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Sökning: WFRF:(Tokarev A)

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1.
  • Polme, S., et al. (författare)
  • FungalTraits: a user-friendly traits database of fungi and fungus-like stramenopiles
  • 2020
  • Ingår i: Fungal Diversity. - : Springer Science and Business Media LLC. - 1560-2745 .- 1878-9129. ; 105:1, s. 1-16
  • Tidskriftsartikel (refereegranskat)abstract
    • The cryptic lifestyle of most fungi necessitates molecular identification of the guild in environmental studies. Over the past decades, rapid development and affordability of molecular tools have tremendously improved insights of the fungal diversity in all ecosystems and habitats. Yet, in spite of the progress of molecular methods, knowledge about functional properties of the fungal taxa is vague and interpretation of environmental studies in an ecologically meaningful manner remains challenging. In order to facilitate functional assignments and ecological interpretation of environmental studies we introduce a user friendly traits and character database FungalTraits operating at genus and species hypothesis levels. Combining the information from previous efforts such as FUNGuild and Fun(Fun) together with involvement of expert knowledge, we reannotated 10,210 and 151 fungal and Stramenopila genera, respectively. This resulted in a stand-alone spreadsheet dataset covering 17 lifestyle related traits of fungal and Stramenopila genera, designed for rapid functional assignments of environmental studies. In order to assign the trait states to fungal species hypotheses, the scientific community of experts manually categorised and assigned available trait information to 697,413 fungal ITS sequences. On the basis of those sequences we were able to summarise trait and host information into 92,623 fungal species hypotheses at 1% dissimilarity threshold.
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3.
  • Paquin-Proulx, D, et al. (författare)
  • Preferential and persistent impact of acute HIV-1 infection on CD4+ iNKT cells in colonic mucosa
  • 2021
  • Ingår i: Proceedings of the National Academy of Sciences of the United States of America. - : Proceedings of the National Academy of Sciences. - 1091-6490. ; 118:46
  • Tidskriftsartikel (refereegranskat)abstract
    • Evidence suggests that HIV-1 disease progression is determined in the early stages of infection. Here, preinfection invariant natural killer T (iNKT) cell levels were predictive of the peak viral load during acute HIV-1 infection (AHI). Furthermore, iNKT cells were preferentially lost in AHI. This was particularly striking in the colonic mucosa, where iNKT cells were depleted more profoundly than conventional CD4+T cells. The initiation of antiretroviral therapy during AHI-prevented iNKT cell dysregulation in peripheral blood but not in the colonic mucosa. Overall, our results support a model in which iNKT cells are early and preferential targets for HIV-1 infection during AHI.
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4.
  • Kirilin, A, et al. (författare)
  • Mechanistic investigations of the reaction network in chemobiocatalyzed synthesis of R1Phenylethyl Acetate
  • 2010
  • Ingår i: Kinetics and catalysis. - : Springer. - 0023-1584 .- 1608-3210. ; 51:6, s. 809-815
  • Tidskriftsartikel (refereegranskat)abstract
    • The kinetics and reaction network of the onepot synthesis of R1phenylethyl acetate was investigated at 70°C in toluene over a combination of three different catalysts: PdZn/Al2O3 as a catalyst for acetophenone hydrogenation, lipase as an enzymatic catalyst for R1phenylethanol acylation with ethyl acetate and Ru/Al2O3 as a racemization catalyst for S1phenylethanol. In addition to the desired reactions, other reactions, namely hydrogenolysis and dehydration of (R, S)1phenylethanol and debenzylation of (R, S)1phenylethyl acetate also occurred. The kinetic results revealed that ethylbenzene formation was enhancedwith higher amounts of PdZn/Al2O3, whereas lipase did not catalyze ethylbenzene formation. Furthermore, ethylbenzene was formed in the hydrogenolysis of (R, S)phenylethanol and in the debenzylation of (R, S)1phenylethylacetate over Pd/Al2O3 catalyst. The presence of Ru/Al2O3 catalyst, in which Ru was in the oxidation state of 3+, enhanced the formation of R1phenylethyl acetate, although no clear racemization of S1phenylethanol during the onepot synthesis of  R1phenylethyl acetate was observed. Dynamic kinetic resolution of (R, S)1phenylethanol in toluene, was, however, demonstrated over Ru/Al2O3 and lipase.
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5.
  • Jiroušek, Martin, et al. (författare)
  • Classification of European bog vegetation of the Oxycocco‐Sphagnetea class
  • 2022
  • Ingår i: Applied Vegetation Science. - : Wiley. - 1402-2001 .- 1654-109X. ; 25:1, s. 1-19
  • Tidskriftsartikel (refereegranskat)abstract
    • Aims: Classification of  European bog   vegetation (Oxycocco- Sphagnetea class);    iden  -tification of  diagnostic species for   the   class    and   vegetation subgroups (orders and alliances); development of  an  expert     system for   automatic classification of  vegetation plots; and production of distribution maps of the Oxycocco- Sphagnetea class and its alliances.Location: Europe.Methods: A  data   set   of  vegetation- plot   records was   compiled to  include various bog types    over    most    of  the   European continent. An   unsupervised classification (beta- flexible linkage    method, Sørensen distance measure) and  detrended correspondenceanalysis (DCA)    ordination were    applied. Formal definitions of  syntaxa based    on  spe -cies  presence  and  covers,  and  respecting  the  results  of  the  unsupervised  classifica-tion, were developed and included in a classification expert system.Results: The Oxycocco- Sphagnetea class,    its  two   orders (Sphagno- Ericetalia  tetralicisand Sphagnetalia medii)  and   seven    compositionally distinct alliances were    formally de -fined.    In  addition to  the   syntaxa included in  EuroVegChecklist, three    new    alliances were distinguished: Rubo chamaemori- Dicranion elongati (subarctic polygon and   palsa mires);    Erico mackaianae- Sphagnion papillosi (blanket bogs   of  the  northwestern IberianPeninsula); and  Sphagno  baltici- Trichophorion  cespitosi (boreal bog   lawns). The   latter alliance is newly described in this article.Conclusions: This   first   pan-   European formalized classification of  European bog   veg -etation partially followed the   system presented in  EuroVegChecklist, but   suggested three  additional  alliances.  One  covers  palsa  and  polygon  mires,  one  covers  Iberian  bogs    with    endemics and   one   fills   the   syntaxonomical gap   for   lawn    microhabitats in boreal    bogs.    A  classification expert     system has   been   developed, which    allows    assign   -ment of vegetation plots to the types described.
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6.
  • Kurth, W.S., Hospodarsky, G.B., Gurnett, D.A., Kaiser, M.L., Wahlund, J.E., Roux, A., Canu, P., Zarka, P. and Tokarev, Y. (författare)
  • An overview of observations by the Cassini radio and plasma wave investigation at Earth.
  • 2001
  • Ingår i: Journal of Geophysical Research. ; 106:A12, s. 30239-
  • Tidskriftsartikel (refereegranskat)abstract
    • On August 18, 1999, the Cassini spacecraft flew by Earth at an altitude of 1186 km on its way to Saturn. Although the flyby was performed exclusively to provide the spacecraft with sufficient velocity to get to Saturn, the radio and plasma wave science (R
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7.
  • Tokarev, A V, et al. (författare)
  • The role of bio-ethanol in aqueous phase reforming to sustainable hydrogen
  • 2010
  • Ingår i: International journal of hydrogen energy. - : Elsevier Ltd. - 0360-3199 .- 1879-3487. ; 35:22, s. 12642-9
  • Tidskriftsartikel (refereegranskat)abstract
    • Aqueous Phase Reforming (APR) has during the recent years emerged as a potent, alternative means of processing raw materials of biological origin to component suitable as chemicals and fuel components. In contrary to e.g. steam reforming, aqueous phase reforming bares the promise of lower temperatures in processing which gives rise to potential of reduced energy consumption in the upgrading process itself.Aqueous phase reforming was studied over Pt/Al2O3 at 225 °C. Stable catalyst performance and high selectivity was observed. Upon a comparison of two ‘bio-alcohols’, bio-ethanol and Sorbitol (a sugar alcohol), the latter one is a better feedstock from overall energy utilization viewpoint but the use of it results in a broad range of products. Interestingly, in the case of sorbitol–ethanol mixtures, an improvement in the hydrogen yield was observed.
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8.
  • Murzin, D. Yu., et al. (författare)
  • Arabinogalactan hydrolysis and hydrolytic hydrogenation usingfunctionalized carbon materials
  • 2015
  • Ingår i: Catalysis Today. - : Elsevier BV. - 0920-5861 .- 1873-4308. ; 257, s. 169-176
  • Tidskriftsartikel (refereegranskat)abstract
    • Hydrolysis of the hemicellulose arabinogalactan was studied in this work over several functionalized carbon materials, which were specifically treated to increase their acidities. Hydrolytic hydrogenation of arabinogalactan was investigated using the same materials in a mechanical mixture with ruthenium supported on active carbon. Application of these mixtures resulted in formation of polyols, suppressing simultaneously the generation of side products hydroxymethylfurfural (HMF) and furfural. Formation of high molecular weight compounds (aggregates of sugars and humins) was still quite substantial with a mechanical mixture of Ru/C and a carbon material prepared from sucrose by activation with zinc chloride to increase porosity. Post-treatment of this carbonaceous material with sulphuric acid significantly influenced kinetics of high molecular weight products formation resulting also in elevation of sugar alcohols yields.
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  • Resultat 1-9 av 9

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