| 1. |
- Kargl, Florian, 1978, et al.
(författare)
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The dynamics of water in hydrated white bread by quasielastic neutron scattering
- 2007
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Ingår i: Journal of Physics Condensed Matter. - : IOP Publishing. - 0953-8984 .- 1361-648X. ; 19:41
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Konferensbidrag (refereegranskat)abstract
- The dynamics of water in fresh and in rehydrated white bread is studied using quasielastic neutron scattering (QENS). A diffusion constant for water in fresh bread, without temperature gradients and with the use of a non-destructive technique, is presented here for the first time. The self-diffusion constant for fresh bread is estimated to be D(s) = 3.8 x 10(-10) m(2) s(-1) and the result agrees well with previous findings for similar systems. It is also suggested that water exhibits a faster dynamics than previously reported in the literature using equilibration of a hydration-level gradient monitored by vibrational spectroscopy. The temperature dependence of the dynamics of low hydration bread is also investigated for T = 280-350 K. The average relaxation time at constant momentum transfer (Q) shows an Arrhenius behavior in the temperature range investigated.
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| 2. |
- Sjöström, Johan, 1978, et al.
(författare)
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Dielectric secondary relaxation of water in aqueous binary glass-formers
- 2010
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Ingår i: Physical Chemistry Chemical Physics. - : Royal Society of Chemistry (RSC). - 1463-9084 .- 1463-9076. ; 12:35, s. 10452-10456
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Tidskriftsartikel (refereegranskat)abstract
- Glassy aqueous binary mixtures generally exhibit a water induced dielectric relaxation. The characteristic time-scale of this relaxation follows an Arrhenius temperature dependence with a nearly universal activation energy. We here demonstrate for a series of model aqueous mixtures that the relaxation time also follows a remarkably general exponential dependence on the weight fraction of water. By comparison to literature data we show that this behaviour is shared by a wide range of molecular systems. Neither the detailed nature of the water molecules' glassy environment nor the details of the route of formation of the glassy state has a significant effect on the observed behaviour.
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| 3. |
- Sjöström, Johan, 1978, et al.
(författare)
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Effects of Water Contamination on the Supercooled Dynamics of a Hydrogen-Bonded Model Glass Former
- 2011
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Ingår i: Journal of Physical Chemistry B. - : American Chemical Society (ACS). - 1520-5207 .- 1520-6106. ; 115:8, s. 1842-1847
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Tidskriftsartikel (refereegranskat)abstract
- Broad-band dielectric spectroscopy is a commonly used tool in the study of glass-forming liquids. The high sensitivity of the technique together with the wide range of probed time scales makes it a powerful method for investigating the relaxation spectra of liquids. One particularly important class of glass-forming liquids that is often studied using this technique consists of liquids dominated by hydrogen (H) bond interactions. When investigating such liquids, particular caution has to be taken during sample preparation due to their often highly hygroscopic nature. Water can easily be absorbed from the atmosphere, and dielectric spectroscopy is a very sensitive probe of such contamination due to the large dipole moment of water. Our knowledge concerning the effects of small quantities of water on the dielectric properties of these commonly investigated liquids is limited. We here demonstrate the effects due to the presence of small amounts of water on the dielectric response of a typical H-bonded model glass former, tripropylene glycol. We show how the relaxation processes present in the pure liquid are affected by addition of water, and we find that a characteristic water induced relaxation response is observed for water contents as low as 0.15 wt %. We stress the importance of careful purification of hygroscopic liquids before experiments and quantify what the effects are if such procedures are not undertaken.
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| 4. |
- Sjöström, Johan, 1978-, et al.
(författare)
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En ny modell för gräsbrandsfara i Sverige
- 2021
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Rapport (övrigt vetenskapligt/konstnärligt)abstract
- Risken för antändning och snabb spridning av vegetationsbränder i skogsmark och i gräsmarkerskiljer sig markant. Gräsbränder sprider sig i dött fjolårsgräs, tidigt på våren, innan årets färskagräs hunnit växa till och dessa bränder kan spridas snabbt efter bara några timmars torrt väder.Risken klingar snabbt av med inväxten av färskt gräs för att i stort sett upphöra till sommaren.Skogsbränder har inte samma säsongsberoende av bränslet utan styrs mer av vädret. Därför skerde typiskt under sommaren och kräver oftast flera dagars torrt väder. Dessa skillnader gör attolika riskbedömningssystem måste användas för dessa två karakteristiska typer avvegetationsbränder.Här presenteras en ny modell för gräsbrandsfara som använder potentiell spridningshastighet iobetat, oklippt gräs som indikator på risk. Algoritmen tar väderhistoriken (snötäcke, relativluftfuktighet, vindhastighet, temperatur och solinstrålning) samt progressionen av årsgräsetsinväxt i beaktning. Modellen bygger på en modell för beräkning av fuktkvot i gräs utvecklad iNordamerika samt en modell för hur fuktkvoten och vindhastigheten inverkar påspridningshastigheten. Effekten av årsgräsets inväxt under svenska förhållanden beräknasgenom 25 års insats- och väder-data i tio regioner och en anpassning till tidigare utfördatestbränningar från snösmältning till gräsbrandssäsongens slut. Modellen kan uppdateras varjetimme, i linje med det uppdaterade brandrisksystemet i Sverige.Förslag till hur indelning i risknivåer ska utformas med avseende på riskindikatorn presenterasoch modellen sätts i bruk till våren 2021.
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| 5. |
- Sjöström, Johan, 1978, et al.
(författare)
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Hydrogen Bond Induced Nonmonotonic Composition Behavior of the Glass Transition in Aqueous Binary Mixtures
- 2011
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Ingår i: Journal of Physical Chemistry B. - : American Chemical Society (ACS). - 1520-5207 .- 1520-6106. ; 115:33, s. 10013-10017
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Tidskriftsartikel (refereegranskat)abstract
- The glass transition temperature, T(g), of a binary mixture commonly varies monotonically between the T(g)s of its two components. However, mixtures of strongly associating liquids can instead exhibit a nonmonotonic T(g) variation. The origins of such nonideal mixing behavior have often been correlated with composition dependent structural variations. For binary mixtures between a hydrogen- (H-) bonded liquid and water, however, such behavior is generally not well understood. The ubiquity and importance of aqueous mixtures both in nature and in man-made applications stresses the needed for a better understanding. We here demonstrate nonmonotonic T(g) variations in binary mixtures of n-propylene glycol monomethyl ethers (nPGMEs) and water, where the composition dependent T(g) show maxima within an intermediate composition range. We show that these T(g) maxima correspond to crossovers in the composition dependence of the step amplitude in the isobaric heat capacity at T(g). We further demonstrate that the observed effects are caused by H-bond interactions involving the nPGME hydroxyl group. We can account for our obervations using a simple model based on two effects due to the added water: (i) an H-bond induced formation of effective relaxing entities and (ii) a plasticizing effect at high water contents.
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| 6. |
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| 7. |
- Bainsla, Lakhan, 1985, et al.
(författare)
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Large out-of-plane spin-orbit torque in topological Weyl semimetal TaIrTe 4
- 2024
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Ingår i: Nature Communications. - 2041-1723 .- 2041-1723. ; 15:1, s. 4649-
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Tidskriftsartikel (refereegranskat)abstract
- The unique electronic properties of topological quantum materials, such as protected surface states and exotic quasiparticles, can provide an out-of-plane spin-polarized current needed for external field-free magnetization switching of magnets with perpendicular magnetic anisotropy. Conventional spin-orbit torque (SOT) materials provide only an in-plane spin-polarized current, and recently explored materials with lower crystal symmetries provide very low out-of-plane spin-polarized current components, which are not suitable for energy-efficient SOT applications. Here, we demonstrate a large out-of-plane damping-like SOT at room temperature using the topological Weyl semimetal candidate TaIrTe4 with a lower crystal symmetry. We performed spin-torque ferromagnetic resonance (STFMR) and second harmonic Hall measurements on devices based on TaIrTe4/Ni80Fe20 heterostructures and observed a large out-of-plane damping-like SOT efficiency. The out-of-plane spin Hall conductivity is estimated to be (4.05 ± 0.23)×104 (ℏ ⁄ 2e) (Ωm)-1, which is an order of magnitude higher than the reported values in other materials.
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| 8. |
- De Marchi, Tommaso, et al.
(författare)
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Proteogenomics decodes the evolution of human ipsilateral breast cancer
- 2023
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Ingår i: Communications Biology. - : Springer Science and Business Media LLC. - 2399-3642. ; 6:1
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Tidskriftsartikel (refereegranskat)abstract
- Ipsilateral breast tumor recurrence (IBTR) is a clinically important event, where an isolated in-breast recurrence is a potentially curable event but associated with an increased risk of distant metastasis and breast cancer death. It remains unclear if IBTRs are associated with molecular changes that can be explored as a resource for precision medicine strategies. Here, we employed proteogenomics to analyze a cohort of 27 primary breast cancers and their matched IBTRs to define proteogenomic determinants of molecular tumor evolution. Our analyses revealed a relationship between hormonal receptors status and proliferation levels resulting in the gain of somatic mutations and copy number. This in turn re-programmed the transcriptome and proteome towards a highly replicating and genomically unstable IBTRs, possibly enhanced by APOBEC3B. In order to investigate the origins of IBTRs, a second analysis that included primaries with no recurrence pinpointed proliferation and immune infiltration as predictive of IBTR. In conclusion, our study shows that breast tumors evolve into different IBTRs depending on hormonal status and proliferation and that immune cell infiltration and Ki-67 are significantly elevated in primary tumors that develop IBTR. These results can serve as a starting point to explore markers to predict IBTR formation and stratify patients for adjuvant therapy.
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| 9. |
- Elamin, Khalid, 1977, et al.
(författare)
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Calorimetric and relaxation properties of xylitol-water mixtures
- 2012
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Ingår i: Journal of Chemical Physics. - : AIP Publishing. - 1089-7690 .- 0021-9606. ; 136:10
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Tidskriftsartikel (refereegranskat)abstract
- We present the first broadband dielectric spectroscopy (BDS) and differential scanning calorimetry study of supercooled xylitol-water mixtures in the whole concentration range and in wide frequency (10(-2)-10(6) Hz) and temperature (120-365 K) ranges. The calorimetric glass transition, T-g, decreases from 247 K for pure xylitol to about 181 K at a water concentration of approximately 37 wt. %. At water concentrations in the range 29-35 wt. % a plentiful calorimetric behaviour is observed. In addition to the glass transition, almost simultaneous crystallization and melting events occurring around 230-240 K. At higher water concentrations ice is formed during cooling and the glass transition temperature increases to a steady value of about 200 K for all higher water concentrations. This Tg corresponds to an unfrozen xylitol-water solution containing 20 wt. % water. In addition to the true glass transition we also observed a glass transition-like feature at 220 K for all the ice containing samples. However, this feature ismore likely due to ice dissolution [A. Inaba and O. Andersson, Thermochim. Acta, 461, 44 (2007)]. In the case of the BDS measurements the presence of water clearly has an effect on both the cooperative a-relaxation and the secondary beta-relaxation. The a-relaxation shows a non-Arrhenius temperature dependence and becomes faster with increasing concentration of water. The fragility of the solutions, determined by the temperature dependence of the a-relaxation close to the dynamic glass transition, decreases with increasing water content up to about 26 wt. % water, where ice starts to form. This decrease in fragility with increasing water content is most likely caused by the increasing density of hydrogen bonds, forming a network-like structure in the deeply supercooled regime. The intensity of the secondary beta-relaxation of xylitol decreases noticeably already at a water content of 2 wt. %, and at a water content above 5 wt. % it has been replaced by a considerably stronger water (w) relaxation at about the same frequency. However, the similarities in time scale and activation energy between the w-relaxation and the beta-relaxation of xylitol at water contents below 13 wt. % suggest that the w-relaxation is governed, in some way, by the beta-relaxation of xylitol, since clusters of water molecules are rare at these water concentrations. At higher water concentrations the intensity and relaxation rate of the w-relaxation increase rapidly with increasing water content (up to the concentration where ice starts to form), most likely due to a rapid increase of small water clusters where an increasing number of water molecules interacting with other water molecules.
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| 10. |
- Kozłowski, Marcin, et al.
(författare)
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Structural considerations on timber-glass composites at fire scenarios
- 2018
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Ingår i: Challenging Glass 6. - : TU Delft Open. - 9789463660440 ; , s. 229-240
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Konferensbidrag (refereegranskat)abstract
- This paper focuses on a recently developed concept, in which glass is combined with timber to provide post-breakage strength and ductility. This combination allows for good post-breakage performance and overall robustness of timber-glass composite beams and wall elements, which has been reported in several publications. The application of timber-glass elements in practice, however, raises important issues related to structural fire performance. The paper elaborates on this issue and provides general information about the behavior of glass, timber and adhesives at elevated temperatures and under fire conditions. Furthermore, it presents ideas and strategies developed for potential application of timber-glass composites in practical situations. The paper presents also initial results from an on-going research project on fire performance of timber-glass composites Copyright © with the authors. All rights reserved.
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