| 1. |
- Baginski, Maciej, et al.
(författare)
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Understanding and Controlling the Crystallization Process in Reconfigurable Plasmonic Superlattices
- 2021
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Ingår i: ACS Nano. - : American Chemical Society (ACS). - 1936-0851 .- 1936-086X. ; 15:3, s. 4916-4926
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Tidskriftsartikel (refereegranskat)abstract
- The crystallization of nanomaterials is a primary source of solid-state, photonic structures. Thus, a detailed understanding of this process is of paramount importance for the successful application of photonic nanomaterials in emerging optoelectronic technologies. While colloidal crystallization has been thoroughly studied, for example, with advanced in situ electron microscopy methods, the noncolloidal crystallization (freezing) of nanoparticles (NPs) remains so far unexplored. To fill this gap, in this work, we present proof-of-principle experiments decoding a crystallization of reconfigurable assemblies of NPs at a solid state. The chosen material corresponds to an excellent testing bed, as it enables both in situ and ex situ investigation using X-ray diffraction ( XRD), transmission electron microscopy (TEM), high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), atomic force microscopy (AFM), and optical spectroscopy in visible and ultraviolet range (UV-vis) techniques. In particular, ensemble measurements with small-angle XRD highlighted the dependence of the correlation length in the NPs assemblies on the number of heating/cooling cycles and the rate of cooling. Ex situ TEM imaging further supported these results by revealing a dependence of domain size and structure on the sample preparation route and by showing we can control the domain size over 2 orders of magnitude. The application of HAADF-STEM tomography, combined with in situ thermal control, provided three-dimensional single-particle level information on the positional order evolution within assemblies. This combination of real and reciprocal space provides insightful information on the anisotropic, reversibly reconfigurable assemblies of NPs. TEM measurements also highlighted the importance of interfaces in the polydomain structure of nanoparticle solids, allowing us to understand experimentally observed differences in UV-vis extinction spectra of the differently prepared crystallites. Overall, the obtained results show that the combination of in situ heating HAADF-STEM tomography with XRD and ex situ TEM techniques is a powerful approach to study nanoparticle freezing processes and to reveal the crucial impact of disorder in the solid-state aggregates of NPs on their plasmonic properties.
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| 2. |
- Elfenbein, Hillary Anger, et al.
(författare)
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What Do We Hear in the Voice? An Open-Ended Judgment Study of Emotional Speech Prosody
- 2022
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Ingår i: Personality and Social Psychology Bulletin. - : SAGE Publications. - 0146-1672 .- 1552-7433. ; 48:7, s. 1087-1104
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Tidskriftsartikel (refereegranskat)abstract
- The current study investigated what can be understood from another person's tone of voice. Participants from five English-speaking nations (Australia, India, Kenya, Singapore, and the United States) listened to vocal expressions of nine positive and nine negative affective states recorded by actors from their own nation. In response, they wrote open-ended judgments of what they believed the actor was trying to express. Responses cut across the chronological emotion process and included descriptions of situations, cognitive appraisals, feeling states, physiological arousal, expressive behaviors, emotion regulation, and attempts at social influence. Accuracy in terms of emotion categories was overall modest, whereas accuracy in terms of valence and arousal was more substantial. Coding participants' 57,380 responses yielded a taxonomy of 56 categories, which included affective states as well as person descriptors, communication behaviors, and abnormal states. Open-ended responses thus reveal a wide range of ways in which people spontaneously perceive the intent behind emotional speech prosody.
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| 3. |
- Laukka, Petri, et al.
(författare)
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Cross-cultural decoding of positive and negative non-linguistic emotion vocalizations
- 2013
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Ingår i: Frontiers in Psychology. - : Frontiers Media SA. - 1664-1078. ; 4, s. 353-
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Tidskriftsartikel (refereegranskat)abstract
- Which emotions are associated with universally recognized non-verbal signals? We address this issue by examining how reliably non-linguistic vocalizations (affect bursts) can convey emotions across cultures. Actors from India, Kenya, Singapore, and USA were instructed to produce vocalizations that would convey nine positive and nine negative emotions to listeners. The vocalizations were judged by Swedish listeners using a within-valence forced-choice procedure, where positive and negative emotions were judged in separate experiments. Results showed that listeners could recognize a wide range of positive and negative emotions with accuracy above chance. For positive emotions, we observed the highest recognition rates for relief, followed by lust, interest, serenity and positive surprise, with affection and pride receiving the lowest recognition rates. Anger, disgust, fear, sadness, and negative surprise received the highest recognition rates for negative emotions, with the lowest rates observed for guilt and shame. By way of summary, results showed that the voice can reveal both basic emotions and several positive emotions other than happiness across cultures, but self-conscious emotions such as guilt, pride, and shame seem not to be well recognized from non-linguistic vocalizations.
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| 4. |
- Laukka, Petri, et al.
(författare)
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The expression and recognition of emotions in the voice across five nations : A lens model analysis based on acoustic features
- 2016
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Ingår i: Journal of Personality and Social Psychology. - : American Psychological Association (APA). - 0022-3514 .- 1939-1315. ; 111:5, s. 686-705
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Tidskriftsartikel (refereegranskat)abstract
- This study extends previous work on emotion communication across cultures with a large-scale investigation of the physical expression cues in vocal tone. In doing so, it provides the first direct test of a key proposition of dialect theory, namely that greater accuracy of detecting emotions from one’s own cultural group—known as in-group advantage—results from a match between culturally specific schemas in emotional expression style and culturally specific schemas in emotion recognition. Study 1 used stimuli from 100 professional actors from five English-speaking nations vocally conveying 11 emotional states (anger, contempt, fear, happiness, interest, lust, neutral, pride, relief, sadness, and shame) using standard-content sentences. Detailed acoustic analyses showed many similarities across groups, and yet also systematic group differences. This provides evidence for cultural accents in expressive style at the level of acoustic cues. In Study 2, listeners evaluated these expressions in a 5 × 5 design balanced across groups. Cross-cultural accuracy was greater than expected by chance. However, there was also in-group advantage, which varied across emotions. A lens model analysis of fundamental acoustic properties examined patterns in emotional expression and perception within and across groups. Acoustic cues were used relatively similarly across groups both to produce and judge emotions, and yet there were also subtle cultural differences. Speakers appear to have a culturally nuanced schema for enacting vocal tones via acoustic cues, and perceivers have a culturally nuanced schema in judging them. Consistent with dialect theory’s prediction, in-group judgments showed a greater match between these schemas used for emotional expression and perception.
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