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- Qiu, Minghui, et al.
(författare)
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Observation of Feshbach Resonances in the F + H2 → HF + H Reaction
- 2006
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Ingår i: Science. - : American Association for the Advancement of Science (AAAS). - 0036-8075 .- 1095-9203. ; 311:5766, s. 1440-1443
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Tidskriftsartikel (refereegranskat)abstract
- Reaction resonances, or transiently stabilized transition-state structures, have proven highly challenging to capture experimentally. Here, we used the highly sensitive H atom Rydberg tagging time-of-flight method to conduct a crossed molecular beam scattering study of the F + H2 → HF + H reaction with full quantum-state resolution. Pronounced forward-scattered HF products in the v′ = 2 vibrational state were clearly observed at a collision energy of 0.52 kcal/mol; this was attributed to both the ground and the first excited Feshbach resonances trapped in the peculiar HF(v′ = 3)-H′ vibrationally adiabatic potential, with substantial enhancement by constructive interference between the two resonances.
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