| 1. |
- Parsmo, Rasmus, et al.
(författare)
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BRAVE ECO – Benchmark for Reduction of Anchoring Vessels’ Emissions – Enabling Change of Operation
- 2021
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- This feasibility study aims to evaluate the possibilities to reduce air emissions from ships anchored in port areas and, then especially the Port of Gothenburg. For this purpose, the study uses two main approaches. Firstly, it analyses the reasons and legal/business aspects for anchoring. Secondly, this study develops a reproducible calculation model for anchored vessels' CO2 emissions. Regulation of anchoring sites are not entirely clear since international regulation partly applies, also it is not clear who is responsible for the anchoring sites. This implies that the port´s scope of action is limited mainly to the ships that are calling the port. However, also emission from other ships at in the port area has been evaluated in this study to get a broader perspective. This pre-study provides both qualitative and quantitative findings and it is produced using mixed methods, including workshops with relevant port stakeholders. It also involves different scientific disciplines and several authors from the Port of Gothenburg Authority, IVL Swedish Environmental Research Institute, Maritime Studies at Chalmers University of Technology and the School of Business, Economics and Law at the University of Gothenburg. Furthermore, in connection to this study, one bachelor's thesis and two master's theses have been carried out. The results show that it is mainly tanker ships that are anchoring in Gothenburg and that their main reasons for anchoring are related to awaiting Laycan or waiting for an available berth. The companies involved in the study generally combine time charter and voyage charter contracts to access vessel capacity. The inputs from the workshops, the interviews conducted with stakeholders and the international literature are “rather” consistent: combining just in time arrival with slow steaming has a great potential for making a business case and to reduce fuel consumption and thereby emissions. However, there are many barriers which needs to be addressed, such as: lack of trust, improving information sharing (actors now communicate via phone or email), loss of income (due to demurrage), attitudes in the industry, the “first come, first serve” concept, risk of missing estimated time of arrival and port infrastructure. Even if there are many barriers, several actors in the port already have experience of combining just in time arrival and slow steaming. In this study, we develop a reproducible emission calculation model that calculates CO2eq emissions. The emissions are partly calculated by using the ships’ positions (AIS-data) from 2019, to extract the time spent at anchor. The emission model calculates the anchored vessels' total CO2eq emissions, but the model also calculates the theoretical potential for avoiding emission by using the time at anchor to slow steam. The results show that all tanker ships that anchored outside the port in 2019, could theoretically have reduced their emissions with about 30 ktonnes CO2eq, if they would have been notified of delays 24 hours before arrival and then reduced their speed to 10 knots. The results also show that using time to slow steam have a much greater potential to reduce emissions than if the ships would only reduce the time at anchor (by using fewer ships to perform the same transport work). This is especially true for the initial speed reductions (10-14 knots). This study also evaluates the emission calculation methods and assesses the uncertainties, by comparing different sources and underlying assumptions with real world data. The study argues that it is problematic to just use default values proposed in the global emission inventory issued by the International Maritime Organization (IMO). Using default values for estimating emission makes it harder to estimate the real effect of a new policy, regulation, or incentive in the port. However, a better emission inventory requires that on-board visits are made or that data is obtained digitally. The largest calculation uncertainties now are for boiler fuel consumption and bunker ships fuel consumption at the anchorage areas.
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| 2. |
- Anderson, Maria, 1983, et al.
(författare)
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Characterization of particles from a marine engine operating at low loads
- 2015
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Ingår i: Atmospheric Environment. - : Elsevier BV. - 1873-2844 .- 1352-2310. ; 101, s. 65-71
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Tidskriftsartikel (refereegranskat)abstract
- Particle emissions from a marine diesel engine operating at low loads with four different fuels were characterized with respect to particle number (PN) and particle mass (PM), size distribution, volatility and chemical composition. The four different fuels used were Swedish Environmental class 1 (MK1) and class 3 diesel (MK3), heavy fuel oil (HFO, 0.12 wt% S) and marine diesel oil (MDO, 0.52 wt% S). The measurements were performed for a marine diesel engine in a test-bed engine lab and the particle emissions were measured with an Engine Exhaust Particle Sizer and a Dust Monitor, giving the number concentrations in the size range of 5.6-560 nm and 300 nm to 20 gm, respectively. To quantify the amount of solid particles a thermodenuder was used. Additionally, filter samples were taken for gravimetric, black carbon (BC) and elemental analysis. The particle emissions showed a bimodal size distribution by number and the number concentrations were dominated by nanoparticles (diameter (Dp) 50 nm generally were solid primary particles. Combustion of HFO resulted in the highest PN and PM concentrations. Emission factors (EFs) for PM and PN for both the total particle emissions and the fraction of primary, solid particles are presented for different fuels and loads. EFs for nitrogen oxides (NOx), BC and some elements (Ca, Fe, V, Ni, Zn) are presented as well. This study contributes to understanding particle emissions from potential future fuels as well as emissions in ports and coastal areas where lower engine loads are common.
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| 3. |
- Anderson, Maria, 1983, et al.
(författare)
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Particle- and Gaseous Emissions from an LNG Powered Ship
- 2015
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Ingår i: Environmental Science & Technology. - : American Chemical Society (ACS). - 0013-936X .- 1520-5851. ; 49:20, s. 12568-12575
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Tidskriftsartikel (refereegranskat)abstract
- Measurements of particle number and mass concentrations and number size distribution of particles from a ship running on liquefied natural gas (LNG) were made on-board a ship with dual-fuel engines installed. Today there is a large interest in LNG as a marine fuel, as a means to comply with sulfur and NOX regulations. Particles were studied in a wide size range together with measurements of other exhaust gases under different engine loads and different mixtures of LNG and marine gas oil. Results from these measurements show that emissions of particles, NOX, and CO2 are considerably lower for LNG compared to present marine fuel oils. Emitted particles were mainly of volatile character and mainly had diameters below 50 nm. Number size distribution for LNG showed a distinct peak at 9-10 nm and a part of a peak at diameter 6 nm and below. Emissions of total hydrocarbons and carbon monoxide are higher for LNG compared to present marine fuel oils, which points to the importance of considering the methane slip from combustion of LNG.
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| 4. |
- Beecken, Jörg, 1982, et al.
(författare)
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Airborne emission measurements of SO2, NOx and particles from individual ships using a sniffer technique
- 2014
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Ingår i: Atmospheric Measurement Techniques. - : Copernicus GmbH. - 1867-1381 .- 1867-8548. ; 7:7, s. 1957-1968
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Tidskriftsartikel (refereegranskat)abstract
- A dedicated system for airborne ship emission measurements of SO2, NOx and particles has been developed and used from several small aircraft. The system has been adapted for fast response measurements at 1 Hz, and the use of several of the instruments is unique. The uncertainty of the given data is about 20% for SO2 and 24% for NOx emission factors. The mean values with one standard deviation for multiple measurements of 158 ships measured from the air on the Baltic and North Sea during 2011 and 2012 show emission factors of 18.8+/-6.5 g kg(fuel)(-1), 66.6+/-23.4 g kg(fuel)(-1) and 1.8+/-1.3 1016 particles kg(fuel)(-1) for SO2, NOx and particle number, respectively. The particle size distributions were measured for particle diameters between 15 and 560 nm. The mean sizes of the particles are between 45 and 54 nm dependent on the distance to the source, and the number size distribution is monomodal. Concerning the sulfur fuel content, around 85% of the monitored ships comply with the International Maritime Organization (IMO) limits. The reduction of the sulfur emission control area (SECA) limit from 1.5 to 1% in 2010 appears to have contributed to reduction of sulfur emissions that were measured in earlier studies from 2007 to 2009. The presented method can be implemented for regular ship compliance monitoring.
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| 5. |
- Beecken, Jörg, 1982, et al.
(författare)
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Emission factors of SO2, NOx and particles from ships in Neva Bay from ground-based and helicopter-borne measurements and AIS-based modeling
- 2015
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Ingår i: Atmospheric Chemistry and Physics. - : Copernicus GmbH. - 1680-7316 .- 1680-7324. ; 15:9, s. 5229-5241
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Tidskriftsartikel (refereegranskat)abstract
- Emission factors of SO2, NOx and size-distributed particle numbers were measured for approximately 300 different ships in the Gulf of Finland and Neva Bay area during two campaigns in August/September 2011 and June/July 2012. The measurements were carried out from a harbor vessel and from an Mi-8 helicopter downwind of passing ships. Other measurements were carried out from shore sites near the island of Kronstadt and along the Neva River in the urban area of Saint Petersburg. Most ships were running at reduced speed (10 kn), i.e., not at their optimal load. Vessels for domestic and international shipping were monitored. It was seen that the distribution of the SO2 emission factors is bi-modal, with averages of 4.6 and 18.2 gSO(2) kg(fuel)(-1) for the lower and the higher mode, respectively. The emission factors show compliance with the 1% fuel sulfur content Sulfur Emission Control Areas (SECA) limit for 90% of the vessels in 2011 and 97% in 2012. The distribution of the NOx emission factor is mono-modal, with an average of 58 gNO(x) kg(fuel)(-1). The corresponding emission related to the generated power yields an average of 12.1 gNO(x) kWh(-1). The distribution of the emission factors for particulate number shows that nearly 90% of all particles in the 5.6 nm to 10 mu m size range were below 70 nm in diameter. The distribution of the corresponding emission factors for the mass indicates two separated main modes, one for particles between 30 and 300 nm and the other for above 2 mu m. The average particle emission factors were found to be in the range from 0.7 to 2.7 x 10(16) particles kg(fuel)(-1) and 0.2 to 3.4 gPM kg(fuel)(-1), respectively. The NOx and particulate emissions are comparable with other studies. The measured emission factors were compared, for individual ships, to modeled ones using the Ship Traffic Emission Assessment Model (STEAM) of the Finnish Meteorological Institute. A reasonably good agreement for gaseous sulfur and nitrogen emissions can be seen for ships in international traffic, but significant deviations are found for inland vessels. Regarding particulate mass, the values of the modeled data are about 2-3 times higher than the measured results, which probably reflects the assumptions made in the modeled fuel sulfur content. The sulfur contents in the fuel retrieved from the measurements were lower than the previously used assumptions by the City of Saint Petersburg when carrying out atmospheric modeling, and using these measurements it was possible to better assess the impact of shipping on air quality.
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| 6. |
- Bilde, M., et al.
(författare)
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Saturation Vapor Pressures and Transition Enthalpies of Low-Volatility Organic Molecules of Atmospheric Relevance: From Dicarboxylic Acids to Complex Mixtures
- 2015
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Ingår i: Chemical Reviews. - : American Chemical Society (ACS). - 0009-2665 .- 1520-6890. ; 115:10, s. 4115-4156
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Forskningsöversikt (refereegranskat)abstract
- There are a number of techniques that can be used that differ in terms of whether they fundamentally probe the equilibrium and the temperature range over which they can be applied. The series of homologous, straight-chain dicarboxylic acids have received much attention over the past decade given their atmospheric relevance, commercial availability, and low saturation vapor pressures, thus making them ideal test compounds. Uncertainties in the solid-state saturation vapor pressures obtained from individual methodologies are typically on the order of 50-100%, but the differences between saturation vapor pressures obtained with different methods are approximately 1-4 orders of magnitude, with the spread tending to increase as the saturation vapor pressure decreases. Some of the dicarboxylic acids can exist with multiple solid-state structures that have distinct saturation vapor pressures. Furthermore, the samples on which measurements are performed may actually exist as amorphous subcooled liquids rather than solid crystalline compounds, again with consequences for the measured saturation vapor pressures, since the subcooled liquid phase will have a higher saturation vapor pressure than the crystalline solid phase. Compounds with equilibrium vapor pressures in this range will exhibit the greatest sensitivities in terms of their gas to particle partitioning to uncertainties in their saturation vapor pressures, with consequent impacts on the ability of explicit and semiexplicit chemical models to simulate secondary organic aerosol formation.
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| 7. |
- Donahue, N. M., et al.
(författare)
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Aging of biogenic secondary organic aerosol via gas-phase OH radical reactions
- 2012
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Ingår i: Proceedings of the National Academy of Sciences of the United States of America. - : Proceedings of the National Academy of Sciences. - 0027-8424 .- 1091-6490. ; 109:34, s. 13503-13508
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Tidskriftsartikel (refereegranskat)abstract
- The Multiple Chamber Aerosol Chemical Aging Study (MUCHACHAS) tested the hypothesis that hydroxyl radical (OH) aging significantly increases the concentration of first-generation biogenic secondary organic aerosol (SOA). OH is the dominant atmospheric oxidant, and MUCHACHAS employed environmental chambers of very different designs, using multiple OH sources to explore a range of chemical conditions and potential sources of systematic error. We isolated the effect of OH aging, confirming our hypothesis while observing corresponding changes in SOA properties. The mass increases are consistent with an existing gap between global SOA sources and those predicted in models, and can be described by a mechanism suitable for implementation in those models.
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| 8. |
- Flagiello, Domenico, et al.
(författare)
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A Novel Approach to Reduce the Environmental Footprint of Maritime Shipping
- 2021
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Ingår i: Journal of Marine Science and Application. - : Springer Science and Business Media LLC. - 1993-5048 .- 1671-9433. ; 20:2, s. 229-247
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Tidskriftsartikel (refereegranskat)abstract
- Maritime shipping is a strategic sector with a strong international vocation and management. The need to define regulations valid for many different countries without generating disparities of treatment slowed down the formulation of environmental regulations, especially for atmospheric emissions. In particular, regulations pertaining to the reduction of sulphur compounds allowed two distinct approaches: the use of low-sulphur fuels or exhaust gas cleaning systems, the so-called Scrubbers. The actual implementation of these solutions presents specific concerns either related to the toxicity of atmospheric by-products and to the fuel cost or to the generation of polluting washwaters that may need treatment before discharge. In this paper we analyzed the potential environmental benefit deriving from the use of a distillate fuel, not compliant with current IMO Sulphur Regulations, together with a Scrubber. The pilot-scale experimental results indicated that a limited amount of water and/or scrubber volume is needed to reduce sulphur emissions below regulations on maritime shipping, especially with the addition of NaOH reaching a water-saving between 25%-33% compared to the use of pure seawater. Experiments indicated that scrubber washwater PAHs emissions are within the available water quality standards indicated by EU and USA guidelines. A bottom-up analysis on heavy metals concentration shed light on the prominent role of metal-parts corrosion on the washwater emissions. Taking into account for corrosion phenomena, the actual heavy metals concentration in the washwater deriving from scrubbing was normally below the water quality standards.
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| 9. |
- Flagiello, Domenico, et al.
(författare)
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Effect of seawater alkalinity on the performances of a marine diesel engine desulphurization scrubber
- 2021
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Ingår i: Chemical Engineering Transactions. - 2283-9216. ; 86, s. 505-510
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Tidskriftsartikel (refereegranskat)abstract
- Since the last fifteen years, Flue Gas Desulphurization (FGD) plants based on seawater scrubbing found an interesting application in the maritime transportation, as an answer to the stringent regulations imposed by International Maritime Organization (IMO) on sulphur emissions. This work reports the experimental results on desulphurization in a pilot seawater scrubber (DN 400) from a marine Diesel engine (80 kW) operated under different loads (10, 25 and 50%). The pilot scrubber was fed with a gas velocity 0.15 m/s and a liquid to gas mass ratio 1-3 kg/kg. The scrubbing liquid was available at different alkalinity and salinity levels representing the ion speciation of marine water in different geographic areas. The experiments evaluate the SO2 removal efficiency of the scrubber as a function of seawater alkalinity and pH. Finally, the paper reports a correlation to assess the seawater flow rate required to comply with the current IMO restrictions. This correlation allows tuning the seawater flow rate during the ship navigation based on the registered marine alkalinities and to the operating conditions of the engine. The model can be integrated in the scrubber control system to identify optimal operating conditions and reduce pumping costs, helping to reduce the EEDI and the SEEMP ships energy indexes.
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| 10. |
- Fridell, Erik, 1963, et al.
(författare)
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Measurements of abatement of particles and exhaust gases in a marine gas scrubber
- 2016
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Ingår i: Proceedings of the Institution of Mechanical Engineers Part M: Journal of Engineering for the Maritime Environment. - : SAGE Publications. - 2041-3084 .- 1475-0902. ; 230:1, s. 154-162
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Tidskriftsartikel (refereegranskat)abstract
- Measurements of exhaust gases from a marine engine equipped with an open-loop wet scrubber using seawater for sulphur dioxide (SO2) abatement are reported. The scrubber reduces the SO2 emissions effectively to levels corresponding to
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