| 1. |
- Rahm, Martin, 1982, et al.
(författare)
-
Non-Bonded Radii of the Atoms Under Compression
- 2020
-
Ingår i: ChemPhysChem. - : Wiley. - 1439-7641 .- 1439-4235. ; 21:21, s. 2441-2453
-
Tidskriftsartikel (refereegranskat)abstract
- Abstract: We present quantum mechanical estimates for non-bonded, van der Waals-like, radii of 93 atoms in a pressure range from 0 to 300 gigapascal. Trends in radii are largely maintained under pressure, but atoms also change place in their relative size ordering. Multiple isobaric contractions of radii are predicted and are explained by pressure-induced changes to the electronic ground state configurations of the atoms. The presented radii are predictive of drastically different chemistry under high pressure and permit an extension of chemical thinking to different thermodynamic regimes. For example, they can aid in assignment of bonded and non-bonded contacts, for distinguishing molecular entities, and for estimating available space inside compressed materials. All data has been made available in an interactive web application.
|
|
| 2. |
- Sume, Ain, et al.
(författare)
-
Radar Detection of Moving Targets Behind Corners
- 2011
-
Ingår i: IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING. - : IEEE; 1999. - 0196-2892. ; 49:6, s. 2259-2267
-
Tidskriftsartikel (refereegranskat)abstract
- Detection of moving objects concealed behind a concrete wall corner has been demonstrated, using Doppler-based techniques with a stepped-frequency radar centered at 10 GHz, in a reduced-scale model of a street scenario. Micro-Doppler signatures have been traced in the return from a human target, both for walking and for breathing. Separate material measurements of the reflection and transmission of the concrete in the wall have showed that wall reflections are the dominating wave propagation mechanism for producing target detections, while wave components transmitted through the walls could be neglected. Weaker detections have been made of target returns via diffraction in the wall corner. A simple and fast algorithm for the detection and generation of detection tracks in down range has been developed, based on moving target indication technique.
|
|
| 3. |
- Alling, Vanja, et al.
(författare)
-
Tracing terrestrial organic matter by delta S-34 and delta C-13 signatures in a subarctic estuary
- 2008
-
Ingår i: Limnology and Oceanography. - 0024-3590 .- 1939-5590. ; 53:6, s. 2594-2602
-
Tidskriftsartikel (refereegranskat)abstract
- A key issue to understanding the transformations of terrestrial organic carbon in the ocean is to disentangle the latter from marine-produced organic matter. We applied a multiple stable isotope approach using delta S-34 and delta C-13 isotope signatures from estuarine dissolved organic matter (DOM), enabling us to constrain the contribution of terrestrial-derived DOM in an estuarine gradient of the northern Baltic Sea. The stable isotope signatures for dissolved organic sulfur (delta S-34(DOS)) have twice the range between terrestrial and marine end members compared to the stable isotope signatures for dissolved organic carbon (delta C-13(DOC)); hence, the share of terrestrial DOM in the total estuarine DOM can be calculated more precisely. DOM samples from the water column were collected using ultrafiltration on board the German RV Maria S Merian during a winter cruise, in the Bothnian Bay, Bothnian Sea, and Baltic proper. We calculated the terrestrial fraction of the estuarine DOC (DOCter) from both delta C-13(DOC) and delta S-34(DOS) signatures and applying fixed C: S ratios for riverine and marine end members to convert S isotope signatures into DOC concentrations. The delta S-34(DOS) signature of the riverine end member was +7.02 parts per thousand, and the mean signatures from Bothnian Bay, Bothnian Sea, and Baltic proper were +10.27, +12.51, and +13.67 parts per thousand, respectively, showing an increasing marine signal southwards (d34SDOS marine end member = 18.1 parts per thousand). These signatures indicate that 87%, 75%, and 67%, respectively, of the water column DOC is of terrestrial origin (DOCter) in these basins. Comparing the fractions of DOCter in each basin-that are still based on few winter values only-with the annual river input of DOC, it appears that the turnover time for DOCter in the Gulf of Bothnia is much shorter than the hydraulic turnover time, suggesting that high-latitude estuaries might be efficient sinks for DOCter.
|
|
| 4. |
- Alling, Vanja, 1978-, et al.
(författare)
-
Tracing terrestrial organic matter by delta34S and delta13C signatures in a subarctic estuary
- 2008
-
Ingår i: Limnology and Oceanography. - : Wiley. - 0024-3590 .- 1939-5590. ; 53:6, s. 2594-2602
-
Tidskriftsartikel (refereegranskat)abstract
- A key issue to understanding the transformations of terrestrial organic carbon in the ocean is to disentangle the latter from marine-produced organic matter. We applied a multiple stable isotope approach using 34S and 13C isotope signatures from estuarine dissolved organic matter (DOM), enabling us to constrain the contribution of terrestrial-derived DOM in an estuarine gradient of the northern Baltic Sea. The stable isotope signatures for dissolved organic sulfur (34SDOS) have twice the range between terrestrial and marine end members compared to the stable isotope signatures for dissolved organic carbon (13CDOC); hence, the share of terrestrial DOM in the total estuarine DOM can be calculated more precisely. DOM samples from the water column were collected using ultrafiltration on board the German RV Maria S Merian during a winter cruise, in the Bothnian Bay, Bothnian Sea, and Baltic proper. We calculated the terrestrial fraction of the estuarine DOC (DOCter) from both 13CDOC and 34SDOS signatures and applying fixed C: S ratios for riverine and marine end members to convert S isotope signatures into DOC concentrations. The 34SDOS signature of the riverine end member was +7.02‰, and the mean signatures from Bothnian Bay, Bothnian Sea, and Baltic proper were +10.27, +12.51, and +13.67‰, respectively, showing an increasing marine signal southwards (34SDOS marine end member 5 18.1‰). These signatures indicate that 87‰, 75‰, and 67‰, respectively, of the water column DOC is of terrestrial origin (DOCter) in these basins. Comparing the fractions of DOCter in each basin—that are still based on few winter values only—with the annual river input of DOC, it appears that the turnover time for DOCter in the Gulf of Bothnia is much shorter than the hydraulic turnover time, suggesting that high-latitude estuaries might be efficient sinks for DOCter.
|
|
| 5. |
|
|
| 6. |
- Boström, Cecilia, et al.
(författare)
-
Design proposal of electrical system for linear generator wave power plants
- 2009
-
Ingår i: 35TH ANNUAL CONFERENCE OF IEEE INDUSTRIAL ELECTRONICS. - : IEEE. - 9781424446483 - 9781424446506 ; , s. 4180-4185
-
Konferensbidrag (refereegranskat)abstract
- This paper describes an electrical system layout for a wave power plant connecting linear generators to the grid. The electrical power out from the wave energy converters must be converted before they can be connected to the grid. The conversion is carried out in marine substations that will be placed on the seabed.The paper presents experimental power data from a wave energy converter that has been in operation at the Lysekil research site since March 2006. Moreover, results and analyses from experiments and simulations from tests with the generator connected to a rectifier and filter are presented. A simulation is made to show the difference between having the generator connected to a linear load and a nonlinear load, which would be the case when the generator is connected to the grid.
|
|
| 7. |
- Boström, Cecilia, et al.
(författare)
-
Temperature measurements in a linear generator and marine substation for wave power
- 2010
-
Ingår i: PROCEEDINGS OF THE ASME 29TH INTERNATIONAL CONFERENCE ON OCEAN, OFFSHORE AND ARCTIC ENGINEERING 2010, VOL 3. - 9780791849118 ; , s. 545-552
-
Konferensbidrag (refereegranskat)abstract
- This paper analyzes temperature measurements acquired in offshore operation of a wave energy converter array. The three directly driven wave energy converters have linear generators and are connected to a marine substation placed on the seabed. The highly irregular individual linear generator voltages are rectified and added on a common DC-link and inverted to 50 Hz to facilitate future grid-connection. The electrical power is transmitted to shore and converted to heat in a measuring station. First results of temperature measurements on substation components and on the stator of one of the linear generators are presented from operation in linear and in non-linear damping. Results indicate that there might be some convective heat transport in the substation vessel. If high power levels are extracted from the waves, this has to be considered when placing components in the substation vessel to avoid heating from neighbouring components. The results also indicate that the temperature increase in the linear generator stator is very small. Failure due to excessive heating of the stator winding PVC cable insulation is unlikely to occur even in very energetic sea states. Should this conclusion be incorrect, the thermal conductivity between the stator and the hull of the WEC could be enhanced. Another suggested alteration would be to lower the resistive losses by reducing the linear generator current density.
|
|
| 8. |
- Boström, Cecilia, et al.
(författare)
-
Temperature measurements in a linear generator and marine substation for wave power
- 2012
-
Ingår i: Journal of Offshore Mechanics and Arctic Engineering-Transactions of The Asme. - : ASME International. - 0892-7219 .- 1528-896X. ; 134:2, s. 021901-
-
Tidskriftsartikel (refereegranskat)abstract
- This paper analyzes temperature measurements acquired in the offshore operation of a wave energy converter array. The three directly driven wave energy converters have linear generators and are connected to a marine substation placed on the seabed. The highly irregular individual linear generator voltages are rectified and added on a common dc-link and inverted to 50 Hz to facilitate future grid-connection. The electrical power is transmitted to shore and converted to heat in a measuring station. The first results of temperature measurements on substation components and on the stator of one of the linear generators are presented based on operation in linear and in nonlinear damping. The results indicate that there might be some convective heat transfer in the substation vessel. If high power levels are extracted from the waves, this has to be considered when placing components in the substation vessel in order to avoid heating from neighboring components. The results also indicate that the temperature increase in the linear generator stator is very small. Failure due to excessive heating of the stator winding polyvinyl chloride cable insulation is unlikely to occur even in very energetic sea states. Should this conclusion be incorrect, the thermal conductivity between the stator and the hull of the wave energy converter could be enhanced. Another suggested alteration is to lower the resistive losses by reducing the linear generator current density.
|
|
| 9. |
|
|
| 10. |
- Conley, Daniel, et al.
(författare)
-
Past, present and future state of the biogeochemical Si cycle in the Baltic Sea
- 2008
-
Ingår i: Journal of Marine Systems. - : Elsevier BV. - 0924-7963 .- 1879-1573. ; 73:3-4, s. 338-346
-
Tidskriftsartikel (refereegranskat)abstract
- The Baltic Sea is one of many aquatic ecosystems that show long-term declines in dissolved silicate (DSi) concentrations due to anthropogenic alteration of the biogeochemical Si cycle. Reductions in DSi in aquatic ecosystems have been coupled to hydrological regulation reducing inputs, but also with eutrophication, although the relative significance of both processes remains unknown for the observed reductions in DSi concentrations. Here we combine present and historical data on water column DSi concentrations, together with estimates of present river DSi loads to the Baltic, the load prior to damming together with estimates of the long-term accumulation of BSi in sediments. In addition, a model has been used to evaluate the past, present and future state of the biogeochemical Si cycle in the Baltic Sea. The present day DSi load to the Baltic Sea is 855 ktons y(-1). Hydrological regulation and eutrophication of inland waters can account for a reduction of 420 ktons y(-1) less riverine DSi entering the Baltic Sea today. Using published data on basin-wide accumulation rates we estimate that 1074 ktons y(-1) of biogenic silica (BSi) is accumulating in the sediments, which is 36% higher than earlier estimates from the literature (791 ktons y(-1)). The difference is largely due to the high reported sedimentation rates in the Bothnian Sea and the Bothnian Bay. Using river DSi loads and estimated BSi accumulation, our model was not able to estimate water column DSi concentrations as burial estimates exceeded DSi inputs. The model was then used to estimate the BSi burial from measured DSi concentrations and DSj load. The model estimate for the total burial of BSi in all three basins was 620 ktons y(-1), 74% less than estimated from sedimentation rates and sediment BSi concentrations. The model predicted 20% less BSi accumulation in the Baltic Proper and 10% less in the Bothnian Bay than estimated, but with significantly less BSi accumulation in the Bothnian Sea by a factor of 3. The model suggests there is an overestimation of basin-wide sedimentation rates in the Bothnian Bay and the Bothnian Sea. In the Baltic Proper, modelling shows that historical DSi concentrations were 2.6 times higher at the turn of the last century (ca. 1900) than at present. Although the DSi decrease has leveled out and at present there are only restricted areas of the Baltic Sea with limiting DSi concentrations, further declines in DSi concentrations will lead to widespread DSi limitation of diatoms with severe implications for the food web.
|
|
