic carbene (NHC) complexes, employing different tridentate C^N^C ligands, has been designed and synthesized as earth-abundant photosensitizers for dye sensitized solar cells (DSSCs) and related solar energy conversion applications. This work introduces a linearly aligned push-pull design principle that reaches from the ligand having nitrogen-based electron donors, over the Fe(ii) centre, to the ligand having an electron withdrawing carboxylic acid anchor group. A combination of spectroscopy, electrochemistry, and quantum chemical calculations demonstrate the improved molecular excited state properties in terms of a broader absorption spectrum compared to the reference complex, as well as directional charge-transfer displacement of the lowest excited state towards the semiconductor substrate in accordance with the push-pull design. Prototype DSSCs based on one of the new Fe NHC photosensitizers demonstrate a power conversion efficiency exceeding 1% already for a basic DSSC set-up using only the I−/I3−redox mediator and standard operating conditions, outcompeting the corresponding DSSC based on the homoleptic reference complex. Transient photovoltage measurements confirmed that adding the co-sensitizer chenodeoxycholic acid helped in improving the efficiency by increasing the electron lifetime in TiO2. Time-resolved spectroscopy revealed spectral signatures for successful ultrafast (<100 fs) interfacial electron injection from the heteroleptic dyes to TiO2. However, an ultrafast recombination process results in undesirable fast charge recombination from TiO2back to the oxidized dye, leaving only 5-10% of the initially excited dyes available to contribute to a current in the DSSC. On slower timescales, time-resolved spectroscopy also found that the recombination dynamics (longer than 40 μs) were significantly slower than the regeneration of the oxidized dye by the redox mediator (6-8 μs). Therefore it is the ultrafast recombination down to fs-timescales, between the oxidized dye and the injected electron, that remains as one of the main bottlenecks to be targeted for achieving further improved solar energy conversion efficiencies in future work.
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| 2. |
- Allentoft, Morten E., et al.
(författare)
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Population genomics of post-glacial western Eurasia
- 2024
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Ingår i: Nature. - 0028-0836 .- 1476-4687. ; 625:7994, s. 301-311
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Tidskriftsartikel (refereegranskat)abstract
- Western Eurasia witnessed several large-scale human migrations during the Holocene1–5. Here, to investigate the cross-continental effects of these migrations, we shotgun-sequenced 317 genomes—mainly from the Mesolithic and Neolithic periods—from across northern and western Eurasia. These were imputed alongside published data to obtain diploid genotypes from more than 1,600 ancient humans. Our analyses revealed a ‘great divide’ genomic boundary extending from the Black Sea to the Baltic. Mesolithic hunter-gatherers were highly genetically differentiated east and west of this zone, and the effect of the neolithization was equally disparate. Large-scale ancestry shifts occurred in the west as farming was introduced, including near-total replacement of hunter-gatherers in many areas, whereas no substantial ancestry shifts happened east of the zone during the same period. Similarly, relatedness decreased in the west from the Neolithic transition onwards, whereas, east of the Urals, relatedness remained high until around 4,000 bp, consistent with the persistence of localized groups of hunter-gatherers. The boundary dissolved when Yamnaya-related ancestry spread across western Eurasia around 5,000 bp, resulting in a second major turnover that reached most parts of Europe within a 1,000-year span. The genetic origin and fate of the Yamnaya have remained elusive, but we show that hunter-gatherers from the Middle Don region contributed ancestry to them. Yamnaya groups later admixed with individuals associated with the Globular Amphora culture before expanding into Europe. Similar turnovers occurred in western Siberia, where we report new genomic data from a ‘Neolithic steppe’ cline spanning the Siberian forest steppe to Lake Baikal. These prehistoric migrations had profound and lasting effects on the genetic diversity of Eurasian populations.
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| 3. |
- Dahlberg, Hannes, et al.
(författare)
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Ferroelectric-Antiferroelectric Transition of Hf1- xZrxO2on Indium Arsenide with Enhanced Ferroelectric Characteristics for Hf0.2Zr0.8O2
- 2022
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Ingår i: ACS Applied Electronic Materials. - : American Chemical Society (ACS). - 2637-6113. ; 4:12, s. 6357-6363
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Tidskriftsartikel (refereegranskat)abstract
- The ferroelectric (FE)-antiferroelectric (AFE) transition in Hf1-xZrxO2 (HZO) is for the first time shown in a metal-ferroelectric-semiconductor (MFS) stack based on the III-V material InAs. As InAs displays excellent electron mobility and a narrow band gap, the integration of ferroelectric thin films for nonvolatile operations is highly relevant for future electronic devices and motivates further research on ferroelectric integration. When increasing the Zr fraction x from 0.5 to 1, the stack permittivity increases as expected, and the transition from FE to AFE-like behavior is observed by polarization and current-voltage characteristics. At x = 0.8 the polarization of the InAs-based stacks shows a larger FE-contribution as a more open hysteresis compared to both literature and reference metal-ferroelectric-metal (MFM) devices. By field-cycling the devices, the switching domains are studied as a function of the cycle number, showing that the difference in FE-AFE contributions for MFM and MFS devices is stable over switching and not an effect of wake-up. The FE contribution of the switching can be accessed by successively lowering the bias voltage in a proposed pulse train. The possibility of enhanced nonvolatility in Zr-rich HZO is relevant for device stacks that would benefit from an increase in permittivity and a lower operating voltage. Additionally, an interfacial layer (IL) is introduced between the HZO film and the InAs substrate. The interfacial quality is investigated as frequency-dependent capacitive dispersion, showing little change for varying ZrO2 concentrations and with or without included IL. This suggests material processing that is independently limiting the interfacial quality. Improved endurance of the InAs-Hf1-xZrxO2 devices with x = 0.8 was also observed compared to x = 0.5, with further improvement with the additional IL for Zr-rich HZO on InAs.
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| 4. |
- Dalui, Malay, et al.
(författare)
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Influence of micromachined targets on laser accelerated proton beam profiles
- 2018
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Ingår i: Plasma Physics and Controlled Fusion. - : IOP Publishing. - 0741-3335 .- 1361-6587. ; 60:3
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Tidskriftsartikel (refereegranskat)abstract
- High intensity laser-driven proton acceleration from micromachined targets is studied experimentally in the target-normal-sheath-acceleration regime. Conical pits are created on the front surface of flat aluminium foils of initial thickness 12.5 and 3 μm using series of low energy pulses (0.5-2.5 μJ). Proton acceleration from such micromachined targets is compared with flat foils of equivalent thickness at a laser intensity of 7 ×1019 W cm-2. The maximum proton energy obtained from targets machined from 12.5 μm thick foils is found to be slightly lower than that of flat foils of equivalent remaining thickness, and the angular divergence of the proton beam is observed to increase as the depth of the pit approaches the foil thickness. Targets machined from 3 μm thick foils, on the other hand, show evidence of increasing the maximum proton energy when the depths of the structures are small. Furthermore, shallow pits on 3 μm thick foils are found to be efficient in reducing the proton beam divergence by a factor of up to three compared to that obtained from flat foils, while maintaining the maximum proton energy.
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| 5. |
- Erjefält, Jonas, et al.
(författare)
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Allergen-induced eosinophil cytolysis is a primary mechanism for granule protein release in human upper airways
- 1999
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Ingår i: American Journal of Respiratory and Critical Care Medicine. - 1535-4970. ; 160:1, s. 304-312
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Tidskriftsartikel (refereegranskat)abstract
- Cytotoxic eosinophil granule proteins are considered important in the pathogenesis of allergic airway diseases such as rhinitis and asthma. To explore the cellular mechanisms behind eosinophil granule release in human allergic airways, 16 symptom-free patients with seasonal allergic rhinitis were challenged daily with allergen during 1 wk. Nasal lavage samples and biopsies, obtained before and 24 h after the last allergen exposure, were processed for immunohistochemical and electron microscopic analysis. The allergen challenges produced nasal symptoms, marked tissue eosinophilia, and an increase in lavage fluid levels of eosinophil cationic protein (ECP). The nasal mucosa areas with intense extracellular immunoreactivity for ECP were associated with abundant free eosinophil granules. Electron microscopy confirmed the free granules and revealed that all mucosal eosinophils were involved in granule release, either by cytolysis (33%) or piecemeal degranulation (PMD) (67%). Resting or apoptotic eosinophils were not observed. Cytolytic eosinophils had less signs of intracellular granule release (p < 0. 001) and a higher content of intact granules (p < 0.001) compared with viable eosinophils in the same tissue. This study demonstrates eosinophil cytolysis (ECL) as a distinct mechanism for granule mediator release in human allergic airway mucosa. The nature and extent of the ECL and its product (i.e., protein-laden extracellular granules) indicate that allergen-induced cytolysis is a primary and major mechanism for the release of eosinophil proteins in human allergic airway inflammation in vivo.
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| 6. |
- Holm, Hannes, et al.
(författare)
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A quantitative evaluation of vulnerability scanning
- 2011
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Ingår i: Information Management & Computer Security. - : Emerald Group Publishing Limited. - 0968-5227 .- 1758-5805. ; 19:4, s. 231-247
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Tidskriftsartikel (refereegranskat)abstract
- Purpose – The purpose of this paper is to evaluate if automated vulnerability scanning accurately identifies vulnerabilities in computer networks and if this accuracy is contingent on the platforms used.Design/methodology/approach – Both qualitative comparisons of functionality and quantitative comparisons of false positives and false negatives are made for seven different scanners. The quantitative assessment includes data from both authenticated and unauthenticated scans. Experiments were conducted on a computer network of 28 hosts with various operating systems, services and vulnerabilities. This network was set up by a team of security researchers and professionals.Findings – The data collected in this study show that authenticated vulnerability scanning is usable. However, automated scanning is not able to accurately identify all vulnerabilities present in computer networks. Also, scans of hosts running Windows are more accurate than scans of hosts running Linux.Research limitations/implications – This paper focuses on the direct output of automated scans with respect to the vulnerabilities they identify. Areas such as how to interpret the results assessed by each scanner (e.g. regarding remediation guidelines) or aggregating information about individual vulnerabilities into risk measures are out of scope.Practical implications – This paper describes how well automated vulnerability scanners perform when it comes to identifying security issues in a network. The findings suggest that a vulnerability scanner is a useable tool to have in your security toolbox given that user credentials are available for the hosts in your network. Manual effort is however needed to complement automated scanning in order to get satisfactory accuracy regarding network security problems.Originality/value – Previous studies have focused on the qualitative aspects on vulnerability assessment. This study presents a quantitative evaluation of seven of the most popular vulnerability scanners available on the market.
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| 7. |
- Karlsson, Hannes, et al.
(författare)
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Deep-learning-based denoising for photon-counting CT : Image domain or projection domain?
- 2022
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Ingår i: MEDICAL IMAGING 2022. - : SPIE-Intl Soc Optical Eng.
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Konferensbidrag (refereegranskat)abstract
- Photon-counting detectors (PCD) are the most recent advancement in computed tomography (CT). PCDs allow, among other things, for material decomposition, which decomposes the imaged object into a set of basis materials. Another field that is gaining attention, is the use of deep learning to improve the image reconstruction process in CT. In this work, we study the use of deep learning, specifically convolutional neural networks trained on the KiTS19 Challenge kidney data set, to improve the image quality of basis images resulting from three-material decomposition, a problem that is difficult due to its high sensitivity to noise. Our objective is to compare different network architectures and investigate whether these are best implemented in the projection domain or in the image domain. We study three different network architectures: U-Net, Dilated U-Net and ResNet, each applied in either the image domain or in the projection domain. The resulting image quality is evaluated in terms of contrast-to-noise ratio, task transfer function and noise power spectrum. Results show that for the type of phantoms the networks were trained on, the most effective option is to implement the network in the image domain and to use either the U-Net or Dilated U-Net architectures. However, when applying the networks to other phantoms, it seems that the networks in the sinogram generalize better, and produce better results. We also discuss why this might be the case, compare it with previous research, and consider what further improvements can be made.
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| 8. |
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| 9. |
- Mogensen, Hannes, et al.
(författare)
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Non-Invasive Ultrasonic Measurement of the Relative Volume Change of the Arterial Wall - First in vivo trial
- 2008
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Ingår i: 2008 IEEE Ultrasonics symposium, vols 1-4 and appendix. - 1051-0117. ; , s. 856-858
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Konferensbidrag (refereegranskat)abstract
- The objective of this study was to show a method that combine non-invasive measurements of the relative diameter change, the radial and the longitudinal strain of the intima-media complex of arterial walls, respectively, to obtain total change in arterial wall volume for a segment of the common carotid artery. The method was evaluated in a limited trial in vivo, comprising five normotensive subjects. Compared to the volume at end-diastole, the average maximum increase in arterial wall volume during each cardiac cycle was 3.2 % (SD 1.8). The aver-age maximum decrease of the arterial wall volume was -5.7 % (SD 3.5). This provides a new way of examining and quantifying the elastic properties of arterial walls.
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| 10. |
- Persson, Hannes, et al.
(författare)
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Evaluation of Soft Information based JPEG2000 Decoders
- 2004
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Konferensbidrag (refereegranskat)abstract
- Error free transmission is not always possible in todays nor future's communication networks without making retransmissions. Retransmissions, however, introduce delay. To delay sensitive applications the concept of soft information, i.e. lower layer knowledge about the channel conditions, could reduce the number of retransmissions. This paper explores the utilization of soft information in image decoding. It is not sufficient to treat the soft information and the image decoder separately. By combining soft information and error resilience in the decoder the image quality can be improved. Two modified JPEG2000 image decoders that utilize soft information have been developed. Experiment results with images transmitted over a simulated wireless channel show that a simple decoding process which utilizes soft information can give high gains in image quality. Only marginally higher gains are observed with a more complex decoding process
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