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- Pyo, Sang Hyun, et al.
(författare)
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A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis
- 2020
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Ingår i: Green Chemistry. - : Royal Society of Chemistry (RSC). - 1463-9262 .- 1463-9270. ; 22:14, s. 4450-4455
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Tidskriftsartikel (refereegranskat)abstract
- A green route for the production of 6-carbon polymer building blocks 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone from 1,6-hexanediol, a hydrogenation product of biobased 5-hydroxymethylfurfural is reported. Gluconobacter oxydans oxidized 1,6-hexanediol completely to adipic acid, and selectively at pH 6-7 to 6-hydroxyhexanoic acid, which was converted to ϵ-caprolactone by catalytic cyclization. This journal is
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