| 1. |
- Bianco, Federica B., et al.
(författare)
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Optimization of the Observing Cadence for the Rubin Observatory Legacy Survey of Space and Time : A Pioneering Process of Community-focused Experimental Design
- 2022
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Ingår i: Astrophysical Journal Supplement Series. - : American Astronomical Society. - 0067-0049 .- 1538-4365. ; 258:1
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Tidskriftsartikel (refereegranskat)abstract
- Vera C. Rubin Observatory is a ground-based astronomical facility under construction, a joint project of the National Science Foundation and the U.S. Department of Energy, designed to conduct a multipurpose 10 yr optical survey of the Southern Hemisphere sky: the Legacy Survey of Space and Time. Significant flexibility in survey strategy remains within the constraints imposed by the core science goals of probing dark energy and dark matter, cataloging the solar system, exploring the transient optical sky, and mapping the Milky Way. The survey's massive data throughput will be transformational for many other astrophysics domains and Rubin's data access policy sets the stage for a huge community of potential users. To ensure that the survey science potential is maximized while serving as broad a community as possible, Rubin Observatory has involved the scientific community at large in the process of setting and refining the details of the observing strategy. The motivation, history, and decision-making process of this strategy optimization are detailed in this paper, giving context to the science-driven proposals and recommendations for the survey strategy included in this Focus Issue.
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| 2. |
- Calamida, Annalisa, et al.
(författare)
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The Not so Simple Stellar System ω Cen. II. Evidence in Support of a Merging Scenario
- 2020
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Ingår i: Astrophysical Journal. - : American Astronomical Society. - 0004-637X .- 1538-4357. ; 891:2
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Tidskriftsartikel (refereegranskat)abstract
- We present multiband photometry covering ∼5° × 5° across ω Cen collected with the Dark Energy Camera on the 4 m Blanco telescope, combined with Hubble Space Telescope and Wide Field Imager data for the central regions. The unprecedented photometric accuracy and field coverage allows us to confirm the different spatial distribution of blue and red main-sequence stars, and of red giant branch (RGB) stars with different metallicities. The ratio of the number of blue to red main-sequence stars shows that the blue main-sequence stellar subpopulation has a more extended spatial distribution compared to the red main-sequence one, with the frequency of blue main-sequence stars increasing at a distance of ∼20′ from ω Cen's center. Similarly, the more metal-rich RGB stars show a more extended spatial distribution compared to the more metal-poor ones in the outskirts of the cluster. Moreover, the centers of the distributions of metal-rich and metal-poor RGB stars are shifted in different directions with respect to the geometrical center of ω Cen. We constructed stellar density profiles for the blue and red main-sequence stars; they show that the blue main-sequence stellar subpopulation has a more extended spatial distribution compared to the red main-sequence one in the outskirts of ω Cen, confirming the results based on the number ratio. We also computed the ellipticity profile of ω Cen, which has a maximum value of 0.16 at a distance of ∼8′ from the center, and a minimum of 0.05 at ∼30′; the average ellipticity is ∼0.10. The circumstantial evidence presented in this work suggests a merging scenario for the formation of the peculiar stellar system ω Cen.
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| 3. |
- Chatterjee, Debashis, et al.
(författare)
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Assessment of arsenic exposure from groundwater and rice in Bengal Delta Region, West Bengal, India
- 2010
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Ingår i: Water Research. - : Elsevier BV. - 0043-1354 .- 1879-2448. ; 44:19, s. 5803-5812
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Tidskriftsartikel (refereegranskat)abstract
- Arsenic (As) induced identifiable health outcomes are now spreading across Indian subcontinent with continuous discovery of high As concentrations in groundwater. This study deals with groundwater hydrochemistry vis-a-vis As exposure assessment among rural population in Chakdaha block, West Bengal, India. The water quality survey reveals that 96% of the tubewells exceed WHO guideline value (10 mu g/L of As). The groundwaters are generally anoxic (-283 to -22 mV) with circum-neutral pH (6.3 to 7.8). The hydrochemistry is dominated by HCO3- (208 to 440 mg/L), Ca2+ (79 to 178 mg/L) and Mg2+ (17 to 45 mg/L) ions along with high concentrations of As-T (As total, below detection limit to 0.29 mg/L), Fe-T (Fe total, 1.2 to 16 mg/L), and Fe(II) (0.74 to 16 mg/L). The result demonstrates that Fe(II)-Fe(III) cycling is the dominant process for the release of As from aquifer sediments to groundwater (and vice versa), which is mainly controlled by the local biogeochemical conditions. The exposure scenario reveals that the consumption of groundwater and rice are the major pathways of As accumulation in human body, which is explained by the dietary habit of the surveyed population. Finally, regular awareness campaign is essential as part of the management and prevention of health outcomes. (c) 2010 Elsevier Ltd. All rights reserved.
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| 4. |
- Chowdhury, Suman, et al.
(författare)
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A real-space study of random extended defects in solids : Application to disordered Stone–Wales defects in graphene
- 2014
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Ingår i: Physica. E, Low-Dimensional systems and nanostructures. - : Elsevier BV. - 1386-9477 .- 1873-1759. ; 61:0, s. 191-197
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Tidskriftsartikel (refereegranskat)abstract
- Abstract We propose here a first-principles, parameter free, real space method for the study of disordered extended defects in solids. We shall illustrate the power of the technique with an application to graphene sheets with randomly placed Stone–Wales defects and shall examine the signature of such random defects on the density of states as a function of their concentration. The technique is general enough to be applied to a whole class of systems with lattice translational symmetry broken not only locally but by extended defects and defect clusters. The real space approach will allow us to distinguish signatures of specific defects and defect clusters.
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| 5. |
- Mukherjee, Abhijit, et al.
(författare)
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Occurrence, predictors and hazards of elevated groundwater arsenic across India through field observations and regional-scale AI-based modeling
- 2021
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Ingår i: Science of the Total Environment. - : Elsevier BV. - 0048-9697 .- 1879-1026. ; 759
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Tidskriftsartikel (refereegranskat)abstract
- Existence of wide spread elevated concentrations of groundwater arsenic (As) across South Asia, including India, has endangered a huge groundwater-based drinking water dependent population. Here, using high-spatial resolution As field-observations (similar to 3 million groundwater sources) across India, we have delineated the regional-scale occurrence of elevated groundwater As (>= 10 mu g/L), along with the possible geologic-geomorphologic-hydrologic and human-sourced predictors that influence the spatial distribution of the contaminant. Using statistical and machine learning method, we also modeled the groundwater As concentrations probability at 1 Km resolution, along with probabilistic delineation of high As-hazard zones across India. The observed occurrence of groundwater As was found to be most strongly influenced by geology-tectonics, groundwater-fed irrigated area (%) and elevation. Pervasive As contamination is observed in major parts of the Himalayan mega-river Indus-Ganges-Brahmaputra basins, however it also occurs in several more-localized pockets, mostly related to ancient tectonic zones, igneous provinces, aquifers in modern delta and chalcophile mineralized regions. The model results suggest As-hazard potential in yet-undetected areas. Our model performed well in predicting groundwater arsenic, with accuracy: 82% and 84%; area under the curve (AUC): 0.89 and 0.88 for test data and validation datasets. An estimated similar to 90 million people across India are found to be exposed to high groundwater As from field-observed data, with the five states with highest hazard are West Bengal (28 million), Bihar (21 million), Uttar Pradesh (15 million), Assam(8.6 million) and Punjab (6 million). However it can be much more if the modeled hazard is considered (>250 million). Thus, our study provides a detailed, quantitative assessment of high groundwater As across India, with delineation of possible intrinsic influences and exogenous forcings. The predictive model is helpful in predicting As-hazard zones in the areas with limited measurements.
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| 6. |
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| 7. |
- Saha, Sayan, et al.
(författare)
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Exploring the water oxidation catalytic activity of a Mn-Based magnetic metal-organic framework : the role of proton conductivity and oxygen evolution reaction overpotential
- 2024
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Ingår i: Inorganic Chemistry. - : American Chemical Society (ACS). - 0020-1669 .- 1520-510X.
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Tidskriftsartikel (refereegranskat)abstract
- The present work evaluates the water oxidation catalytic activity of a Mn-based metal-organic framework (MOF), which we envisioned to reduce the oxygen evolution reaction (OER) overpotential because of its high electrical conductivity, facilitated by solvent-encapsulated structural features. The presence of Mn centers induces interesting magnetic features in the MOF, which exhibits impressive cryogenic magnetic refrigeration with a ΔSM value of 29.94 J kg-1 K-1 for a field change of ΔH = 5T at 2.3 K. To the best of our knowledge, the ΔSM value of the current system ranked the highest position among the published examples. The crystal structure aligns perfectly with the thematic expectations and features as many as ten metal-coordinated water molecules, forming an extensive web of a hydrogen-bonded network while facing toward the porous channel filled with another set of much-anticipated entrapped lattice water molecules. Such structural features are expected to manifest high proton conductivity, and detailed investigation indeed yields the best value for the system at 1.57 × 10-4 S/cm at 95% humidity and 85 °C. In order to evaluate the thematic notion of a one-to-one relationship between OER and improved electrical conductivity, extensive electrocatalytic water splitting (WS) investigations were carried out. The final results show highly encouraging WS ability of the Mn-MOF, showing the electrocatalytic surface area value of the active species as 0.0686 F/g with a turnover frequency value of 0.043 [(mol. O2) (mol. Mn-MOF)-1 s-1]. Another fascinating aspect of the current communication is the excellent synergy observed between the experimental WS outcomes and the corresponding theoretical data calculated using density functional theory (DFT). Consequently, a plausible mechanism of the overall OER and the role of the Mn-MOF as a water oxidation catalyst, along with the importance of water molecules, have also been derived from the theoretical calculations using DFT.
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| 8. |
- Singh, Purnima, et al.
(författare)
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High-spin spectroscopy of I-122
- 2012
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Ingår i: Physical Review C (Nuclear Physics). - 0556-2813. ; 85:5
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Tidskriftsartikel (refereegranskat)abstract
- High-spin states in I-122 have been investigated using the Cd-116(B-11,5n)I-122 reaction at a beam energy of 65 MeV and gamma-ray coincidence events were recorded with the INGA spectrometer. The level scheme of I-122 has been extended up to spin I = 30. Experimental features, such as band-crossing frequencies, aligned angular momenta, signature splitting, and B(M1)/B(E2) ratios have been used for configuration assignments to low-energy band structures. Maximally aligned states involving all eight particles outside the Sn-114 core and states with one particle antialigned have been identified. Cranked Nilsson-Strutinsky calculations have been used to interpret high-spin structures.
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| 9. |
- Sinha, T. P., et al.
(författare)
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Electronic structure and optical properties of ordered compounds potassium tantalate and potassium niobate and their disordered alloys
- 2012
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Ingår i: Physica. B, Condensed matter. - : Elsevier BV. - 0921-4526 .- 1873-2135. ; 407:24, s. 4615-4621
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Tidskriftsartikel (refereegranskat)abstract
- The electronic energy band structure, site and angular momentum decomposed density of states (DOS) of cubic perovskite oxides KNbO 3 and KTaO 3 have been obtained from a first principles density functional based full potential linearized augmented plane wave (FLAPW) method within a generalized gradient approximation (GGA). The total DOS in valence region is compared with the experimental photo-emission spectra (PES). The calculated DOS is in good agreement with the experimental energy spectra and the features in the spectra are interpreted by comparison with the projected density of states (PDOS). The valence band PES is mainly composed of Nb-4d/Ta-5d and O 2p states in KNbO 3 and KTaO 3, respectively. Using the PDOS and the band structure we have analyzed the inter-band contribution to the optical properties of these materials. The real and imaginary parts of the dielectric function have been calculated and compared with experimental data. They are found to be in a reasonable agreement. The role of band structure on the optical properties have been discussed.
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