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1.
  • Karsli, O., et al. (författare)
  • Melting of the juvenile lower crust in a far-field response to roll-back of the southern Neotethyan oceanic lithosphere: the Oligocene adakitic dacites, NE Turkey
  • 2020
  • Ingår i: Lithos. - : Elsevier BV. - 0024-4937. ; 370-371:October
  • Tidskriftsartikel (refereegranskat)abstract
    • Late Cenozoic tectono-thermal events and associated magmatism in the Sakarya Zone (SZ) are still contested. Although documented in the western part of the SZ, thus far, no magmatic activity has been identified in the eastern part of the Oligocene SZ. Here, we report a newly identified Oligocene magmatism to interpret the genesis with tectonic setting and gain new insight into the geological evolution of the eastern SZ. We present extensive geochemical, bulk-rock Sr-Nd and zircon Hf isotope, and zircon U-Pb chronological analyses for the Tepebasi dacites in the Artvin area, NE Turkey. Zircon UPb dating analyses revealed a dacite formation age of similar to 29.8 +/- 0.3 Ma. Geochemically, with a K2O/Na2O ratio of 0.5 to 0.6, they are composed of rocks of a medium-K calc-alkaline adakitic affinity. The samples are further characterized by low Y (6-7 ppm), and high Sr (362-588 ppm) and Sr/Y ratios (58-98), with low Mg# (41-45) values, demonstrating a close affinity with the crustal source of adakitic rocks. They have slightly radiogenic isotope concentrations (Sr-87/Sr-86(t) = 0.70460-0.70544, epsilon(Nd)(t) = +1.7 to +2.0), and single-stage Nd model ages of T-DM1 = 0.61-0.63 Ga, as well as uniform and positive epsilon(Hf) (t) of 8.2-10.5, with young Hf depleted mantle ages (T-DM1 = 0.31-0.41 Ga). These isotopic features, in combination with the geochemical signature, preclude a mantle origin. Instead, they most likely originated from a juvenile mafic lower crustal material by low degree partial melting (<%5) rather than through partial fusion of a subducting slab or thickened lower crust. Trace element modeling reveals that the mafic juvenile lower crust is composed of <10% garnet-bearing amphibolite. Furthermore, trace element compositions imply that adakitic melts formed in an extensional setting without delamination of a thick mafic lower continental crust. We conclude that the Oligocene adakitic magmatism originated in an intracontinental setting, which was subjected to far-field extensional forces induced by roll-back of south Neotethyan oceanic lithosphere just before its detachment in the collision zone. We believe that hot asthenospheric upwelling due to the far-field extension induced by the roll-back of the southern branch of the Neotethyan oceanic lithosphere triggered adakitic magmatism. The heat induced by the upwelling of the asthenosphere likely led to the heat-fluxed melting of juvenile mafic crustal material in such an extensional tectonic setting during the Oligocene epoch in the eastern SZ. (C) 2020 Elsevier B.V. All rights reserved.
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2.
  • Karsli, O., et al. (författare)
  • Silurian to Early Devonian arc magmatism in the western Sakarya Zone (NW Turkey), with inference to the closure of the Rheic Ocean
  • 2020
  • Ingår i: Lithos. - : Elsevier BV. - 0024-4937. ; 370-371:October
  • Tidskriftsartikel (refereegranskat)abstract
    • The Rheic Ocean is the most significant Paleozoic ocean that detached peri-Gondwana terranes from the northern Gondwana margin throughout the closure of the Iapetus Ocean. The suture of the Rheic Ocean spreads from Mexico to the Middle East, and the timing of its final closure is well-documented by the rocks formed in the Variscan-Alleghanian-Ouachita orogeny which led to the formation of the supercontinent Pangaea. However, as robust paleomagnetic and quantitative data are mostly lacking, the onset and evolution of the subduction of the Rheic Ocean are highly speculative, and they require further confirmation. Recently, the well-preserved metagranitoids along the western Sakarya Zone (SZ) in Anatolia have been identified, and they provide new data that improve our knowledge on the evolution of the Early Paleozoic Rheic Ocean along the northern Gondwana. Here, we present new geochronological, in situ zircon Hf isotope, and whole-rock geochemical analyses of these metagranitoids from the western SZ to enhance our understanding of the subduction processes of the Rheic Ocean. IA-ICP-MS zircon U-Pb dating demonstrated that the Boziiyuk and Borcak metagranitoids from the western SZ were emplaced during the Silurian to Early Devonian (431 +/- 2.7 to 403 +/- 3.5 Ma). The both granitoids have medium- to high-K. calc-alkaline magmatic character, and exhibit peraluminous to slightly metaluminous geochemical signature. They show a typical arc pattern in terms of trace elements and have a uniform, moderate negative epsilon(Hf) (t) of -3.2 to -9.7, with Mesoproterozoic Hf depleted mantle model ages (T-DM1 = 12 to 1.4 Ga). The geochemical and isotopic characteristics are not consistent with those of depleted mantle melts and melts derived from the crustal rocks in an intracontinental environment. Instead, the parental magma is likely generated from the partial melting of a homogeneous and enriched mantle wedge source. We propose that the Silurian to Early Devonian arc-related magmatism is associated with a northward subduction episode of the Rheic Oceanic lithosphere beneath the peri-Gondwana terranes. Hence, we consider that the opening of Paleotethys Ocean formed in a back-arc basin of subduction in Andean style to the north rather than a continental rift to the south in response to south-directed and short-lived supra-subduction zone (SSZ)-type subduction during the Silurian to Early Devonian. (C) 2020 Elsevier B.V. All rights reserved.
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3.
  • Karsli, O., et al. (författare)
  • Tracking the timing of Neotethyan oceanic slab break-off: Geochronology and geochemistry of the quartz diorite porphyries, NE Turkey
  • 2020
  • Ingår i: Journal of Asian Earth Sciences. - : Elsevier BV. - 1367-9120. ; 200
  • Tidskriftsartikel (refereegranskat)abstract
    • The initiation of the break-off of the northern branch of the Neotethyan oceanic lithosphere is an important but poorly understood event in the geology of the Sakarya Zone (SZ) in northeastern Turkey. Although it is wellknown that Latest Cretaceous intrusives (-70 Ma) and early Eocene adakitic magmatic rocks are present in the eastern SZ, the outcrops of the early Eocene non-adakitic rocks are very limited, and their tectono-magmatic evolution has not been studied. We describe a small outcrop of non-adakitic quartz diorite porphyry in the Kov area of the Gumushane region in northeastern Turkey. The genesis of these porphyries is significant in evaluating the syn-to post-collision-related magmatism. The LA-ICP-MS zircon U-Pb dating revealed that the Kov quartz diorite porphyries (KQDP) formed at ca. 50 Ma, coeval with adakitic rocks, and-20 Myr later than the slab rollback-related intrusive rocks. The KQDPs are calc-alkaline in composition and enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs) and depleted in high field strength elements (HFSEs; e.g., Nb, Ta, Ti), with significant negative anomalies of Nb, Ta, and Ti but positive anomalies of Th, U, and Pb. Isotopic compositions of the samples show limited range of variation and slight enrichment of 87Sr/86Sr(t) (0.70489 to 0.70555), epsilon Nd(t) (-1.4 to -1.2) with TDM of 1.11 to 1.61 Ga. Pb isotopic ratios of the samples point to an enriched mantle source. They were likely crystallized from the melt that originated from an EM2-type spinel-facies subcontinental lithospheric mantle (SCLM), followed by the fractionation with insignificant crustal assimilation. The SCLM was metasomatically enriched, and the metasomatic agent was likely H2O-rich fluids rather than sediments released from subducting oceanic crust during the Late Cretaceous closure of the Neotethyan oceanic lithosphere. In conjunction with the geological background and previous data, we propose that the generation of the KQDPs resulted from a slab break-off event that caused ascending or infiltration of hot asthenosphere, triggering mantle melting. Such sporadic occurrences of the KQDPs, with coeval adakitic rocks in the SZ, are likely associated with the onset of extensional tectonics due to the earlier stage of slab break-off along the region during the early Eocene period.
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4.
  • Sengün, Firat, et al. (författare)
  • In situ Rb-Sr dating of K-bearing minerals from the orogenic Akçaabat gold deposit in the Menderes Massif, Western Anatolia, Turkey
  • 2019
  • Ingår i: Journal of Asian Earth Sciences. - : Elsevier BV. - 1367-9120. ; 185
  • Tidskriftsartikel (refereegranskat)abstract
    • The Akçaabat gold deposit is mainly composed of massive arsenopyrite veins in strongly foliated augen gneisses of the Çine Sub-massif in western Turkey. K-bearing minerals from orogenic gold veins were dated by the in situ Rb-Sr method in order to determine the formation age of the Akçaabat gold deposit. Textural relationships between the vein minerals suggest that arsenopyrite, K-feldspar, quartz, and muscovite formed in one paragenetic stage. Native gold, native bismuth, scorodite, and galena were introduced in a later paragenetic stage. The isochron derived from K-feldspar and muscovite occurring in the veins yielded 31.3 ± 4.7 Ma. In situ Rb-Sr dating of the same assemblage (K-feldspar and muscovite) in the host rock gave an isochron age of 40.8 ± 3.8 Ma, 10 Ma older than the vein ages, and corresponding to peak metamorphism of the regional main Menderes metamorphism during the Alpine-Himalayan orogenic event. Biotite from the host rock gave an isochron age of 28.1 ± 2.2 Ma and probably reflects the cooling age. Homogenization temperatures from fluid inclusions in quartz show that quartz formed at 280–390 ℃ but has a dominant mode in the 350–360 ℃ temperature interval. The age of vein formation was successfully distinguished from the age of the Alpine-Himalayan orogenic event associated with main Menderes metamorphism. This study demonstrates that in situ Rb-Sr isotopic study can be applied to resolve absolute dating of orogenic deposits in metamorphic complexes. © 2019 Elsevier Ltd
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5.
  • Şengün, Firat, et al. (författare)
  • Rutile geochemistry and thermometry of eclogites and associated garnet-mica schists in the Biga Peninsula, NW Turkey
  • 2017
  • Ingår i: Chemie der Erde - Geochemistry. - : Elsevier BV. - 0009-2819. ; 77, s. 503-515
  • Tidskriftsartikel (refereegranskat)abstract
    • © 2017 Elsevier GmbH In northwest Turkey, high-pressure metamorphic rocks occur as exotic blocks within the Çetmi mélange located on the south of the Biga Peninsula. Rutile chemistry and rutile thermometry obtained from the eclogite and associated garnet-mica schist in the Çetmi mélange indicate significant trace element behaviour of subducted oceanic crust and source-rock lithology of detrital rutiles. Cr and Nb contents in detrital rutile from garnet-mica schist vary from 355 to 1026 μg/g and 323 and 3319 μg/g, respectively. According to the Cr-Nb discrimination diagram, the results show that 85% of the detrital rutiles derived from metapelitic and 15% from metamafic rocks. Temperatures calculated for detrital rutiles and rutiles in eclogite range from 540 °C to 624 °C with an average of 586 °C and 611 °C to 659 °C with an average of 630 °C at P = 2.3 GPa, respectively. The calculated formation temperatures suggest that detrital rutiles are derived from amphibolite- and eclogite-facies metamorphic rocks. Amphibolite-facies rocks of the Kazdağ Massif could be the primary source rocks for the rutiles in the garnet-mica schist from the Çetmi mélange. Nb/Ta ratios of metapelitic and metamafic rutiles fall between 7–24 and 11–25, respectively. Nb/Ta characteristics in detrital rutiles may reflect a change in source-rock lithology. However, Nb/Ta ratios of rutiles in eclogite vary from 9 to 22. The rutile grains from eclogites are dominated by subchondritic Nb/Ta ratios. It can be noted that subchondritic Nb/Ta may record rutile growth from local sinks of aqueous fluids from metamorphic dehydration.
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6.
  • Sengün, Firat, et al. (författare)
  • The geochemistry, origin and tectonic setting of the Tozlu metaophiolite in the Kazdağ Massif (Biga Peninsula, NW Anatolia)
  • 2023
  • Ingår i: Geologica Carpathica. - 1335-0552. ; 74:4, s. 281-296
  • Tidskriftsartikel (refereegranskat)abstract
    • The Tozlu metaophiolite is composed predominantly of metagabbro, banded amphibolite, metadunite, and serpentinite, which are exposed in the Kazdag Massif located in the northwestern part of Turkey. The geochemistry (major, trace, and rare earth elements) and petrography of the Tozlu metaophiolite in the Kazdag Massif provided significant knowledge about protolith, petrogenesis, source characteristics and tectonic setting in northwest Turkey. Trace element geochemistry, Ti/Y (29.95-296.92 ppm) and Nb/Y (0.01-0.17 ppm) ratios suggest that metaophiolitic rocks were derived from a tholeiitic magma and igneous protolith of basaltic composition. The immobile trace element tectono-magmatic discrimination diagrams define a mid-ocean ridge basalt (MORB) to volcanic arc (IAT) affinity for the Tozlu metaophiolite. The metaophiolitic rocks demonstrate flat rare earth element (REE) patterns and enrichment of large ion lithophile elements (LILEs; i.e., Rb, Ba, Th), as well as depletion of high field strength elements (HFSEs; i.e., Nb, Th, Ti, Hf). N-MORB characteristics of the Tozlu metaophiolite on a multi-element diagram suggest that the protolith of metaophiolitic rocks generated in a subduction-related setting. The tholeiitic metaophiolitic rocks resulted from the metamorphism of an island arc-type basaltic protolith and display subduction zone components according to the Th/Yb and Ta/Yb ratios. The Tozlu metaophiolite with MORB/IAT affinity witness for supra-subduction zone originated in island arc/back-arc settings.
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7.
  • Sengun, Firat, et al. (författare)
  • Trace element composition of rutile and Zr-in-rutile thermometry in meta-ophiolitic rocks from the Kazdag Massif, NW Turkey
  • 2016
  • Ingår i: Mineralogy and Petrology. - 0930-0708. ; 110, s. 547-560
  • Tidskriftsartikel (refereegranskat)abstract
    • In northwest Turkey, ophiolitic meta-gabbros are exposed on the Kazdağ Massif located in the southern part of the Biga Peninsula. Trace element composition of rutile and Zr-in-rutile temperatures were determined for meta-gabbros from the Kazdağ Massif. The Zr content of all rutiles range from 176 to 428 ppm and rutile grains usually have a homogeneous Zr distribution. The rutile grains from studied samples in the Kazdağ Massif are dominated by subchondritic Nb/Ta (11–19) and Zr/Hf ratios (20–33). Nb/Ta and Zr/Hf show positive correlation, which is probably produced by silicate fractionation. The Nb/Ta and Zr/Hf ratios increase with a decrease in Ta and Hf contents. The core of rutile grains are generally characterized by low Nb/Ta ratios of 17–18 whereas the rims exhibit relatively high Nb/Ta ratios of 19–23. Trace element analyses in rutile suggest that these rutile grains were grown from metamorphic fluids. The P-T conditions of meta-gabbros were estimated by both Fe–Mg exchange and Zr-in-rutile thermometers, as well as by the Grt-Hb-Plg-Q geothermobarometer. The temperature range of 639 to 662 °C calculated at 9 kbar using the Zr-in-rutile thermometer is comparable with temperature estimates of the Fe-Mg exchange thermometer, which records amphibolite-facies metamorphism of intermediate P-T conditions. The P-T conditions of meta-ophiolitic rocks suggest that they occur as a different separate higher-pressure tectonic slice in the Kazdağ metamorphic sequence. Amphibolite-facies metamorphism resulted from northward subduction of the İzmir-Ankara branch of the Neo-Tethyan Ocean under the Sakarya Zone. Metamorphism was followed by internal imbrication of the Kazdağ metamorphic sequence resulting from southerly directed compression during the collision.
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