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Sökning: WFRF:(Stiernet Pierre)

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1.
  • Fan, Zhiwen, et al. (författare)
  • Porous Ionic Network/CNT Composite Separator as a Polysulfide Snaring Shield for High Performance Lithium–Sulfur Battery
  • 2023
  • Ingår i: Macromolecular rapid communications. - 1022-1336 .- 1521-3927. ; 44:24
  • Tidskriftsartikel (refereegranskat)abstract
    • Lithium–sulfur (Li–S) battery features a high theoretical energy density, but the shuttle of soluble polysulfides between the two electrodes often results in a rapid capacity decay. Herein, a straightforward electrostatic adsorption strategy based on a cross-linked polyimidazolium separator as a snaring shield of polysulfides is reported, which suppresses the undesirable migration of polysulfides to the anode. The porous ionic network (PIN)-modified carbon nanotubes (CNTs) are successfully prepared and coated onto a commercial porous polypropylene membrane in a vacuum-filtration step. The favorable affinity of the imidazolium ring toward polysulfide via the polar interaction and the electrostatic effect of ions mitigates the undesirable shuttle of polysulfides in the electrolyte, improving the Li─S battery in terms of rate performance and cycling life. Compared to the reference PIN-free CNT-coated separator, the PIN/CNT-coated one has an increased initial capacity of 1.3 folds (up to 1394.8 mAh g−1 for PIN/CNT/PP-3) at 0.1 C. 
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2.
  • Shu, Chenhua, et al. (författare)
  • Desulfurization of diesel via joint adsorption and extraction using a porous liquid derived from ZIF-8 and a phosphonium-type ionic liquid
  • 2023
  • Ingår i: Reaction Chemistry & Engineering. - 2058-9883. ; :12, s. 3124-3132
  • Tidskriftsartikel (refereegranskat)abstract
    • A type-III porous liquid based on zeolitic imidazolate framework-8 (ZIF-8) and an ionic liquid trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)imide ([THTDP][BTI]) was synthesized and used for the desulfurization of model diesel. The desulfurization effect by ZIF-8/[THTDP][BTI] combined both the adsorptive desulfurization by ZIF-8 and the extraction desulfurization by [THTDP][BTI]. The removal of the three chosen aromatic organic sulfides by the ZIF-8/[THTDP][BTI] porous liquid followed the order of dibenzothiophene (73.1%) > benzothiophene (70.0%) > thiophene (61.5%). It was further found that deep desulfurization could be realized by ZIF-8/[THTDP][BTI] through triple desulfurization cycles and ZIF-8/[THTDP][BTI] can be regenerated readily. The desulfurization mechanism was explored further in detail by conformation search and density functional theory calculations. Calculations supported that the large molecular volume of [THTDP][BTI] excluded itself from the cavities of ZIF-8, making the pores of ZIF-8 in the porous liquid unoccupied and accessible by other guest species, here the studied organic sulfides. These calculations indicate that the van der Waals interactions were the main interactions between ZIF-8/[THTDP][BTI] and specifically benzothiophene. This work supports that the porous liquid ZIF-8/[THTDP][BTI] could potentially be used for desulfurization of diesel in industry.
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  • Resultat 1-2 av 2
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tidskriftsartikel (2)
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refereegranskat (2)
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Yuan, Jiayin, 1979- (2)
Stiernet, Pierre (2)
Tang, Juntao (1)
Pan, Chunyue (1)
Yu, Guipeng (1)
Zhao, Min (1)
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Wang, Yan (1)
Han, Kai (1)
Cheng, Hua (1)
Fan, Zhiwen (1)
Tao, Jian (1)
Peng, Shuting (1)
Yang, Yumin (1)
Gu, Shuai (1)
Hedin, Niklas, 1969- (1)
Shu, Chenhua (1)
Deng, Yajie (1)
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Stockholms universitet (2)
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