| 1. |
|
|
| 2. |
|
|
| 3. |
|
|
| 4. |
- Arya, N., et al.
(författare)
-
Porosity-Engineered CNT-MoS2 Hybrid Nanostructures for Bipolar Supercapacitor Applications
- 2023
-
Ingår i: ACS Applied Materials and Interfaces. - : American Chemical Society. - 1944-8244 .- 1944-8252. ; 15:29, s. 34818-34828
-
Tidskriftsartikel (refereegranskat)abstract
- Bipolar supercapacitors that can store many fold higher capacitance in negative voltage compared to positive voltage are of great importance if they can be engineered for practical applications. The electrode material encompassing high surface area, better electrochemical stability, high conductivity, moderate distribution of pore size, and their interaction with suitable electrolytes is imperative to enable bipolar supercapacitor performance. Apropos of the aforementioned aspects, the intent of this work is to ascertain the effect of ionic properties of different electrolytes on the electrochemical properties and performance of a porous CNT-MoS2 hybrid microstructure toward bipolar supercapacitor applications. The electrochemical assessment reveals that the CNT-MoS2 hybrid electrode exhibited a two- to threefold higher areal capacitance value of 122.3 mF cm-2 at 100 μA cm-2 in 1 M aqueous Na2SO4 and 42.13 mF cm-2 at 0.30 mA cm-2 in PVA-Na2SO4 gel electrolyte in the negative potential window in comparison to the positive potential window. The CNT-MoS2 hybrid demonstrates a splendid Coulombic efficiency of ∼102.5% and outstanding stability with capacitance retention showing a change from 100% to ∼180% over 7000 repeated charging-discharging cycles. © 2023 American Chemical Society.
|
|
| 5. |
- Attri, Shubham Dutt, et al.
(författare)
-
Multi-attribute sustainability assessment of wastewater treatment technologies using combined fuzzy multi-criteria decision-making techniques
- 2022
-
Ingår i: Journal of Cleaner Production. - : Elsevier BV. - 0959-6526 .- 1879-1786. ; 357
-
Tidskriftsartikel (refereegranskat)abstract
- Water, which is predicted to be one of the most critical resources for the near future, also plays a vital role in society's sustainable development. Wastewater treatment is a critical part of the circular water management system and offers various technological alternatives. Taking appropriate decision for the technology selection is, therefore, essential for a long-term perspective. A complex yet imperative process is the sustainable selection of the wastewater treatment process. This paper presents the use of multi-criteria decision-making (MCDM) in the sustainability assessment of wastewater treatment technologies that may be very relevant to the growing sector with many emerging options. A comparison of six wastewater treatment technologies based on four sustainability parameters using three MCDM techniques, namely FSWARA, FMOORA and FTOPSIS is presented in detail. FSWARA is used for weighting criteria and the other two for technology ranking. The detailed step-by-step comparison study is presented and the results were somewhat predictable for the study, and this confirms the reliability of the methodology. This paper's primary objective is to propose a well-defined increscent practice for making sustainable wastewater treatment decisions among state-of-the-art technologies.
|
|
| 6. |
- Barthwal, M., et al.
(författare)
-
Effect of Nanomaterial Inclusion in Phase Change Materials for Improving the Thermal Performance of Heat Storage : A Review
- 2021
-
Ingår i: ACS Applied Energy Materials. - : American Chemical Society (ACS). - 2574-0962. ; 4:8, s. 7462-7480
-
Tidskriftsartikel (refereegranskat)abstract
- Dispersion of nanoparticles is one of the potential solutions to improve the thermophysical properties of phase change (or transition) materials (PCMs) and enhance the performance of latent thermal energy storage (LTES) systems. The PCM ought to have a high latent heat of fusion, and zero or negligible coefficient of thermal expansion. A good PCM should have melting and solidification compatibility with negligible or zero subcooling, and it should not react with the common chemical reagents. The present known PCMs possess low thermal conductivity that results into a longer solidification and melting time of PCMs. In the past two decades, researchers have reported improved thermal conductivity and heat-storing capacity of PCMs employing graphite nanoparticles/fibers, carbon nanotubes/fibers, metal, and metal oxide nanoparticles. This work reviews the reported experimental and numerical studies describing the consequences of nanoparticle inclusions of various shapes and sizes on the thermal properties of the PCMs. This review attempts to make a consolidated database of the studies related to nanoadditive inclusion into PCMs for various applications. Graphene dispersed into PCM has resulted into 14 times thermal conductivity enhancement. As far as metal oxide nanoparticles are concerned, TiO2 and Al2O3 nanoparticles outperformed others. The compatibility between the nanoadditive and PCM is necessary to tailor favorable thermal properties. This work reviews numerous studies of different nanoparticle-PCM duos. © 2021 American Chemical Society.
|
|
| 7. |
|
|
| 8. |
- Bonthu, D., et al.
(författare)
-
3D printed functionally graded foams response under transverse load
- 2023
-
Ingår i: Results in Materials. - : Elsevier B.V.. - 2590-048X. ; 19
-
Tidskriftsartikel (refereegranskat)abstract
- The applications of 3D printing are rapidly increasing in aerospace and naval applications. Nonetheless, 3D printing (3DP) of graded foams exhibiting property variation along the thickness direction is yet to be explored. In the current work, the different volume fractions of hollow glass micro balloon (GMB) reinforced high-density polyethylene (HDPE) composite based graded foams are 3D printed using the fused deposition modelling (FDM) technique. The bonding between successive layers and porosity distribution of these graded configurations are studied using micro-CT scan. Further, the 3D Printed functionally graded foams (FGFs) are tested for flexural response, and results are compared with numerical values. The micro-CT results showed delamination absence between the layers. In neat HDPE layers, porosity is not evident, while minor porosity creeps in the layers having the highest GMB content. Experimental results of the flexural test showed that the graded sandwiches exhibited better strength than the graded core alone. Compared to neat HDPE, the modulus of FGF-2 (H20–H40–H60) increased by 33.83%, implying better mechanical stiffness. Among all the FGFs, FGF-2 exhibited a better specific modulus. A comparative study of experimental and numerical results showed a slight deviation due to neglecting the induced porosity. © 2023 The Authors
|
|
| 9. |
- Choudhary, D., et al.
(författare)
-
Recycling of waste toner derived from exhausted printer cartridges as adsorbent for defluoridation of water
- 2024
-
Ingår i: Environmental Technology & Innovation. - : Elsevier. - 2352-1864. ; 34
-
Tidskriftsartikel (refereegranskat)abstract
- Due to the broad adoption of electronic and electrical equipment and the quick advancement of contemporary innovations in this domain, significant amounts of electronic waste have been produced. This category of waste includes the toner powder used by printers, copiers, and fax machines to print text and images. This paper describes a sustainable and environmentally friendly method of recycling waste toner powder. The chemical composition of this printer cartridge toner (PCt) powder is carbon, Fe3O4, polypropylene (polymeric resin), and SiO2 composite. Toner powder from exhausted printer cartridges was utilized as an adsorbent to remove fluoride from water. It has a fluoride adsorption capacity of 60 mg/g and a specific surface area of 20 m2/g. X-ray diffraction and electron microscopic investigations were used to investigate the chemical composition, structure, and surface morphology of the material. To analyze the collected experimental data, the Freundlich and Langmuir adsorption isotherm models were used. Time-dependent kinetic experiments were conducted to determine the mechanism of the adsorption process using pseudo-first-order kinetics, pseudo-second-order kinetics, and intraparticle diffusion kinetic models. The fluoride adsorption process was shown to be feasible and spontaneous (ΔG < 0) based on calculated thermodynamic characteristics, which included enthalpy, Gibbs free energy, entropy (ΔS > 0), and adsorption activation energy. The study also discussed its reusability as an adsorbent and examined its functioning capability in actual water. © 2024 The Authors
|
|
| 10. |
|
|
