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- Santos, Olga, et al.
(författare)
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Modified stainless steel surfaces targeted to reduce fouling - surface characterization
- 2004
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Ingår i: Journal of Food Engineering. - : Elsevier BV. - 0260-8774. ; 64:1, s. 63-79
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Tidskriftsartikel (refereegranskat)abstract
- The surface properties of several modified stainless steel samples were characterized according to their chemical composition, roughness, topography and wettability. The modifications tested were SiF3+ and MoS22+ ion implantation; diamond-like carbon (DLC) sputtering: DLC. DLC-Si-O and SiOx, plasma enhanced chemical vapor deposition (PECVD); autocatalytic Ni-P-PTFE and silica coating. X-ray photoelectron spectroscopy (XPS) and X-ray microanalysis were applied to determine the surface chemical composition. Atomic force microscopy (AFM) and stylus-type instruments were used for roughness determination, and the surface topography was imaged with AFM and scanning electron microscopy (SEM). The contact angle and surface tension were measured with the Wilhelmy plate method and the sessile drop method. For thick modified layers, only the elements of the coating were detected at the surface, whereas for thin layers the surface composition determined was that of the stainless steel substrate. The roughness of the 2R (cold rolled and annealed in a protective atmosphere) Surfaces was not altered by the modification techniques (except for the Ni-P-PTFE coating), while for the 2B (cold rolled. heat treated, pickled and skinpassed) surfaces an increase in roughness was observed. The silica coating produced surfaces with consistent roughness, independent of which steel substrate was used. DLC sputtering and Ni-P-PTFE coating produced surfaces with the highest roughness. All modified surfaces revealed a similar surface topography with the exception of the Ni-P-PTFE coating, for which the coating masked the underlying steel topography. In terms of wettability, the SiOx-plasmaCVD and NiP-PTFE coating, techniques produced the most hydrophilic and hydrophobic surfaces, respectively. (C) 2003 Elsevier Ltd. All rights reserved.
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- Wilson, Stephanie J., et al.
(författare)
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Global subterranean estuaries modify groundwater nutrient loading to the ocean
- 2024
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Ingår i: Limnology And Oceanography Letters. - 2378-2242.
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Tidskriftsartikel (refereegranskat)abstract
- Terrestrial groundwater travels through subterranean estuaries before reaching the sea. Groundwater-derived nutrients drive coastal water quality, primary production, and eutrophication. We determined how dissolved inorganic nitrogen (DIN), dissolved inorganic phosphorus (DIP), and dissolved organic nitrogen (DON) are transformed within subterranean estuaries and estimated submarine groundwater discharge (SGD) nutrient loads compiling > 10,000 groundwater samples from 216 sites worldwide. Nutrients exhibited complex, nonconservative behavior in subterranean estuaries. Fresh groundwater DIN and DIP are usually produced, and DON is consumed during transport. Median total SGD (saline and fresh) fluxes globally were 5.4, 2.6, and 0.18 Tmol yr−1 for DIN, DON, and DIP, respectively. Despite large natural variability, total SGD fluxes likely exceed global riverine nutrient export. Fresh SGD is a small source of new nutrients, but saline SGD is an important source of mostly recycled nutrients. Nutrients exported via SGD via subterranean estuaries are critical to coastal biogeochemistry and a significant nutrient source to the oceans.
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- Grewe, E. W., et al.
(författare)
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Studies on the double-beta decay nucleus Zn-64 using the (d,He-2) reaction
- 2008
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Ingår i: Physical Review C - Nuclear Physics. - 2469-9985 .- 2469-9993. ; 77:6
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Tidskriftsartikel (refereegranskat)abstract
- The (d,He-2) charge-exchange reaction on the double-beta decay (beta beta) nucleus Zn-64 has been studied at an incident energy of 183 MeV. The two protons in the S-1(0) state (indicated as He-2) were both momentum analyzed and detected simultaneously by the BBS magnetic spectrometer and its position-sensitive detector. He-2 spectra with a resolution of about 115 keV (FWHM) have been obtained allowing identification of many levels in the residual nucleus Cu-64 with high precision. Zn-64 is one of the rare cases undergoing a beta beta decay in beta(+) direction. In the experiment presented here, Gamow-Teller (GT(+)) transition strengths have been extracted. Together with the GT(-) transition strengths from Ni-64(He-3,t) data to the same intermediate nucleus Cu-64, the nuclear matrix elements of the beta beta decay of Zn-64 have been evaluated. Finally, the GT(+/-) distributions are compared with shell-model calculations and a critical assessment is given of the various residual interactions presently employed for the pf shell.
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