| 1. |
- Braungardt, C. B., et al.
(författare)
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Analysis of dissolved metal fractions in coastal waters: An inter-comparison of five voltammetric in situ profiling (VIP) systems
- 2009
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Ingår i: Marine Chemistry. - : Elsevier BV. - 0304-4203. ; 114:1-2, s. 47-55
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Tidskriftsartikel (refereegranskat)abstract
- This paper presents the results of an inter-comparison exercise undertaken to test the reliability and performance of a voltammetric in situ profiling system (VIP system) and carried out by partners based in Italy, Sweden, Switzerland and the UK. The VIP system was designed to allow in situ simultaneous monitoring of the dynamic fractions (i.e. the maximum potentially bioavailable fractions) of Cu(II). Pb(II) and Cd(II) in natural waters at a frequency of 2-3 analyses h(-1). The four participating groups used the VIP systems under laboratory conditions to determine dissolved concenterations of Cu, Pb and Cd in river, estuarine and coastal water reference materials (SLRS-3/4, SLEW-2/3 and CASS3/4, respectively). The accuracy of the VIP method was comparable to that of established methodologies, including inductively coupled plasma mass spectrometry and voltammetric methods using mercury-electrodes. The VIP systems were also applied to determine the dynamic fractions of the target analytes in freshly collected samples ex situ, as well as in situ in contrasting European marine waters. There was good agreement between the concentrations of the dynamic metal fractions determined in laboratory analyses, and observed during the Simultaneous deployment of up to five VIP instruments for periods of several hours in coastal waters. The simultaneous in situ deployment of two VIP instruments in an estuary showed a consistent analytical performance over several days of continuous operation. The results of this inter-comparison exercise show that the VIP system is a reliable submersible probe for accurate, sensitive and high resolution in situ monitoring of dissolved metal fractions in the picomolar (Cd, Pb) and nanomolar (Cu) concentration ranges. (C) 2009 Elsevier B.V. All rights reserved.
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| 2. |
- Illuminati, S., et al.
(författare)
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In-situ trace metal (Cd, Pb, Cu) speciation along the Po River plume (Northern Adriatic Sea) using submersible systems
- 2019
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Ingår i: Marine Chemistry. - : Elsevier BV. - 0304-4203. ; 212, s. 47-63
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Tidskriftsartikel (refereegranskat)abstract
- Information on the distribution and speciation of trace metals is of critical importance for our ability to interpret the links between the bioavailability and uptake of an element, and its biogeochemical cycle in coastal environments. Within the framework of the European Project "In-situ automated Monitoring of Trace metal speciation in Estuaries and Coastal zones in relation with the biogeochemical processes (IMTEC)", the chemical speciation of Cd, Pb and Cu was carried out along the Po River plume in the period 27 October - 2 November 2002. During the cruise, five Voltammetric In-situ Profiling systems and one Multi Physical Chemical Profiler, as well as conventional voltammetric instruments, were successfully applied in order to evaluate the distribution of Cd, Pb and Cu between different fractions (free ion, dynamic, colloidal, dissolved and particulate fractions) and to assess the evolution of these fractions during estuarine mixing and in the water column. Dynamic concentrations were 0.05-0.2 nmol L-1 Cd, 0.02-0.2 nmol L-1 Pb, and 0.15-4.0 nmol L-1 Cu. Cd was mainly present as dynamic fraction (40-100% of the dissolved Cd). High proportions of Pb (similar to 70%) and Cu (similar to 80%) were present as colloids probably of biogenic origin. Principal components analysis reveals a strong influence of the Po River discharge on the spatial and vertical distributions of metal species. Almost all the metal fractions globally decreased following the salinity gradient. Metal concentrations are far below (at least one order of magnitude lower) the Environmental Quality Standard established by the Italian law. However, the Cu dynamic fraction showed concentrations likely to be toxic to sensitive phytoplankton community and to have negative effects on larva development of coastal macroinvertebrate species (toxicity data extracted from literature).
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| 3. |
- Scarponi, M., et al.
(författare)
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New gravity data and 3-D density model constraints on the Ivrea Geophysical Body (Western Alps)
- 2020
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Ingår i: Geophysical Journal International. - : Oxford University Press (OUP). - 0956-540X .- 1365-246X. ; 222:3, s. 1977-1991
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Tidskriftsartikel (refereegranskat)abstract
- We provide a high-resolution image of the Ivrea Geophysical Body (IGB) in the Western Alps with new gravity data and 3-D density modelling, integrated with surface geological observations and laboratory analyses of rock properties. The IGB is a sliver of Adriatic lower lithosphere that is located at shallow depths along the inner arc of the Western Alps, and associated with dense rocks that are exposed in the Ivrea-Verbano Zone (IVZ). The IGB is known for its high seismic velocity anomaly at shallow crustal depths and a pronounced positive gravity anomaly. Here, we investigate the IGB at a finer spatial scale, merging geophysical and geological observations. We compile existing gravity data and we add 207 new relative gravity measurements, approaching an optimal spatial coverage of 1 data point per 4–9 km2 across the IVZ. A compilation of tectonic maps and rock laboratory analyses together with a mineral properties database is used to produce a novel surface rock-density map of the IVZ. The density map is incorporated into the gravity anomaly computation routine, from which we defined the Niggli gravity anomaly. This accounts for Bouguer Plate and terrain correction, both considering the in situ surface rock densities, deviating from the 2670 kg m–3 value commonly used in such computations. We then develop a 3-D single-interface crustal density model, which represents the density distribution of the IGB, including the above Niggli-correction. We retrieve an optimal fit to the observations by using a 400 kg m–3 density contrast across the model interface, which reaches as shallow as 1 km depth below sea level. The model sensitivity tests suggest that the ∼300–500 kg m–3 density contrast range is still plausible, and consequently locates the shallowest parts of the interface at 0 km and at 2 km depth below sea level, for the lowest and the highest density contrast, respectively. The former model requires a sharp density discontinuity, the latter may feature a vertical transition of densities on the order of few kilometres. Compared with previous studies, the model geometry reaches shallower depths and suggests that the width of the anomaly is larger, ∼20 km in west–east direction and steeply E–SE dipping. Regarding the possible rock types composing the IGB, both regional geology and standard background crustal structure considerations are taken into account. These exclude both felsic rocks and high-pressure metamorphic rocks as suitable candidates, and point towards ultramafic or mantle peridotite type rocks composing the bulk of the IGB.
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