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- Chen, Miaoxiang, 1962-, et al.
(författare)
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1 micron wavelength photo- and electroluminescence from a conjugated polymer
- 2004
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Ingår i: Applied Physics Letters. - : AIP Publishing. - 0003-6951 .- 1077-3118. ; 84:18, s. 3570-3572
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Tidskriftsartikel (refereegranskat)abstract
- We report photo- and electroluminescence from an alternating conjugated polymer consisting of fluorene units and low-band gap donor-acceptor-donor (D-A-D) units. The D-A-D segment includes two electron-donating thiophene rings combined with a thiadiazolo-quinoxaline unit, which is electron withdrawing to its nature. The resulting polymer is conjugated and has a band gap of 1.27 eV. The corresponding electro- and photoluminescence spectra both peak at approximately 1 mum. Light-emitting diodes, based on a single layer of the polymer, demonstrated external quantum efficiencies from 0.03% to 0.05%.
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| 2. |
- Chen, Miaoxiang, et al.
(författare)
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Low band gap donor–acceptor–donor polymers for infra-red electroluminescence and transistors
- 2004
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Ingår i: Synthetic metals. - : Elsevier BV. - 0379-6779 .- 1879-3290. ; 146:3, s. 233-236
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Tidskriftsartikel (refereegranskat)abstract
- We report on transistors and light-emitting diodes using a conjugated polymer consisting of alternated segments of fluorene units and low-band gap donor–acceptor–donor (D–A–D) units. The D–A–D segment includes two electron-donating thiophene rings combined with a thiadiazolo-quinoxaline unit, which is electron withdrawing to its nature. The resulting polymer is conjugated and has a band gap of around 1.27 eV. Here we present the corresponding electro- and photoluminescence spectra, which both peak at approximately 1 μm. Single layer light-emitting diodes demonstrated external quantum efficiencies from 0.03% to 0.05%. The polymer was employed as active material in thin film transistors, a field-effect mobility of 3 × 10−3 cm2/V s and current on/off ratio of 104 were achieved at ambient atmosphere.
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| 6. |
- Jönsson, Stina, et al.
(författare)
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Electronic structure of novel low band gap conjugated polymers
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Annan publikation (övrigt vetenskapligt/konstnärligt)abstract
- The electronic structures of two novel low band gap conjugated polymers have been studied. Both materials are conjugated alternating copolymers based on fluorene units and low band gap donor-acceptor-donor units. The emphasis in this study has been to study the valence and the conduction bands. In particular the degree of localization or delocalization along the polymers and the symmetry of these states have been studied, since these features can be related to their transport properties. The main experimental part of this work is photoelectron spectroscopy, near-edge X-ray photon absorption and resonant photoemission. These techniques have been used to probe the frontier electronic structure of these systems. The experimental results are interpreted with the help of density functional theory calculations. The valence bands are dispersed originating from orbitals delocalized along the polymer chain shile the conduction bands are more flat, as they are derived from orbitals localized on the acceptor units. This band structure would predict good hole transporting properties but poor electron transport.
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