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Sökning: WFRF:(Solorza Feria O.)

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1.
  • Suarez Alcantara, Karina, et al. (författare)
  • SEM and XAS characterization at beginning of life of Pd-based cathode electrocatalysts in PEM fuel cells
  • 2014
  • Ingår i: International Journal of Hydrogen Energy. - : Elsevier BV. - 1879-3487 .- 0360-3199. ; 39:10, s. 5358-5370
  • Tidskriftsartikel (refereegranskat)abstract
    • The fuel cell performance of membrane electrode assemblies with a Pt anode and Pd, PdCu or Pd5Cu4Pt cathodes has been tested during 116 h (beginning of life). The incorporation of Cu to Pd increases the fuel cell performance. Incorporation of Pt leads to further improvement. SEM micrographs of the as-prepared and the fuel cell-tested assemblies show the effects of the 116 h of continuous operation. Nafion membranes were characterized by small angle X-ray scattering. The results show a reduction of the size of the lamellar domains in the perfluorinated matrix after fuel cell testing, but no correlation with the cathode electrocatalyst material. The cathode electrocatalysts were characterized by ex-situ synchrotron radiation X-ray diffraction and X-ray absorption spectroscopy at the Pd L-3, Cu K and Pt L-3 edges. Re-organization of Pd5Cu4Pt electrocatalyst after fuel cell testing was observed. The Cu in the electrocatalyst can be described as a nano-mixture of metallic Cu, alloyed Cu and CuO. The CuO acts as a promoter of the ORR. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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2.
  • Suarez Alcantara, Karina, et al. (författare)
  • Synchrotron-based structural and spectroscopic studies of ball milled RuSeMo and RuSnMo particles as oxygen reduction electrocatalyst for PEM fuel cells
  • 2014
  • Ingår i: International Journal of Hydrogen Energy. - : Elsevier BV. - 1879-3487 .- 0360-3199. ; 39:29, s. 16715-16721
  • Tidskriftsartikel (refereegranskat)abstract
    • Particles of RuSeMo and RuSnMo have been produced by ball milling; they present catalytic activity towards the oxygen reduction reaction (ORR) in acid media. A Tafel slope close to 120 mV/dec was found for both materials. Their morphology was first characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). SEM and TEM images reveal particles in the sub-micrometer range. The structure of the materials was further probed with synchrotron radiation powder X-ray diffraction (SR-PXD) and X-ray absorption spectroscopy (XAS). SR-PXD reveals the existence of metallic Ru as the main phase and the formation of phases such as RuSe2 in RuSeMo and Ru3Sn7 in RuSnMo. Mo was found to form solid solution into the RuSe2 phase in ball milled RuSeMo. Finally, The Ru L-3-edge and Mo L-3-edge XAS fingerprints were correlated with the catalytic activity towards ORR. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
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