| 1. |
- Braga, R., et al.
(författare)
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Modelling methane hydrate stability changes and gas release due to seasonal oscillations in bottom water temperatures on the Rio Grande cone, offshore southern Brazil
- 2020
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Ingår i: Marine and Petroleum Geology. - : Elsevier. - 0264-8172 .- 1873-4073. ; 112, s. 1-15
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Tidskriftsartikel (refereegranskat)abstract
- The stability of methane hydrates on continental margins worldwide is sensitive to changes in temperature and pressure conditions. It has been shown how gradual increases in bottom water temperatures due to ocean warming over post-glacial timescales can destabilize shallow oceanic hydrate deposits, causing their dissociation and gas release into the ocean. However, bottom water temperatures (BWT) may also vary significantly over much shorter timescales, including due to seasonal temperature oscillations of the ocean bottom currents. In this study, we investigate how a shallow methane hydrate deposit responds to seasonal BWT oscillations with an amplitude of up to 1.5 °C. We use the TOUGH + HYDRATE code to model changes in the methane hydrate stability zone (MHSZ) using data from the Rio Grande Cone, in the South Atlantic Ocean off the Brazilian coast. In all the cases studied, BWT oscillations resulted in significant gaseous methane fluxes into the ocean for up to 10 years, followed by a short period of small fluxes of gaseous methane into the ocean, until they stopped completely. On the other hand, aqueous methane was released into the ocean during the 100 years simulated, for all the cases studied. During the temperature oscillations, the MHSZ recedes continuously both horizontally and, in a smaller scale, vertically, until a permanent and a seasonal region in MHSZ are defined. Sensitivity tests were carried out for parameters of porosity, thermal conductivity and initial hydrate saturation, which were shown to play an important role on the volume of methane released into the ocean and on the time interval in which such release occurs. Overall, the results indicate that in a system with no gas recharge from the bottom, seasonal temperature oscillations alone cannot account for long-term gas release into the ocean.
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| 2. |
- Dano, Alexandre, et al.
(författare)
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Fluid Seepage in Relation to Seabed Deformation on the Central Nile Deep-Sea Fan, Part 1 : Evidence from Sidescan Sonar Data
- 2014
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Ingår i: Submarine Mass Movements and their Consequences. - Cham : Springer. - 9783319009728 - 9783319009711 ; , s. 129-139
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Konferensbidrag (refereegranskat)abstract
- The central Nile Deep-Sea Fan contains a broad area of seabed destabilisation in association with fluid seepage: slope-parallel sediment undulations are associated with multibeam high-backscatter patches (HBPs) related to authigenic carbonates. During the 2011 APINIL campaign, a deep-towed sidescan and profiling system (SAR) was used to acquire high-resolution data along three transects across water depths of 1,700-2,650 m. Three seabed domains are distinguished, all developed within stratified sediments overlying mass-transport deposits (MTDs). Upslope of the undulations (<1,950 m), sidescan HBPs record focused fluid seepage via seabed cracks. In the western area of undulations, sidescan HBPs are distinct from intermediate-backscatter patches (IBPs) that extend up to 850 m parallel to the undulations, mainly along their downslope flanks; some contain sub-circular HBPs up to 300 m wide, three associated with smaller (<10 m) hydroacoustic gas flares. Focused fluid seeps are inferred to have shifted over time to form elongate carbonate pavements, preferentially along the footwalls of faults beneath the undulations that provide pathways for fluid flow. In contrast, in the eastern area of undulations, sidescan imagery reveal only slope-transverse furrows formed by turbulent flows, interpreted to indicate that fossil carbonates sampled during submersible operations have been exhumed by erosion.
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| 3. |
- Ketzer, João Marcelo, et al.
(författare)
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Gas hydrate dissociation linked to contemporary ocean warming in the southern hemisphere
- 2020
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Ingår i: Nature Communications. - : Nature Publishing Group. - 2041-1723. ; 11:1, s. 1-9
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Tidskriftsartikel (refereegranskat)abstract
- Ocean warming related to climate change has been proposed to cause the dissociation of gas hydrate deposits and methane leakage on the seafloor. This process occurs in places where the edge of the gas hydrate stability zone in sediments meets the overlying warmer oceans in upper slope settings. Here we present new evidence based on the analysis of a large multi-disciplinary and multi-scale dataset from such a location in the western South Atlantic, which records massive gas release to the ocean. The results provide a unique opportunity to examine ocean-hydrate interactions over millennial and decadal scales, and the first evidence from the southern hemisphere for the effects of contemporary ocean warming on gas hydrate stability. Widespread hydrate dissociation results in a highly focused advective methane flux that is not fully accessible to anaerobic oxidation, challenging the assumption that it is mostly consumed by sulfate reduction before reaching the seafloor.
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| 4. |
- Ketzer, João Marcelo, et al.
(författare)
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Gas Hydrate Systems on the Brazilian Continental Margin
- 2022
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Ingår i: World Atlas of Submarine Gas Hydrates in Continental Margins. - Cham : Springer. - 9783030811853 - 9783030811860 ; , s. 343-352
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Bokkapitel (refereegranskat)abstract
- The existence of gas hydrate systems along Brazil’s vast continental margin has been known since the 1980s, based on observations of bottom simulating reflectors (BSRs) in two large shelf-slope depocenters: (1) the Amazon deep-sea fan in the Foz do Amazonas Basin and (2) Rio Grande Cone in Pelotas Basin. These depocenters are both undergoing gravitational collapse above deep detachment surfaces, resulting in upslope extensional and downslope compressional domains. The BSR is discontinuous across the Amazon deep-sea fan, mainly observed at water depths of 600–2800 m and at anticlines within an upper slope thrust-fold belt related to the compressional domain of the fan. Conversely, a fairly continuous BSR extends across Rio Grande Cone at water depths of 520–3500 m, within both extensional and compressional domains. Interestingly, the well-defined BSR that spans Rio Grande Cone rises to meet the seafloor at water depths of 515–520 m, forming an unusual ‘BSR outcrop’. This phenomenon has been observed previously in only a few locations worldwide. Gas hydrates have been recovered within piston cores taken from seafloor seeps in both depocenters, and analyses reveal that gas is dominated by methane of microbial origin.
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| 5. |
- Ketzer, João Marcelo, et al.
(författare)
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Gas seeps and gas hydrates in the Amazon deep-sea fan
- 2018
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Ingår i: Geo-Marine Letters. - : Springer. - 0276-0460 .- 1432-1157. ; 38:5, s. 429-438
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Tidskriftsartikel (refereegranskat)abstract
- Deep-sea fans have been proposed to act as carbon sinks, rapid deposition driving shallow methanogenesis to favor net storage within the gas hydrate stability zone (GHSZ). Here, we present new evidence of widespread gas venting from the GHSZ on the upper Amazon deep-sea fan, together with analyses of the first samples of gas hydrates recovered offshore NE Brazil. Multibeam water column and seafloor imagery over an 18,000-km2 area of the upper Amazon fan reveal 53 water column gas plumes, rising from venting features in water depths of 650–2600 m. Most gas vents (60%) are located along seafloor faults that record the ongoing gravitational collapse of the fan above deep décollements, while others (40%) are located in water depths of 650–715 m within the upper edge of the GHSZ. Gas compositions from hydrates recovered in vents at three locations on and north of the fan indicate biogenic sources (dominantly methane with 2–15% of CO2; δ13C from − 81.1 to − 77.3‰), whereas samples from vents adjacent to the fan proper include possible thermogenic contributions (methane 95%, CO2 4%, and ethane 1%; δ13C – 59.2‰). These results concur with previous findings that the upper edge of the GHSZ may be sensitive to temporal changes in water temperatures, but further point to the importance of gas escape from within areas of gas hydrate stability. Our results suggest the role of fluid migration along pathways created by faulting within rapidly deposited passive margin depocenters, which are increasingly recognized to undergo gravitational collapse above décollements. Our findings add to evidence that gas can escape from sediments to the sea in areas where gas hydrates are stable on passive margins, and suggest the need of further studies of the dynamics of deep-sea depocenters in relation to carbon cycling.
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| 6. |
- Ketzer, João Marcelo, et al.
(författare)
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Gas Seeps at the Edge of the Gas Hydrate Stability Zone on Brazil’s Continental Margin
- 2019
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Ingår i: Geosciences. - : MDPI. - 2076-3263. ; 9:5, s. 1-11
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Tidskriftsartikel (refereegranskat)abstract
- Gas hydrate provinces occur in two sedimentary basins along Brazil’s continental margin: (1) The Rio Grande Cone in the southeast, and (2) the Amazon deep-sea fan in the equatorial region. The occurrence of gas hydrates in these depocenters was first detected geophysically and has recently been proven by seafloor sampling of gas vents, detected as water column acoustic anomalies rising from seafloor depressions (pockmarks) and/or mounds, many associated with seafloor faults formed by the gravitational collapse of both depocenters. The gas vents include typical features of cold seep systems, including shallow sulphate reduction depths (<4 m), authigenic carbonate pavements, and chemosynthetic ecosystems. In both areas, gas sampled in hydrate and in sediments is dominantly formed by biogenic methane. Calculation of the methane hydrate stability zone for water temperatures in the two areas shows that gas vents occur along its feather edge (water depths between 510 and 760 m in the Rio Grande Cone and between 500 and 670 m in the Amazon deep-sea fan), but also in deeper waters within the stability zone. Gas venting along the feather edge of the stability zone could reflect gas hydrate dissociation and release to the oceans, as inferred on other continental margins, or upward fluid flow through the stability zone facilitated by tectonic structures recording the gravitational collapse of both depocenters. The potential quantity of venting gas on the Brazilian margin under different scenarios of natural or anthropogenic change requires further investigation. The studied areas provide natural laboratories where these critical processes can be analyzed and quantified.
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| 7. |
- Migeon, Sebastien, et al.
(författare)
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Post-failure Processes on the Continental Slope of the Central Nile Deep-Sea Fan : Interactions Between Fluid Seepage, Sediment Deformation and Sediment-Wave Construction
- 2014
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Ingår i: Submarine Mass Movements and their Consequences. - Cham : Springer. - 9783319009728 - 9783319009711 ; , s. 117-127
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Konferensbidrag (refereegranskat)abstract
- Voluminous mass-transport deposits (MTD) have been identified on seismic profiles across the central Nile Deep-Sea Fan (NDSF). The youngest MTDs are buried under 30-100 m of well-stratified slope deposits that, in water depths of 1,800-2,600 m, are characterized by undulating reflectors correlated with slope-parallel seabed ridges and troughs. Seabed imagery shows that, in the western part of the central NDSF, short, arcuate undulations are associated with fluid venting (carbonate pavements, gas flares), while to the east, long, linear undulations have erosional furrows on their downslope flanks and fluid seeps are less common. Sub-bottomprofiles suggest that the western undulations correspond to rotated fault-blocks above the buried MTDs, while those in the east are sediment waves generated by gravity flows. We suggest that fluids coming from dewatering of MTDs and/or from deeper layers generate overpressures along the boundary between MTDs and overlying fine-grained sediment, resulting in a slow downslope movement of the sediment cover and formation of tilted blocks separated by faults. Fluids can migrate to the seafloor, leading to the construction of carbonate pavements. Where the sediment cover stabilizes, sediment deposition by gravity flows may continue building sediment waves. These results suggest that complex processes may follow the emplacement of large MTDs, significantly impacting continental-slope evolution.
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| 8. |
- Praeg, Daniel, et al.
(författare)
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A Gas Hydrate System of Heterogeneous Character in the Nile Deep-Sea Fan
- 2022
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Ingår i: World Atlas of Submarine Gas Hydrates in Continental Margins. - Cham : Springer. - 9783030811853 - 9783030811860 ; , s. 437-447
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Bokkapitel (refereegranskat)abstract
- Large deep-sea fans are useful settings to study gas hydrate systems, the rapid burial of organic-rich sediment driving linked processes of gas generation, fluid expulsion and syn-sedimentary tectonism. The Nile deep-sea fan (100,000 km2) is a collapsing Late Cenozoic depocentre that is both a hydrocarbon province and an area of widespread seafloor fluid seepage. Evidence for gas hydrates has been reported in this area, but remains poorly documented. Available seismic and well data are used together with information on seafloor features to characterise a deep-water (1500–2700 m) gas hydrate system in the central Nile fan. The system is in part expressed as a bottom simulating reflection (BSR) discontinuously observed across a relatively small area (6000 km2), both cross-cutting the stratified fill of fault-bound slope basins, and upslope of the basins within thick unstratified mass transport deposits. West of the BSR area, log data from two wells 45 km apart indicate the presence of gas hydrates in intervals up to 75 m thick near the base of the stability zone. Gas hydrates are also likely to be present near the seafloor within hundreds of pockmark-like mounds that record gas venting through the stability zone, most observed west of the BSR area. The central Nile fan thus contains a gas hydrate system expressed as two areas of comparable size, one with a discontinuous BSR but few seafloor gas vents, another lacking a BSR but with downhole evidence of gas hydrates and abundant gas venting. This heterogenous character is suggested to reflect spatial variations in fluid expulsion from the Nile fan, which can inhibit BSR formation while favouring gas hydrate accumulation over wide areas. This possibility has implications for other large deep-sea fans, many of which have restricted BSRs but may contain more extensive gas hydrate systems.
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| 9. |
- Praeg, Daniel, et al.
(författare)
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Fluid Seepage in Relation to Seabed Deformation on the Central Nile Deep-Sea Fan, Part 2 : Evidence from Multibeam and Sidescan Imagery
- 2014
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Ingår i: Submarine Mass Movements and their Consequences. - Cham : Springer. - 9783319009728 - 9783319009711 ; , s. 141-150
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Konferensbidrag (refereegranskat)abstract
- On the central Nile deep-sea fan, stratified sediments overlying mass-transport deposits (MTDs) are deformed into slope-parallel seabed undulations associated with fluid seepage. The western part of this system, in water depths of 1,950-2,250 m, is examined using multi-frequency data from hull-mounted and deep-towed swath/profiling systems. Sub-bottom profiles show sub-vertical fluid pipes that terminate both at and below seabed, and gas signatures along fault planes bounding the undulations. Fluid seepage is recorded by high-to intermediate-backscatter patches (HBPs, IBPs) that differ in appearance on multibeam imagery (30 kHz, <= 3 m penetration) and sidescan swaths (170/190 kHz, <0.1 m penetration). Comparison of the two suggests a distinction of (a) buried carbonates (0.1-3 m), (b) broad near-seabed (<0.1 m) carbonate pavements elongate along the undulations, (c) sub-circular areas of seabed seepage up to 300 m across. Four of the latter have narrower gas flares at their edges rising 400-800 m above seabed. These results are consistent with an evolving system of narrow fluid conduits that support the growth and burial of carbonate pavements, shifting over millennial timescales along linear zones parallel to fault planes rooted in MTDs. Sediment deformation above MTDs is inferred to provide pathways for fluid escape, but migration of gas-rich fluids from depth is likely to have facilitated slope destabilisation.
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| 10. |
- Praeg, Daniel, et al.
(författare)
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Seismic evidence of gas hydrate and seafloor fluid escape on the upper Amazon deep-sea fan, Brazilian equatorial margin
- 2022
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Ingår i: Brazilian Journal of Geophysics. - : Sociedade Brasileira de Geofísica. - 2764-8044. ; 40:3
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Tidskriftsartikel (refereegranskat)abstract
- The Amazon fan contains a gas hydrate province known from a bottom-simulating reflection (BSR) that lies within an upper slope compressional belt. In this study, the extent and character of the BSR and its relation to thrust-fold structures is examined using a grid of 2D and 3D seismic data. We show the BSR to comprise a series of elongate patches up to 16 km wide that are present along 300 km of the slope in water depths of 750-2250 m and extend over a total area of 6800 km2. The elongate BSR patches show a strong spatial correspondence with the arcuate crests of thrust-fold anticlines. In profile, the BSR patches exhibit convex forms and/or locally irregular relief that rises toward the seafloor. In plan, 3D seismic horizon maps reveal columnar BSR elevations up to 1 km wide, which rise beneath seafloor mounds and depressions, up to 0.5 km wide and 30 m in relief, interpreted as small mud volcanoes and possible pockmarks. The elongate BSR patches are interpreted to record the structurally-controlled rise of warm, gas-rich fluids into the crests of thrust-folds and their leakage into the gas hydrate stability zone, and in places to seafloor, through a near-surface system of faults, hydrofractures and vents.
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